Cold catalysis for water splitting. This project aims to develop photocatalysts via AC magnetic field through nanoscale heating for efficient H2 generation. This project is to introduce cold catalysis concept, which heats catalysts only but not solution, thus called cold catalysis, in the area of production of renewable energy. Expected outcome is the creation of clean and low cost catalysts to effectively harvest the chemical energy from the sun via splitting of water into H2 and O2 without cau ....Cold catalysis for water splitting. This project aims to develop photocatalysts via AC magnetic field through nanoscale heating for efficient H2 generation. This project is to introduce cold catalysis concept, which heats catalysts only but not solution, thus called cold catalysis, in the area of production of renewable energy. Expected outcome is the creation of clean and low cost catalysts to effectively harvest the chemical energy from the sun via splitting of water into H2 and O2 without causing any environmental damage. This unique technology will also help to address clean energy generation, which is in line with H2 economy plan by Australia government, and provide opportunities for new industries that will benefit Australian economy.Read moreRead less
Integrated composite electrodes for electrochemical synthesis of ammonia. This project aims to develop multifunctional composite electrodes for electrochemical synthesis of ammonia from water, nitrogen gas and renewable energy under ambient conditions. Hydrophobic subnanometre water channels will be integrated with an electrocatalyst to control supply of water as vapour, thereby effectively minimising hydrogen evolution reaction and enabling high-efficiency ammonia synthesis. Expected outcomes i ....Integrated composite electrodes for electrochemical synthesis of ammonia. This project aims to develop multifunctional composite electrodes for electrochemical synthesis of ammonia from water, nitrogen gas and renewable energy under ambient conditions. Hydrophobic subnanometre water channels will be integrated with an electrocatalyst to control supply of water as vapour, thereby effectively minimising hydrogen evolution reaction and enabling high-efficiency ammonia synthesis. Expected outcomes include enhanced capacity in developing electrochemical reaction systems, and new fundamental knowledge of electrocatalyst design and reaction engineering. This should provide significant economic and environmental benefits by developing a sustainable manufacturing technology to transform the century-old ammonia industry.Read moreRead less
High Performance Anode for Direct Ammonia Solid Oxide Fuel Cells. Solid oxygen fuel cells are a clean energy generation device with very high energy efficiency and if with hydrogen as fuel, the emission is zero. However, the utilisation of hydrogen is limited by on-board storage. Ammonia is a promising hydrogen carrier and can be directly fed to solid oxide fuel cells without fuel storage problem, and the products are just hydrogen and nitrogen. For direct ammonia solid oxide fuel cells, the key ....High Performance Anode for Direct Ammonia Solid Oxide Fuel Cells. Solid oxygen fuel cells are a clean energy generation device with very high energy efficiency and if with hydrogen as fuel, the emission is zero. However, the utilisation of hydrogen is limited by on-board storage. Ammonia is a promising hydrogen carrier and can be directly fed to solid oxide fuel cells without fuel storage problem, and the products are just hydrogen and nitrogen. For direct ammonia solid oxide fuel cells, the key challenge is the anode. This project aims to develop a high performance anode for direct ammonia solid oxide fuel cells with both high activity and high stability at low temperature (below 600 degree C), thus addressing a key issue to make the direct ammonia solid oxide fuel cells commercially viable.Read moreRead less
Composites for thermal expansion matched oxygen electrodes. This project aims to develop high performance composite oxygen electrodes by using both negative thermal expansion materials and electrolyte materials to tailor the thermal expansion and activities of the perovskite-based electrodes for use in reduced temperature solid oxide cells. Such composite electrodes will show highly matched thermal expansion with electrolyte without sacrificing high activity at reduced temperatures. This project ....Composites for thermal expansion matched oxygen electrodes. This project aims to develop high performance composite oxygen electrodes by using both negative thermal expansion materials and electrolyte materials to tailor the thermal expansion and activities of the perovskite-based electrodes for use in reduced temperature solid oxide cells. Such composite electrodes will show highly matched thermal expansion with electrolyte without sacrificing high activity at reduced temperatures. This project seeks to address an important practical issue in the operation of solid oxide power cells - thermal expansion compatibility, which causes poor efficiency outside a narrow temperature band.Read moreRead less
Biochar as a renewable catalyst for hot gas cleaning. This project aims to generate new knowledge for the development of a novel hot gas cleaning technology. This project expects to understand the mechanisms of tar reforming using biochar as a renewable catalyst, which can avoid the problems associated with the catalyst deactivation and catalyst disposal if conventional supported catalysts are used. Expected outcomes of this project include a theoretical framework and a kinetic model describing ....Biochar as a renewable catalyst for hot gas cleaning. This project aims to generate new knowledge for the development of a novel hot gas cleaning technology. This project expects to understand the mechanisms of tar reforming using biochar as a renewable catalyst, which can avoid the problems associated with the catalyst deactivation and catalyst disposal if conventional supported catalysts are used. Expected outcomes of this project include a theoretical framework and a kinetic model describing the catalytic reforming of tar as part of the hot gas cleaning during the conversion of biomass. The technology will contribute to Australia’s improved energy security and reduced carbon dioxide (CO2) emissions in the carbon-constrained future.Read moreRead less
