A Midas touch for electrophiles in new reaction development. This project aims to address the lack of knowledge about how high-value organic molecules are formed in gold-catalysed reactions by advancing a novel mode of catalysis. This project expects to generate new knowledge about these gold-catalysed reactions using an innovative, interdisciplinary approach incorporating computational and synthetic techniques. Expected outcomes of this project include the optimisation and development of import ....A Midas touch for electrophiles in new reaction development. This project aims to address the lack of knowledge about how high-value organic molecules are formed in gold-catalysed reactions by advancing a novel mode of catalysis. This project expects to generate new knowledge about these gold-catalysed reactions using an innovative, interdisciplinary approach incorporating computational and synthetic techniques. Expected outcomes of this project include the optimisation and development of important organic reactions and enhancing collaboration nationally and internationally between computational and synthetic chemists. This should provide significant benefits in the form of improved chemical reactions for chemists to prepare new pharmaceuticals, agrochemicals and materials.Read moreRead less
Switchable and stereocontrolled photoredox catalysis. This project aims to develop new catalytic synthetic reactions for the rapid and more direct functionalisation of organic compounds under mild conditions with the use of visible light. An integrated experimental and computational approach will be used to design potent visible-light photocatalysts that retain the advantages of standard photoredox catalysis but with the added ability to intercept and, thus control, reactive intermediates in sit ....Switchable and stereocontrolled photoredox catalysis. This project aims to develop new catalytic synthetic reactions for the rapid and more direct functionalisation of organic compounds under mild conditions with the use of visible light. An integrated experimental and computational approach will be used to design potent visible-light photocatalysts that retain the advantages of standard photoredox catalysis but with the added ability to intercept and, thus control, reactive intermediates in situ. This will enable the control of stereochemistry in photoredox reactions – not possible with standard catalysts - and establish other useful synthetic transformations. These strategies will make it easier to prepare valuable classes of organic molecules – efficiently, safely, and cost-effectively.
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A new route to linear alpha olefins - catalytic isomerisation of internal olefins. Linear alpha olefins are an extremely important class of chemical building blocks used for everyday consumer products, such as plastics, detergents and lubricants. This research aims to develop a new platform technology for the production of these materials from low cost precursors.
Calcification and shell chemistry response of Southern Ocean planktic foraminifers to ocean acidification and changing climates. Plankton that form tiny calcium carbonate shells will be cultured to determine how they will respond to acidification of the Southern Ocean caused by rising CO2 in the atmosphere. The same experiments will be used to gauge from their fossil shells how the Southern Ocean has caused and responded to changing atmosphere CO2 over the last glacial climate cycle
Ancient Ecology: Changes in penguin diet over ~30,000 years in Antarctica. This project proposes the first direct study of ancient ecology using a combination of second-generation DNA sequencing and targeted gene recovery. The food web of the Antarctic Ocean is a classic textbook example of energy and nutrient cycling in the marine environment. Although a great deal is known about the current status of this food web, understanding how this complex set of predator / prey relationships have change ....Ancient Ecology: Changes in penguin diet over ~30,000 years in Antarctica. This project proposes the first direct study of ancient ecology using a combination of second-generation DNA sequencing and targeted gene recovery. The food web of the Antarctic Ocean is a classic textbook example of energy and nutrient cycling in the marine environment. Although a great deal is known about the current status of this food web, understanding how this complex set of predator / prey relationships have changed over long periods of time is vital to understanding the nature of the system itself. The project intends to track changes in the diet of Adélie penguins from serially preserved ancient fecal (guano) remains dating back approximately 30,000 years. These remains are known to contain microscopic remnants of penguin prey.Read moreRead less
