Electrostatic catalysis from single-molecule events to macroscopic systems. Electrostatics has important applications in day-to-day technologies, from recycling plastics to photocopying, but the exploration of how static charges affect chemical bonds and bonding is still in its infancy. This project aims to demonstrate the experimental links between the magnitude and polarity of an external electric field and chemical rates, expanding our understanding of chemical reactivity and transforming our ....Electrostatic catalysis from single-molecule events to macroscopic systems. Electrostatics has important applications in day-to-day technologies, from recycling plastics to photocopying, but the exploration of how static charges affect chemical bonds and bonding is still in its infancy. This project aims to demonstrate the experimental links between the magnitude and polarity of an external electric field and chemical rates, expanding our understanding of chemical reactivity and transforming our view of catalysis. By investigating the role of static electricity over systems selected from different sub-disciplines of chemistry, the project will derive the ground and selection rules for reactivity and selectivity by electrostatics. The project is expected to show that for chemical reactions of practical and conceptual value a specific catalyst can be replaced by a generic electric field stimulus, an invisible catalyst, enabling cleaner and cheaper opportunities that current technologies cannot fulfil.Read moreRead less
Mesoporous Metal Scaffolds: Reactive Containment Vessels. The storage of hydrogen is one of the most important issues that remains to be solved before the mass implementation of hydrogen as an energy carrier becomes commercially viable. This project aims to determine the kinetic and thermodynamic benefits of mesoporous metal scaffolds as reactive containment vessels for hydrogen storage materials. Fundamental experimental research into the synthesis, characterisation, and modification of nano-co ....Mesoporous Metal Scaffolds: Reactive Containment Vessels. The storage of hydrogen is one of the most important issues that remains to be solved before the mass implementation of hydrogen as an energy carrier becomes commercially viable. This project aims to determine the kinetic and thermodynamic benefits of mesoporous metal scaffolds as reactive containment vessels for hydrogen storage materials. Fundamental experimental research into the synthesis, characterisation, and modification of nano-confined hydrogen storage materials will be carried out. The results of this research are expected be used to tune hydrogen desorption temperatures and pressures of various light weight hydrogen storage materials to generate new materials attractive to the automobile industry.Read moreRead less