Catalytic Degardation of Emerging Microplastic Pollutants. This project aims to develop robust and low-cost nanocarbon hybrids and advanced remediation technology to address globally emerging microplastic contaminations. The project expects to boost innovations in development of novel magnetic nanomaterials, process of microplastic purification, and green catalysis. Expected outcomes of this project will include efficient strategies in materials fabrication and a cutting-edge nanotechnology. The ....Catalytic Degardation of Emerging Microplastic Pollutants. This project aims to develop robust and low-cost nanocarbon hybrids and advanced remediation technology to address globally emerging microplastic contaminations. The project expects to boost innovations in development of novel magnetic nanomaterials, process of microplastic purification, and green catalysis. Expected outcomes of this project will include efficient strategies in materials fabrication and a cutting-edge nanotechnology. The success of the project will underpin the scientific bases of carbocatalysis, provide significant benefits to the Australian industry and society for a sustainable future with clean water, and increase the leading capacity of Australia in fundamental research and frontier technology.Read moreRead less
Designing a photo-electro-catalysis system for selective organic oxidation. The research aims to establish new composite materials to enable realisation of next generation organic electrolysers for renewable hydrogen production. Water electrolysis is seen as the front-running technology in Australia's drive to be a renewable hydrogen exporter. Significant opportunity exists in adopting organic electrolysis as an alternative with additional benefits, including lower energy input and value-added c ....Designing a photo-electro-catalysis system for selective organic oxidation. The research aims to establish new composite materials to enable realisation of next generation organic electrolysers for renewable hydrogen production. Water electrolysis is seen as the front-running technology in Australia's drive to be a renewable hydrogen exporter. Significant opportunity exists in adopting organic electrolysis as an alternative with additional benefits, including lower energy input and value-added chemical production (alongside H2), off-setting costs. Challenges exist with controlling organic product selectivity and restricting carbon dioxide generation. The project intends to deliver a system which uses complementary phenomena (light activation, controllable polarity, magnetic response) to resolve said challenges. Read moreRead less
Catalytic conversion of Australia's natural gas to value added products. While natural gas (of which methane is the primary component) is an abundant source of energy, it is normally found in remote areas and for its successful exploitation it needs to be processed. The processing usually requires significant energy and resources input. In this project we will develop a fundamental understanding to a single step catalytic process that can utilise natural gas and nitrous oxide (both potent greenh ....Catalytic conversion of Australia's natural gas to value added products. While natural gas (of which methane is the primary component) is an abundant source of energy, it is normally found in remote areas and for its successful exploitation it needs to be processed. The processing usually requires significant energy and resources input. In this project we will develop a fundamental understanding to a single step catalytic process that can utilise natural gas and nitrous oxide (both potent greenhouse gases) and oxygen to produce selectively methanol and hydrocarbons from a natural gas feedstream in a controlled manner. A single step process for natural gas conversion utilising waste green-house gases is expected to be of great benefit to the Australian economy, environment and energy securityRead moreRead less
Controllable Synthesis of Defects in Catalysts for Electrocatalysis . This project aims to address the most critical issue of electrocatalysis: identification of active sites for carbon-based metal free catalysts (CMFCs). Through the development of new methodologies, this proposal will, for the first time, controllably synthesise the vacancy defects that are the major active sites for CMFCs. The expected outcomes from this project include in-depth understanding of the fundamentals of electrocata ....Controllable Synthesis of Defects in Catalysts for Electrocatalysis . This project aims to address the most critical issue of electrocatalysis: identification of active sites for carbon-based metal free catalysts (CMFCs). Through the development of new methodologies, this proposal will, for the first time, controllably synthesise the vacancy defects that are the major active sites for CMFCs. The expected outcomes from this project include in-depth understanding of the fundamentals of electrocatalysis: the reactivity of active sites and the catalytic performance with the number of active sites; which will not only significantly advance knowledge but also achieve breakthrough technologies that greatly benefit to the society and economy both for Australia and worldwide.Read moreRead less
Electrocatalytic Generation of Ammonia from Air and Water. The aim is to directly convert nitrogen under mild conditions, using renewable power, to form ammonia for fertilisers and fuels, enabled by new, nanostructured, electrocatalysts based on single-sheet and composite materials. Unlike nitrogen fixation using a three-electrode system, the project will use a novel mixed gas- and liquid-phase electrocatalytic nitrogen reduction two-electrode reactor. Based on fuel cells, it is designed to acce ....Electrocatalytic Generation of Ammonia from Air and Water. The aim is to directly convert nitrogen under mild conditions, using renewable power, to form ammonia for fertilisers and fuels, enabled by new, nanostructured, electrocatalysts based on single-sheet and composite materials. Unlike nitrogen fixation using a three-electrode system, the project will use a novel mixed gas- and liquid-phase electrocatalytic nitrogen reduction two-electrode reactor. Based on fuel cells, it is designed to accelerate the naturally sluggish nitrogen reduction reaction, NRR, significantly improving the reaction rate and selectivity. The project will also gain atomic-level understanding of the mechanism of NRR, based on in-situ spectroscopies used under operando conditions, e.g., Raman or X-ray absorption.Read moreRead less