AirLIFT – an airborne active chlorophyll fluorescence sensing system for assessment of photosynthetic activity in plant canopies. Assessment of plant health and productivity is vital to ensure future food security of the global population under a changing climate. Chlorophyll fluorescence (CF), a signal emitted by green plants, can reveal this information. Although CF has revolutionised photosynthetic research, current measurements are limited to individual plants. Remote sensing of canopy CF is ....AirLIFT – an airborne active chlorophyll fluorescence sensing system for assessment of photosynthetic activity in plant canopies. Assessment of plant health and productivity is vital to ensure future food security of the global population under a changing climate. Chlorophyll fluorescence (CF), a signal emitted by green plants, can reveal this information. Although CF has revolutionised photosynthetic research, current measurements are limited to individual plants. Remote sensing of canopy CF is required for efficient management of agricultural crops, forests, and natural ecosystems and is crucial for accurate estimation of plant carbon assimilation and production. This project will deliver remote sensing technology to bridge the gap between leaf and canopy productivity and pave the way for understanding both artificial and solar induced canopy CF measured from space.Read moreRead less
The future of forests under climatic stress. This project aims to measure the vulnerability of forest trees to more extreme drought as global temperatures inevitably rise. Australian forests face the immediate threat of increased mortality associated with intensifying drought stress in the future. Understanding the magnitude of this threat is of the utmost urgency. This project aims to predict future mortality of forest communities in Australia and worldwide using recent breakthroughs enabling t ....The future of forests under climatic stress. This project aims to measure the vulnerability of forest trees to more extreme drought as global temperatures inevitably rise. Australian forests face the immediate threat of increased mortality associated with intensifying drought stress in the future. Understanding the magnitude of this threat is of the utmost urgency. This project aims to predict future mortality of forest communities in Australia and worldwide using recent breakthroughs enabling the rapid quantification of lethal stress in trees. This new understanding will provide a basis upon which to make far-reaching decisions about land management, conservation and restoration.Read moreRead less
Using animal-borne sensors to unravel East Antarctic coastal productivity. This project will examine the mechanisms underpinning the high productivity in Antarctic coastal polynyas, which are ice-free oases within the sea ice supporting abundant marine life. The study expects to generate essential new biochemical and biological observations using autonomous platforms to understand phytoplankton dynamics in these inaccessible habitats along Australia’s Antarctic Territory. Expected outcomes inclu ....Using animal-borne sensors to unravel East Antarctic coastal productivity. This project will examine the mechanisms underpinning the high productivity in Antarctic coastal polynyas, which are ice-free oases within the sea ice supporting abundant marine life. The study expects to generate essential new biochemical and biological observations using autonomous platforms to understand phytoplankton dynamics in these inaccessible habitats along Australia’s Antarctic Territory. Expected outcomes include novel insight into the role of iron supply from melting glaciers in supporting marine production. This should reduce the high uncertainty in prognoses for polynya activity under anthropogenic climate change, and support Australia’s international leadership in conservation and management of important Antarctic ecosystems.Read moreRead less
Hot iron: Are submarine volcanoes important for Southern Ocean iron supply? The scarcity of iron limits biological productivity and carbon uptake in the nutrient rich waters of the Southern Ocean. This project will explore for the first time the role of undersea "hot spot" volcanoes in supplying iron to surface waters, thus linking the solid earth and the biosphere. The project will measure iron abundance, reactivity and nutritional value in buoyant plumes emanating from vents near Heard/McDonal ....Hot iron: Are submarine volcanoes important for Southern Ocean iron supply? The scarcity of iron limits biological productivity and carbon uptake in the nutrient rich waters of the Southern Ocean. This project will explore for the first time the role of undersea "hot spot" volcanoes in supplying iron to surface waters, thus linking the solid earth and the biosphere. The project will measure iron abundance, reactivity and nutritional value in buoyant plumes emanating from vents near Heard/McDonald Islands, Australia's only active volcanoes. The project aims to estimate the hydrothermal contribution to regional biological productivity and extrapolate to the whole Southern Ocean. Successful outcomes will benefit Australia by identifying iron sources that govern productivity and carbon uptake of an economically important ecosystem.Read moreRead less
Polymer nanoparticles and their assembled supracolloidal monolithic structures for applications in separation science. This project will generate new polymeric materials that will improve the analysis of complex samples. This will be applied in a wide range of areas of national importance including: pharmaceutical analysis and drug discovery; environmental, clinical and forensic analysis; and energy generation and foods.