Anomalous isotope effects in atmospheric ozone and carbon dioxide. The anomalous isotopic composition of atmospheric ozone, which has been a puzzle for over twenty years, will be investigated by laboratory and atmospheric measurements. An understanding of the source of this anomaly and its effect on the isotopic composition of other trace atmospheric gases, especially CO2, would provide unique opportunities for constraining the tropospheric and stratospheric ozone budgets and determining the his ....Anomalous isotope effects in atmospheric ozone and carbon dioxide. The anomalous isotopic composition of atmospheric ozone, which has been a puzzle for over twenty years, will be investigated by laboratory and atmospheric measurements. An understanding of the source of this anomaly and its effect on the isotopic composition of other trace atmospheric gases, especially CO2, would provide unique opportunities for constraining the tropospheric and stratospheric ozone budgets and determining the history of a particular air mass. The method of detection will be high resolution FTIR spectroscopy which, in contrast to traditional mass-spectrometric methods, provides information about the position of the heavy atom in an enriched ozone molecule and requires no sample preparation.Read moreRead less
New insights into free radical reactivity via gas phase studies of radical anions. Free radicals are known to be critical reactive intermediates in chemical processes ranging from the formation of photochemical smog, through combustion to the onset of age-related diseases. This research increases our understanding of how free radicals react and will thus allow for more accurate prediction, and in some instances greater control, of the outcomes of chemical reactions and their health and environme ....New insights into free radical reactivity via gas phase studies of radical anions. Free radicals are known to be critical reactive intermediates in chemical processes ranging from the formation of photochemical smog, through combustion to the onset of age-related diseases. This research increases our understanding of how free radicals react and will thus allow for more accurate prediction, and in some instances greater control, of the outcomes of chemical reactions and their health and environmental consequences. New instrumental technologies will be developed and young Australian researchers will be trained here, and with collaborators in the USA, in state-of-the-art techniques (particularly in mass spectrometry) that are essential to our emerging technology-based economy.Read moreRead less
Gas-phase and catalytic reaction of halons under reducing conditions. Halons are ozone-depleting substances, but their use continues in most countries. This project pursues techniques to convert, rather than destroy, halons into benign and useful products. The aims of this project are to gain a fundamental understanding of the reactions of the most commonly used halons, 1301, 1211 and 2402, and perform a detailed examination of catalytic processes for conversion of halons to HFCs. The primary ....Gas-phase and catalytic reaction of halons under reducing conditions. Halons are ozone-depleting substances, but their use continues in most countries. This project pursues techniques to convert, rather than destroy, halons into benign and useful products. The aims of this project are to gain a fundamental understanding of the reactions of the most commonly used halons, 1301, 1211 and 2402, and perform a detailed examination of catalytic processes for conversion of halons to HFCs. The primary outcome from the study will be the development of a process specifically designed to convert halons into useful products. This will assist with efforts to phase out continued halon use.Read moreRead less
Tectonic versus biological processes: What controls the long-term global carbon cycle? A major debate in Earth system analysis concerns two competing hypotheses on the driving forces behind dramatic changes in atmospheric CO2 over geological time. One hypothesis considers tectonic/geological processes to be the major driving force. The other argues that it is the competition between plants and animals that drives the long-term CO2 cycle. We propose to test these hypotheses using a novel set of g ....Tectonic versus biological processes: What controls the long-term global carbon cycle? A major debate in Earth system analysis concerns two competing hypotheses on the driving forces behind dramatic changes in atmospheric CO2 over geological time. One hypothesis considers tectonic/geological processes to be the major driving force. The other argues that it is the competition between plants and animals that drives the long-term CO2 cycle. We propose to test these hypotheses using a novel set of global oceanic palaeo-age grids and subduction models for the last 180 million years. This will allow us to appraise key tectonic carbon cycle components such as mantle degassing, seafloor weathering and sediment subduction.Read moreRead less
