New biosensing strategies based on bipolar electrochemiluminescence. Chemical analysis is a vital activity in our society, which is to a large extent confined to scientific laboratories and carried out with complex instrumentation. The breakthrough technology envisioned in this proposal will pave the way for simple, low-cost tests which can be used by non-scientists. The development of small, portable sensors for applications ranging from pollution monitoring to health testing, will enable ordi ....New biosensing strategies based on bipolar electrochemiluminescence. Chemical analysis is a vital activity in our society, which is to a large extent confined to scientific laboratories and carried out with complex instrumentation. The breakthrough technology envisioned in this proposal will pave the way for simple, low-cost tests which can be used by non-scientists. The development of small, portable sensors for applications ranging from pollution monitoring to health testing, will enable ordinary people to gain knowledge about the concentrations of molecular compounds in their environments and in themselves. This will stimulate economic and social benefits related to environmental testing and early disease diagnosis and generate new commercial opportunities for the Australian biotechnology industry.Read moreRead less
Bioinspired tuneable catalysts for renewable ammonia production. The project will design a new solar-powered system for electrosynthesis of ammonia to replace the current energy intensive, non-sustainable process that generates 1.5% of global CO2 emissions. An innovative new system will be developed by combining cutting edge electrochemical, spectroscopic and theoretical methods. Expected key outcomes include novel concepts in the design of advanced materials, and an efficient process for the gr ....Bioinspired tuneable catalysts for renewable ammonia production. The project will design a new solar-powered system for electrosynthesis of ammonia to replace the current energy intensive, non-sustainable process that generates 1.5% of global CO2 emissions. An innovative new system will be developed by combining cutting edge electrochemical, spectroscopic and theoretical methods. Expected key outcomes include novel concepts in the design of advanced materials, and an efficient process for the green ammonia synthesis. Given the strategic importance of ammonia as a future energy carrier for the export of Australian renewables and as a major source of fertilisers, this project should provide significant national economic and ecological benefits and is expected to have a broad reaching global impact.Read moreRead less
Ambient Electrochemical C-N Coupling via Co-electrolysis of N2 and CO2. To overcome the hurdles in N2 fixation (massive energy consumption and CO2 emission), investigators creatively hypothesize that the simultaneous electrocatalytic coupling of N2 and CO2 would enable the selective formation of N-products and thus realize their conversion into N--fertilizers and acetamides. Based on the CI's recent discoveries, this project will develop an innovative / sustainable system, which could promote th ....Ambient Electrochemical C-N Coupling via Co-electrolysis of N2 and CO2. To overcome the hurdles in N2 fixation (massive energy consumption and CO2 emission), investigators creatively hypothesize that the simultaneous electrocatalytic coupling of N2 and CO2 would enable the selective formation of N-products and thus realize their conversion into N--fertilizers and acetamides. Based on the CI's recent discoveries, this project will develop an innovative / sustainable system, which could promote the N2 fixation along with CO2 conversion process, a significant alternative approach to simplify the pathways of C-N bond formation. It will thereby contribute to mitigation of greenhouse emissions and create an ecofriendly protocol/technology for distributed production of C-N products under ambient conditions. Read moreRead less
Ionic Liquids and Solids - New Designs, Insights and Applications. Ionic Materials in the form of liquid salts and plastic crystals are of interest in a wide range of applications including environmentally benign synthesis of chemicals and high stability electrolytes for batteries, capacitors and other devices. These materials represent some of the most stable chemicals known, making them attractive for any application where complete stability and recycling are issues. Building on our recent wor ....Ionic Liquids and Solids - New Designs, Insights and Applications. Ionic Materials in the form of liquid salts and plastic crystals are of interest in a wide range of applications including environmentally benign synthesis of chemicals and high stability electrolytes for batteries, capacitors and other devices. These materials represent some of the most stable chemicals known, making them attractive for any application where complete stability and recycling are issues. Building on our recent work, this project will design, prepare and characterize novel materials of this type for a number of target applications. Collaborators in Europe and USA will be involved in the analysis and testing of the materials.Read moreRead less
