Multiblock copolymer synthesis for nano-engineered materials. This project aims to develop methodology for environmentally friendly and industrially applicable synthesis of new types of advanced polymeric materials comprising multiblock copolymers. Polymeric materials play an important role in society with applications from bulk plastics to advanced technological applications. This would enable the creation of advanced materials with specific engineering targets and applications ranging from nan ....Multiblock copolymer synthesis for nano-engineered materials. This project aims to develop methodology for environmentally friendly and industrially applicable synthesis of new types of advanced polymeric materials comprising multiblock copolymers. Polymeric materials play an important role in society with applications from bulk plastics to advanced technological applications. This would enable the creation of advanced materials with specific engineering targets and applications ranging from nanomedicine to materials science.Read moreRead less
Highly functional green materials platform: Starch-ionic liquid-carbon nanotube polymer melt nanocomposites. This project will deliver state of the art scientific advances in green polymers, green plasticisers and tailored nanomaterials for melt processible renewable starch plastics for high-performance applications as electroactive polymers in areas such as biosensors and biodiagnostics.
Discovery Early Career Researcher Award - Grant ID: DE200101788
Funder
Australian Research Council
Funding Amount
$415,498.00
Summary
Advanced Macromolecular Architecture via Selenium. The overarching aim of this project is to drastically expand the scale and scope of selenium-based macromolecular chemistry via safe, odor-free multicomponent reactions utilising elemental selenium. This project will develop new methods and techniques in drastically reducing the cost while increasing worker and environmental safety of industrial elastomers such as Spandex. Next the project will exploit selenium's sensitivity to ozonolysis to des ....Advanced Macromolecular Architecture via Selenium. The overarching aim of this project is to drastically expand the scale and scope of selenium-based macromolecular chemistry via safe, odor-free multicomponent reactions utilising elemental selenium. This project will develop new methods and techniques in drastically reducing the cost while increasing worker and environmental safety of industrial elastomers such as Spandex. Next the project will exploit selenium's sensitivity to ozonolysis to design a new instrument capable of extreme precision in monitoring oxidative damage in polymeric materials. Finally, selenium's unique reactivity will lend itself towards the next generation of smart materials which will be capable of completely reorganizing their structure down to the molecular level.Read moreRead less
Discovery Early Career Researcher Award - Grant ID: DE170101249
Funder
Australian Research Council
Funding Amount
$360,000.00
Summary
Polymers with controllable networks. This project aims to understand the mechanism and molecular level factors controlling the network flexibility, reversibility and rapid curing of cross-linked polymer structures. A highly formable, rapidly curing polymer network could improve manufacture of composites where a fibre material is embedded in a polymer matrix. The key challenges for these materials are achieving high rates of production (one part per minute) and end of life recyclability. Expected ....Polymers with controllable networks. This project aims to understand the mechanism and molecular level factors controlling the network flexibility, reversibility and rapid curing of cross-linked polymer structures. A highly formable, rapidly curing polymer network could improve manufacture of composites where a fibre material is embedded in a polymer matrix. The key challenges for these materials are achieving high rates of production (one part per minute) and end of life recyclability. Expected outcomes are polymer materials with tailorable properties and the uptake of lightweight composite materials into mass transport systems.Read moreRead less
Biomimetic templating radical polymerisation in nanoreactors. The aim is to develop methodology for synthesis of polymer with hitherto inaccessible control of the microstructure by free radical means, that is the molecular weight distribution and monomer sequences. This will be achieved by combining the two concepts of biomimetic templated radical polymerisation and polymerisation in nanoreactors in the form of submicron-sized micelles or droplets. Scale-up of the methodology will be developed b ....Biomimetic templating radical polymerisation in nanoreactors. The aim is to develop methodology for synthesis of polymer with hitherto inaccessible control of the microstructure by free radical means, that is the molecular weight distribution and monomer sequences. This will be achieved by combining the two concepts of biomimetic templated radical polymerisation and polymerisation in nanoreactors in the form of submicron-sized micelles or droplets. Scale-up of the methodology will be developed based on an environmentally friendly approach whereby miniemulsions are generated using carbon dioxide. Increased ability to control the polymer microstructure will enable advanced design of functional polymers with far-reaching applications in materials science, nanotechnology and nanomedicine. Read moreRead less