Resolving Critical Knowledge Gaps Relating to Light and Free-Radical Mediated Transformations of Iron and Copper in Oxic Natural Waters. Understanding the transformation kinetics of iron and copper species is critical to maintaining Australia's water resources since i) iron transformations are key to generation and transport of acid in Australia's coastal environment; ii) growth of toxic algae are stimulated by dissolution of iron-rich sediments with subsequent release of nutrients phosphorus an ....Resolving Critical Knowledge Gaps Relating to Light and Free-Radical Mediated Transformations of Iron and Copper in Oxic Natural Waters. Understanding the transformation kinetics of iron and copper species is critical to maintaining Australia's water resources since i) iron transformations are key to generation and transport of acid in Australia's coastal environment; ii) growth of toxic algae are stimulated by dissolution of iron-rich sediments with subsequent release of nutrients phosphorus and iron, and iii) algal toxicity is related to iron and copper nutrition and interplay of these metals with oxygen. Additionally, global cycles of carbon, phosphorus and nitrogen are influenced by iron and copper interactions with light and oxygen. Improved understanding of these processes should lead to an awareness of how to prevent these problems and, if they occur, approaches to their mitigation.Read moreRead less
Transformation of halons and CFC to valuable products through their reaction with methane. Halons and CFCs are well known as ozone depleting substances (ODS). This project pursues the development of a novel process to transform stockpiles of halons and CFCs into vinylidene difluoride (C2H2F2). Vinylidene difluoride is a highly valued commodity, used in the synthesis of heat resistant materials. The primary aim of this research is to gain understanding of the role of catalysts during conversion o ....Transformation of halons and CFC to valuable products through their reaction with methane. Halons and CFCs are well known as ozone depleting substances (ODS). This project pursues the development of a novel process to transform stockpiles of halons and CFCs into vinylidene difluoride (C2H2F2). Vinylidene difluoride is a highly valued commodity, used in the synthesis of heat resistant materials. The primary aim of this research is to gain understanding of the role of catalysts during conversion of CFC 12 and halon 1211 into the desired reaction product. The signifigance of the project is that it will facilitate development of a process for non-destructive treatment of ozone depleting substances. The major outcome of the proposed research is it will lay the technical foundation for the development of an energy efficient process to convert rather than destroy these ODS.Read moreRead less
Molecular signatures of complex photodissociation reactions. All energy on earth comes from the sun, either directly (e.g photosynthesis) or indirectly (e.g fossil fuels). Photochemistry is the study of how this light is absorbed and what happens to a molecule afterwards. Despite significant experimental and theoretical advances in the past decade (some in our lab), scientists still cannot predict the outcomes of most photochemical reactions. In this project we will determine the reactivity o ....Molecular signatures of complex photodissociation reactions. All energy on earth comes from the sun, either directly (e.g photosynthesis) or indirectly (e.g fossil fuels). Photochemistry is the study of how this light is absorbed and what happens to a molecule afterwards. Despite significant experimental and theoretical advances in the past decade (some in our lab), scientists still cannot predict the outcomes of most photochemical reactions. In this project we will determine the reactivity of several small, fundamental organic molecules. Not only are these molecules pollutants around our cities, but discovery of how they react in the presence of light will allow us to understand and predict the photochemistry of a much wider range of organic species.Read moreRead less
Linkage Infrastructure, Equipment And Facilities - Grant ID: LE0989390
Funder
Australian Research Council
Funding Amount
$500,000.00
Summary
Versatile Scanning X-ray Microscopy Facility at the Australian Synchrotron. The challenges of the modern world means that the Australian community must continue to have access to state of the art research tools. An important component of international synchrotron sources is the very high resolution x-ray microscope. These microscopes are used to image samples of biological, material or environmental significance with extraordinary precision. This project will establish such a microscope at the A ....Versatile Scanning X-ray Microscopy Facility at the Australian Synchrotron. The challenges of the modern world means that the Australian community must continue to have access to state of the art research tools. An important component of international synchrotron sources is the very high resolution x-ray microscope. These microscopes are used to image samples of biological, material or environmental significance with extraordinary precision. This project will establish such a microscope at the Australian Synchrotron in Clayton, and nucleates an extensive nationwide collaboration that is devoted to the development of this and related techniques and their application to problems of national scientific, environmental and technological importance.Read moreRead less