Novel Scanning Electrochemical Microscopy applications in molecular, supramolecular electrochemistry and biological systems. Improved understanding of chemical reactivity in natural and artificial molecular systems and acquisition of a wider perspective of electron transfer processes are two important challenges in chemistry and biology. Through this well defined research project, the CI, jointly with the host facility, has the skills to achieve valuable new insights. This project will expand Au ....Novel Scanning Electrochemical Microscopy applications in molecular, supramolecular electrochemistry and biological systems. Improved understanding of chemical reactivity in natural and artificial molecular systems and acquisition of a wider perspective of electron transfer processes are two important challenges in chemistry and biology. Through this well defined research project, the CI, jointly with the host facility, has the skills to achieve valuable new insights. This project will expand Australia's knowledge base and research capability and open new scenarios for frontier technologies and advanced materials. This project will introduce the SECM methods into Australia. The foreseen benefits include technology exchange and contribution to fundamental and applied science.Read moreRead less
Multifunctional and environmentally friendly corrosion inhibitor systems. This project aims to design new, environmentally friendly coating systems for steel in marine environments by incorporating novel, non-toxic pigments that can be combined to protect against both corrosion and microbial attack. Structural requirements for these compounds will be determined through the use of advanced characterisation techniques to identify the largely unknown mechanisms of attachment and protection on steel ....Multifunctional and environmentally friendly corrosion inhibitor systems. This project aims to design new, environmentally friendly coating systems for steel in marine environments by incorporating novel, non-toxic pigments that can be combined to protect against both corrosion and microbial attack. Structural requirements for these compounds will be determined through the use of advanced characterisation techniques to identify the largely unknown mechanisms of attachment and protection on steel surfaces. The components may themselves be dual active, or be combined to capitalise on individual protection mechanisms that provide a synergy whereby the combination leads to better protection outcomes. Such coatings have the potential to significantly improve the lifetime of marine infrastructure.Read moreRead less
Nano-engineered multi-functional materials for catalysis and sensing by an integrated chemical and electrochemical approach. This project aims to deliver a facile and cheap method to produce a class of nanostructured materials to be used in applications which will have environmental and social benefits such as: green synthesis of fine chemicals, catalyst development for clean energy fuel cells and sensor technology for the detection of potent biotoxins.
Future sodium based electrochemical energy storage technologies. New rechargeable batteries will be developed through the use of breakthrough electrolytes based on liquid salts. These batteries are vital for the widespread use of renewables in Australia's electricity grid. They will also enable new generations of environmental sensor technology.
Medium temperature electrolysis for low-cost carbon dioxide utilization. Carbon dioxide is a notorious greenhouse gas. Its capture, and subsequent storage or utilization, is a major focus not only for researchers, but also for governments trying to meet their obligations of the Paris Agreement on climate change and for industries managing their legal and social responsibilities. This project aims to develop commercially viable medium temperature electrolysers to convert carbon dioxide into value ....Medium temperature electrolysis for low-cost carbon dioxide utilization. Carbon dioxide is a notorious greenhouse gas. Its capture, and subsequent storage or utilization, is a major focus not only for researchers, but also for governments trying to meet their obligations of the Paris Agreement on climate change and for industries managing their legal and social responsibilities. This project aims to develop commercially viable medium temperature electrolysers to convert carbon dioxide into value added chemicals using electricity from renewable sources. New design principles will be developed to generate highly active and selective catalysts with long-term stability. These electrolyzers will be integrated with carbon capture technologies to directly utilize captured carbon dioxide with high energy efficiency.Read moreRead less
Electrochemically, photochemically and magnetically tuneable organic semi-conducting electrodes for probing biologically important redox chemistry and catalysis. Newly developed tuneable, semi-conductor electrode materials will facilitate substantial advances in electrochemistry. The almost unprecedented levels of flexibility with respect to metal and organic constituents will facilitate insights into biologically important electron transfer and coupled catalytic processes and promote commercia ....Electrochemically, photochemically and magnetically tuneable organic semi-conducting electrodes for probing biologically important redox chemistry and catalysis. Newly developed tuneable, semi-conductor electrode materials will facilitate substantial advances in electrochemistry. The almost unprecedented levels of flexibility with respect to metal and organic constituents will facilitate insights into biologically important electron transfer and coupled catalytic processes and promote commercial opportunities for sensor development. Electrochemistry represents an enabling discipline in science. The project offers the opportunity for high quality multi-disciplinary doctoral training, integration of skills of scientists from different backgrounds and opportunities to work in world-class national and international infrastructure in the areas of chemistry, biological chemistry and materials science.Read moreRead less