Characterization of Sub- and Super-Critical Fluids in Nanomaterials. In recent years, nano-porous materials have become the most potential media for applications in the areas of separation and purification, with materials such as carbon alloy, activated carbon fibre, carbon nanotube and their derivatives. Their effective utilisation depends on how well we characterise them for their adsorption capacities. In this project, we propose a new model for this characterisation and this model can be u ....Characterization of Sub- and Super-Critical Fluids in Nanomaterials. In recent years, nano-porous materials have become the most potential media for applications in the areas of separation and purification, with materials such as carbon alloy, activated carbon fibre, carbon nanotube and their derivatives. Their effective utilisation depends on how well we characterise them for their adsorption capacities. In this project, we propose a new model for this characterisation and this model can be used for the prediction of adsorption of multicomponent systems, which are common in separation and purification industries, without recourse to extensive experimentation. The success of this model could translate to cost savings in those industries.Read moreRead less
Gas phase studies of reactive organic radicals: a novel approach using mass spectrometry. Radical reactions play a crucial role in a range of important chemistries, ranging from the formation of photochemical smog to the accumulation of pathogens in the ageing body. Despite their importance, the reactions of many radicals are poorly understood because of current experimental limitations. In this project we propose to develop two new and broadly applicable techniques for probing radical chemistry ....Gas phase studies of reactive organic radicals: a novel approach using mass spectrometry. Radical reactions play a crucial role in a range of important chemistries, ranging from the formation of photochemical smog to the accumulation of pathogens in the ageing body. Despite their importance, the reactions of many radicals are poorly understood because of current experimental limitations. In this project we propose to develop two new and broadly applicable techniques for probing radical chemistry in the gas phase via novel applications of mass spectrometry. Combined with quantum chemical calculations and state-of-the-art thermodynamic measurements these methods will provide a comprehensive understanding of the reactivity of key organic radicals.Read moreRead less
Carbon dioxide conversion over nanostructured mixed metal catalysts. Nanocatalysts are particles of very small size that have the ability to accelerate chemical reactions. This project will develop nanocatalysts to convert carbon dioxide into other small molecules to provide new options for managing greenhouse gas emissions.
Interfacial Nanofluids. The fundamental understanding of Colloid and Surface Chemistry will be significantly enhanced through the understanding of the formation and properties of interfacial nanofluids. In addition, this project will provide the knowledge of the influence of nanofluids on the lubrication and the surface interaction. The future results will likely have great impact on the development of miniature devices, lab-on-a-chip and microfludics or nanofluidics systems, water treatment, m ....Interfacial Nanofluids. The fundamental understanding of Colloid and Surface Chemistry will be significantly enhanced through the understanding of the formation and properties of interfacial nanofluids. In addition, this project will provide the knowledge of the influence of nanofluids on the lubrication and the surface interaction. The future results will likely have great impact on the development of miniature devices, lab-on-a-chip and microfludics or nanofluidics systems, water treatment, minerals processing, the food industries, pumping of fuel and water, and other processes. And the research described in this proposal will help to maintain the high international profile of Australian science in the field of Colloid and Surface Research. Read moreRead less
Ionic Liquids and Solids - New Designs, Insights and Applications. Ionic Materials in the form of liquid salts and plastic crystals are of interest in a wide range of applications including environmentally benign synthesis of chemicals and high stability electrolytes for batteries, capacitors and other devices. These materials represent some of the most stable chemicals known, making them attractive for any application where complete stability and recycling are issues. Building on our recent wor ....Ionic Liquids and Solids - New Designs, Insights and Applications. Ionic Materials in the form of liquid salts and plastic crystals are of interest in a wide range of applications including environmentally benign synthesis of chemicals and high stability electrolytes for batteries, capacitors and other devices. These materials represent some of the most stable chemicals known, making them attractive for any application where complete stability and recycling are issues. Building on our recent work, this project will design, prepare and characterize novel materials of this type for a number of target applications. Collaborators in Europe and USA will be involved in the analysis and testing of the materials.Read moreRead less