Encoding Interactions and Printability into Hairy Colloidal Biomaterials. Printing mixtures of live cells and biomaterials (or 'BioInks') to make bespoke engineered tissues has the potential to enable personalised platforms for therapeutic discovery and organ replacement. Using a novel high throughput approach to materials synthesis, BioInk design and process optimisation, this project aims to discover new biomaterials and printing nozzles to help realise this potential. It will produce new insi ....Encoding Interactions and Printability into Hairy Colloidal Biomaterials. Printing mixtures of live cells and biomaterials (or 'BioInks') to make bespoke engineered tissues has the potential to enable personalised platforms for therapeutic discovery and organ replacement. Using a novel high throughput approach to materials synthesis, BioInk design and process optimisation, this project aims to discover new biomaterials and printing nozzles to help realise this potential. It will produce new insights in colloid science, cell-laden biomaterials design, and BioInk processing. Structure-property-function guides for colloid-based BioInks and quality-assured bioprinting as outcomes represent significant benefits for researchers and industries alike engaged in biofabrication, cell therapy and biotherapeutics.Read moreRead less
Self-reinforced biopolymer composites. This project will pioneer high performance and biodegradable composites using self-reinforced biopolymer composites. Composites can have poor properties due to interfacial issues, and this reduces their performance. By producing a fully self-reinforced (where the fibre and the polymer are the same type of polymer) polymer composites, the project will develop a way to improve properties, increase the use of biobased materials, and improve recyclability and b ....Self-reinforced biopolymer composites. This project will pioneer high performance and biodegradable composites using self-reinforced biopolymer composites. Composites can have poor properties due to interfacial issues, and this reduces their performance. By producing a fully self-reinforced (where the fibre and the polymer are the same type of polymer) polymer composites, the project will develop a way to improve properties, increase the use of biobased materials, and improve recyclability and biodegradability. Outcomes include greater understanding of design of self-reinforced biopolymer composites structure, processing and properties. This will produce opportunities for high performance biobased composite manufacturing and a growing circular plastics economy for Australia.Read moreRead less
Next-generation lithography: photo-directing assembly of block copolymers. This project aims to introduce a novel approach to organising block polymers through the photochemical modification of the surface of a photo-sensitive polymer. Chemo-epitaxy is the science of organising materials on a surface decorated with chemical patterns. The process has the potential to revolutionise the manufacture of integrated circuits, enabling faster processors. This project expects to introduce innovative conc ....Next-generation lithography: photo-directing assembly of block copolymers. This project aims to introduce a novel approach to organising block polymers through the photochemical modification of the surface of a photo-sensitive polymer. Chemo-epitaxy is the science of organising materials on a surface decorated with chemical patterns. The process has the potential to revolutionise the manufacture of integrated circuits, enabling faster processors. This project expects to introduce innovative concepts in polymer chemistry and nanoscale assembly with the potential to advance a multi-billion-dollar industry.Read moreRead less
Catalytic conversion of Australia's natural gas to value added products. While natural gas (of which methane is the primary component) is an abundant source of energy, it is normally found in remote areas and for its successful exploitation it needs to be processed. The processing usually requires significant energy and resources input. In this project we will develop a fundamental understanding to a single step catalytic process that can utilise natural gas and nitrous oxide (both potent greenh ....Catalytic conversion of Australia's natural gas to value added products. While natural gas (of which methane is the primary component) is an abundant source of energy, it is normally found in remote areas and for its successful exploitation it needs to be processed. The processing usually requires significant energy and resources input. In this project we will develop a fundamental understanding to a single step catalytic process that can utilise natural gas and nitrous oxide (both potent greenhouse gases) and oxygen to produce selectively methanol and hydrocarbons from a natural gas feedstream in a controlled manner. A single step process for natural gas conversion utilising waste green-house gases is expected to be of great benefit to the Australian economy, environment and energy securityRead moreRead less
Vesicles stabilised by compressed carbon dioxide as nanoreactors and templates for radical polymerisation. A new environmentally friendly method for synthesis of surfactant vesicles involving stabilisation using low pressure carbon dioxide will be applied to the synthesis of hollow polymeric nanoparticles and polymer of well-defined structure. The resulting polymeric structures will have applications in drug delivery and nano-engineered materials.