Advanced Ionic Materials for Organic Photovoltaics. Australia will greatly benefit from the development of improved solar energy technology, as a means of addressing the issue of climate change as a result of continued fossil fuel use. Solar power is also advantageous as it also allows electricity to be generated locally where it is needed, which is particularly important for the many remote areas of Australia. The climate in Australia is ideally suited for the electricity production through pho ....Advanced Ionic Materials for Organic Photovoltaics. Australia will greatly benefit from the development of improved solar energy technology, as a means of addressing the issue of climate change as a result of continued fossil fuel use. Solar power is also advantageous as it also allows electricity to be generated locally where it is needed, which is particularly important for the many remote areas of Australia. The climate in Australia is ideally suited for the electricity production through photovoltaics, and this project will focus on improving the performance of these devices to enable their widespread use. Read moreRead less
Characterization and design of new soft electrolyte materials. The use of fossil fuels for energy generation contributes heavily to global warming. The development of new types of energy sources (e.g. fuel cells) and energy storage devices (e.g. batteries) is of crucial importance to ease this pressure on the environment. The search for new, high energy-density electrolyte materials for these applications is intense. Recently, plastic crystal materials have been identified as potential electroly ....Characterization and design of new soft electrolyte materials. The use of fossil fuels for energy generation contributes heavily to global warming. The development of new types of energy sources (e.g. fuel cells) and energy storage devices (e.g. batteries) is of crucial importance to ease this pressure on the environment. The search for new, high energy-density electrolyte materials for these applications is intense. Recently, plastic crystal materials have been identified as potential electrolytes in a variety of electrochemical devices. These materials show high conductivity at ambient temperatures in their plastic (or soft) phase. This project aims to further investigate and develop these novel materials.Read moreRead less
Computational approaches to selection and design of ionic materials. Advanced batteries, fuel cells and solar cell technologies are beginning to use ionic liquids/plastic crystals as electrolytes due to their superb stability and valuable properties. As a broad class these ionic materials have only been known for the last 10 years or so and there is much to learn about their structure and properties. The project will develop and advance quantum chemical techniques for selection and design of ion ....Computational approaches to selection and design of ionic materials. Advanced batteries, fuel cells and solar cell technologies are beginning to use ionic liquids/plastic crystals as electrolytes due to their superb stability and valuable properties. As a broad class these ionic materials have only been known for the last 10 years or so and there is much to learn about their structure and properties. The project will develop and advance quantum chemical techniques for selection and design of ionic materials with the goal of developing electrolytes for a range of applications from advanced metal batteries, solar cells to fuel cells. These applications will have impact on energy efficiency and energy conservation by enabling CO2 replacing technologies. Read moreRead less
New Materials for Energy Capture and Conversion: Ionic Liquid-derived Conducting Polymers. Inherently conducting polymers (ICPs) have applications in a wide range of electrochemical devices including actuators, for artificial muscles, and photovoltaic cells for harnessing solar energy. Use of an ionic liquid as the electrolyte within these devices greatly increases the stability and cyclability of the ICP. Our preliminary work shows that an ionic liquid solvent in the synthesis of ICPs results i ....New Materials for Energy Capture and Conversion: Ionic Liquid-derived Conducting Polymers. Inherently conducting polymers (ICPs) have applications in a wide range of electrochemical devices including actuators, for artificial muscles, and photovoltaic cells for harnessing solar energy. Use of an ionic liquid as the electrolyte within these devices greatly increases the stability and cyclability of the ICP. Our preliminary work shows that an ionic liquid solvent in the synthesis of ICPs results in materials with dramatically different morphologies and improved electronic properties. Ionic liquids will be used to prepare ICPs with enhanced electrical and mechanical properties and prototype photovoltaic and actuator devices will be developed based on these new materials.Read moreRead less
Fully ab initio, large-scale calculations of thermodynamic and transport properties of ionic materials. Advanced batteries, fuel cells, and photonic device technologies are beginning to use ionic materials as electrolytes due to their superb stability and technologically valuable properties. As a broad class these materials have only been known for just over a decade and there is still more unknown than known about their structure and properties. The project will develop new advanced computation ....Fully ab initio, large-scale calculations of thermodynamic and transport properties of ionic materials. Advanced batteries, fuel cells, and photonic device technologies are beginning to use ionic materials as electrolytes due to their superb stability and technologically valuable properties. As a broad class these materials have only been known for just over a decade and there is still more unknown than known about their structure and properties. The project will develop new advanced computational methods as a basis for understanding their properties and thereby allowing us to design-in desired features. Ultimately these advances will have support the development of energy efficient CO2 replacement technologies.Read moreRead less