Electrochemical Applications of Plastic Crystalline Electrolytes. A number of new and emerging electrochemical device applications such as lithium batteries, dye-sensitized solar cells, electrochemical capacitors, actuators and bio-sensors are limited by their need for a liquid electrolyte. Many of these devices are considered vital to energy efficiency and the lowering of greenhouse gas emissions. The recent discovery of ambient temperature plastic crystalline electrolyte materials by the Monas ....Electrochemical Applications of Plastic Crystalline Electrolytes. A number of new and emerging electrochemical device applications such as lithium batteries, dye-sensitized solar cells, electrochemical capacitors, actuators and bio-sensors are limited by their need for a liquid electrolyte. Many of these devices are considered vital to energy efficiency and the lowering of greenhouse gas emissions. The recent discovery of ambient temperature plastic crystalline electrolyte materials by the Monash Electrolytes group has raised the possibility of solving this problem. In this project new plastic crystalline electrolyte materials will be developed to suit these applications and their electrochemical properties investigated. Laboratory prototype devices will be prepared and tested and via collaborations with appropriate device developers, their performance evaluted.Read moreRead less
Reactive Intermediates in Atmospheric and Combustion Chemistry. Reactive intermediates are the key species that determine outcomes of the chemical reaction networks in atmospheric and combustion chemistry. However, most reactive intermediates remain undiscovered. The project aims to discover these intermediates using laser spectroscopy. Current models of atmospheric chemistry cannot account for the carbon balance over forests, nor the formation of secondary organic aerosols. Combustion models st ....Reactive Intermediates in Atmospheric and Combustion Chemistry. Reactive intermediates are the key species that determine outcomes of the chemical reaction networks in atmospheric and combustion chemistry. However, most reactive intermediates remain undiscovered. The project aims to discover these intermediates using laser spectroscopy. Current models of atmospheric chemistry cannot account for the carbon balance over forests, nor the formation of secondary organic aerosols. Combustion models struggle to predict how next-generation fuels burn in modern engines. The successful discovery of these intermediates would allow models to be more accurate and predictive. This will allow scientists, engineers and policy makers to make more informed decisions about atmospheric processes and design more efficient new fuels.Read moreRead less
Formation, photochemistry and fate of gas-phase peroxyl radicals. This project aims to understand how peroxyl radical reactions modulate the composition of air. The gas-phase chemical reactions of organic peroxyl radicals contribute to air quality in clean and polluted environments. However, experimental observations of these reaction intermediates and the complex mechanisms governing their formation and fate are limited. This project will use mass spectrometry and laser-based methods to interro ....Formation, photochemistry and fate of gas-phase peroxyl radicals. This project aims to understand how peroxyl radical reactions modulate the composition of air. The gas-phase chemical reactions of organic peroxyl radicals contribute to air quality in clean and polluted environments. However, experimental observations of these reaction intermediates and the complex mechanisms governing their formation and fate are limited. This project will use mass spectrometry and laser-based methods to interrogate the chemical and photochemical reactions of peroxyl radicals in the gas phase. This project expects to understand the composition and dynamics of the troposphere and inform strategies to improve air quality.Read moreRead less
Discovery Early Career Researcher Award - Grant ID: DE130100970
Funder
Australian Research Council
Funding Amount
$370,600.00
Summary
Solar energy conversion: illuminating the origin of long-lived charge-separated states in organic donor/acceptor blends. The origin of exceptionally long-lived charges in organic donor/acceptor solid-state blends will be established. This will substantially enhance the efficiency and commercial viability of applications that rely on these long-lived charge-separated states, such as organic solar cells.
Hot exciton dissociation in donor / acceptor organic solar cells: breaking the efficiency limit of organic photovoltaics. Australia will benefit from this project in several key areas with immediate impact. The development of an innovative solar cell architecture through the use of hot exiton dissociation will deliver a potential increase in the maximum achievable power conversion efficiency. The experimental results will significantly advance fundamental knowledge of organic solar cells. This ....Hot exciton dissociation in donor / acceptor organic solar cells: breaking the efficiency limit of organic photovoltaics. Australia will benefit from this project in several key areas with immediate impact. The development of an innovative solar cell architecture through the use of hot exiton dissociation will deliver a potential increase in the maximum achievable power conversion efficiency. The experimental results will significantly advance fundamental knowledge of organic solar cells. This has significant economic benefits by making these solar cells more affordable and also opening up the opportunity to use new materials unconstrained by existing proprietary interests. The training of personnel will contribute towards solving the biggest challenge facing the solar industry in Australia: lack of skilled personnel in a highly specialised industry.Read moreRead less