Molecular archaeology: new knowledge from molecular weight distributions of synthetic and natural polymers. This project will lead to new understanding of how natural and synthetic polymers are formed. Examples are the enzymatic processes that produce the subtle architecture of rice grains, and the processes that pose problems for developing new techniques for making novel polymer-based materials. The fundamental scientific knowledge from this project will provide a platform for the future devel ....Molecular archaeology: new knowledge from molecular weight distributions of synthetic and natural polymers. This project will lead to new understanding of how natural and synthetic polymers are formed. Examples are the enzymatic processes that produce the subtle architecture of rice grains, and the processes that pose problems for developing new techniques for making novel polymer-based materials. The fundamental scientific knowledge from this project will provide a platform for the future development of improved materials, and for superior grain varieties for food and industrial use. These advances will be of significant benefit to Australian industry and consumers.Read moreRead less
Synthesis of nanocomposite polymers with targeted properties. This project aims to synthesise novel nanocomposite polymers by living radical polymerisation in water and to understand the way polymer microstructure and nanomorphology control material properties. This will provide the enabling science so that nanomaterials with targeted properties can be tailor-made for biomedical and speciality-coatings applications, and thus dispense with the current trial-and-error methodology. The innovations ....Synthesis of nanocomposite polymers with targeted properties. This project aims to synthesise novel nanocomposite polymers by living radical polymerisation in water and to understand the way polymer microstructure and nanomorphology control material properties. This will provide the enabling science so that nanomaterials with targeted properties can be tailor-made for biomedical and speciality-coatings applications, and thus dispense with the current trial-and-error methodology. The innovations in this project are the novel synthesis of complex polymer architectures in water, and the first quantitative and qualitative structure-property correlations for such materials. This will also result in a deepened understanding of the mechanisms governing the formation of these nanocomposites.Read moreRead less
Plasmonic nanoparticle catalysis for nitrogen-based synthesis. Light can generate an optical force to capture small objects. This requires intense light – a laser, which limits optical trapping in catalysis applications. This project aims to apply plasmonic nanoparticles with normal-intensity light to take advantage of plasmonic-generated optical forces for catalytic chemical synthesis. The optical trapping/releasing of small molecules is highly selective and responsive to molecule structure and ....Plasmonic nanoparticle catalysis for nitrogen-based synthesis. Light can generate an optical force to capture small objects. This requires intense light – a laser, which limits optical trapping in catalysis applications. This project aims to apply plasmonic nanoparticles with normal-intensity light to take advantage of plasmonic-generated optical forces for catalytic chemical synthesis. The optical trapping/releasing of small molecules is highly selective and responsive to molecule structure and so presents a great opportunity to radically alter chemical synthesis pathways, which will be illustrated with reactions on liquid-solid and gas-solid interfaces. This highly innovative strategy will be used to discover new nitrogen-based syntheses which are both fundamentally and industrially important.Read moreRead less
Promoting transition metal complex catalysis with plasmonic antennae. This project aims to apply visible light photocatalysis to a wide range of chemical reactions by utilizing the intriguing effects of intense light absorption by plasmonic metal nanoparticles, such as generating energetic electrons, changing reactant adsorption and the chemical binding of reactant with the catalyst. These effects will promote catalysis at surface-bound metal complex reaction sites under mild reaction conditions ....Promoting transition metal complex catalysis with plasmonic antennae. This project aims to apply visible light photocatalysis to a wide range of chemical reactions by utilizing the intriguing effects of intense light absorption by plasmonic metal nanoparticles, such as generating energetic electrons, changing reactant adsorption and the chemical binding of reactant with the catalyst. These effects will promote catalysis at surface-bound metal complex reaction sites under mild reaction conditions. This is a part of our long-term effort to transform chemical production by heating into green photocatalytic process. This project expects to generate knowledge crucial for developing theories for catalysis, the design of efficient catalysts, green chemical synthesis methods, and enhance international collaboration.Read moreRead less
Discovery Early Career Researcher Award - Grant ID: DE160101488
Funder
Australian Research Council
Funding Amount
$375,000.00
Summary
New Photocatalysts for CO2 Reduction. The project aims to develop novel photocatalysts for reducing carbon dioxide (CO2) to useful products using solar energy. Carbon dioxide (CO2) photoreduction is attracting growing attention because of its potential to mitigate CO2 emissions and convert the captured CO2 to chemical commodities. The project also plans to identify the photocatalytic mechanisms of the catalysts by investigating the reaction systems, such as the interface morphology, structure co ....New Photocatalysts for CO2 Reduction. The project aims to develop novel photocatalysts for reducing carbon dioxide (CO2) to useful products using solar energy. Carbon dioxide (CO2) photoreduction is attracting growing attention because of its potential to mitigate CO2 emissions and convert the captured CO2 to chemical commodities. The project also plans to identify the photocatalytic mechanisms of the catalysts by investigating the reaction systems, such as the interface morphology, structure coherence and energy alignment of the component phases and reactant. Innovative technologies in the field of sunlight-driven photocatalysis have the potential to significantly reduce greenhouse gas emissions.Read moreRead less
Advanced chemical recycling of mixed plastics for monomer recovery. This project aims to develop innovative catalytic routes to the chemical recycling of mixed plastics for recovery of their molecular building blocks. Plastic pollution poses a significant threat to the Australian ecosystem. Efficient recycling technologies are urgently needed as Australia only recycles ~4% of its 3.4 million tons of mixed waste plastics. This project expects to design highly efficient catalysts for the stepwise ....Advanced chemical recycling of mixed plastics for monomer recovery. This project aims to develop innovative catalytic routes to the chemical recycling of mixed plastics for recovery of their molecular building blocks. Plastic pollution poses a significant threat to the Australian ecosystem. Efficient recycling technologies are urgently needed as Australia only recycles ~4% of its 3.4 million tons of mixed waste plastics. This project expects to design highly efficient catalysts for the stepwise breakdown of mixed polyolefin plastics into monomers for the subsequent manufacturing of virgin plastics in a circular economy, and to elucidate fundamental underpinning reaction mechanisms. Outcomes will stimulate the Australian waste plastic recycling industry, and minimise plastic accumulation in the environment.Read moreRead less
Nanostructured solid acid catalysts for sustainable chemical manufacturing. This project aims to develop next-generation solid acid catalysts for energy- and atom-efficient transformations of waste biomass and carbon dioxide to sustainable chemicals and fuels. Catalysis is a transformative technology, key to both life and lifestyle, contributing to 90% of chemical manufacturing processes and >20% of all industrial products, and will be a key enabler for the emerging Australian bioeconomy. The ex ....Nanostructured solid acid catalysts for sustainable chemical manufacturing. This project aims to develop next-generation solid acid catalysts for energy- and atom-efficient transformations of waste biomass and carbon dioxide to sustainable chemicals and fuels. Catalysis is a transformative technology, key to both life and lifestyle, contributing to 90% of chemical manufacturing processes and >20% of all industrial products, and will be a key enabler for the emerging Australian bioeconomy. The expected development of new high performance catalysts for the production of renewable transportation fuels and sustainable chemical feedstocks will underpin commercially viable low carbon technologies using waste resources, and should provide significant benefits to Australian science, industry, and the environment.
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