Nanotribology and Nanorheometry: A Fundamental Study of the Dynamic Interactions of Particles and Surfaces at the Molecular Level. Friction and deformation occur from the mutual motion and interaction of microscopic particles and surfaces. This research aims to develop new theories and measurement techniques for these non-equilibrium phenomena by combining mathematical analysis and numerical computations with dynamic force measurement, surface modification, and surface characterisation on nanom ....Nanotribology and Nanorheometry: A Fundamental Study of the Dynamic Interactions of Particles and Surfaces at the Molecular Level. Friction and deformation occur from the mutual motion and interaction of microscopic particles and surfaces. This research aims to develop new theories and measurement techniques for these non-equilibrium phenomena by combining mathematical analysis and numerical computations with dynamic force measurement, surface modification, and surface characterisation on nanometre and molecular length scales. These insights and data will be critically important in designing low-friction surfaces that save energy and wear, in developing nanoscopic probes for the mechanical and structural properties of soft polymeric and bio-materials, and in making high performance coatings that control adhesion and particle aggregation in technologically advanced applications.Read moreRead less
Anomalous interfacial air-bubble dynamics: the importance of electrokinetic effects in thin film drainage. Air bubbles play important roles in numerous systems including plastics and paper recycling, water treatment and mineral separation processes, foodstuffs, beverages, cosmetics, cleaning products, fire retardants, and natural systems such as rivers, oceans and biological fluids. The properties and behaviour of these systems and processes depend on how air bubbles in water interact with each ....Anomalous interfacial air-bubble dynamics: the importance of electrokinetic effects in thin film drainage. Air bubbles play important roles in numerous systems including plastics and paper recycling, water treatment and mineral separation processes, foodstuffs, beverages, cosmetics, cleaning products, fire retardants, and natural systems such as rivers, oceans and biological fluids. The properties and behaviour of these systems and processes depend on how air bubbles in water interact with each other, and/or with other materials. Currently our understanding of the bubble interactions is incomplete. The improved understanding gained from this research project will lead to better ability to control the properties of systems and processes such as those listed above.Read moreRead less
Ionic Dispersion Forces in Physical Chemistry: Implications for pH, Electrochemistry, Nanoparticle Formation and Organic Synthesis. Our current understanding of charged systems in solution is deeply flawed . Existing theories are not predictive, mainly because they concentrate entirely on electrostatics. This proposal aims to partially rectify this by including the effects of previously neglected dispersion forces in a number of problems. These forces are responsible for much of the behaviou ....Ionic Dispersion Forces in Physical Chemistry: Implications for pH, Electrochemistry, Nanoparticle Formation and Organic Synthesis. Our current understanding of charged systems in solution is deeply flawed . Existing theories are not predictive, mainly because they concentrate entirely on electrostatics. This proposal aims to partially rectify this by including the effects of previously neglected dispersion forces in a number of problems. These forces are responsible for much of the behaviour seen in the following systems: the theory of electrolytes; electrochemistry pH and buffers; self energy effects in organic chemistry; and zeolite and nano-particle synthesis. The main outcome will be accurate and predictive theories for these systems.Read moreRead less