Photochemical toolkit based on tetracyanoquinodimethane metal-organic semiconducting hybrids. This project aims to develop low-cost light-activated materials for flexible electronics, wearable sensors, antimicrobial fabrics and highly active catalysts. A photochemical toolkit will be developed comprising ultraviolet-active zinc oxide, visible-active metals and visible/infrared-active charge transfer semiconducting materials. Hybridisation of these components will create materials photoactive acr ....Photochemical toolkit based on tetracyanoquinodimethane metal-organic semiconducting hybrids. This project aims to develop low-cost light-activated materials for flexible electronics, wearable sensors, antimicrobial fabrics and highly active catalysts. A photochemical toolkit will be developed comprising ultraviolet-active zinc oxide, visible-active metals and visible/infrared-active charge transfer semiconducting materials. Hybridisation of these components will create materials photoactive across the solar spectrum, leading to photo-redox catalysis and light-activated antimicrobial applications. These materials are expected to lead to cost-effective industrial processes, efficient environmental monitoring, clean-up of industrially-contaminated water streams, infection control in wounds and healthcare settings, and advancing consumer technology platforms.Read moreRead less
Nanoconfined ionic liquids for electrochemical reduction of carbon dioxide. This project aims to develop ionic liquid-based nanoporous composite catalysts for efficient electrochemical reduction of carbon dioxide into value-added chemicals and fuels using electricity generated from renewable sources. Novel nanoporous catalysts will be constructed and impregnated with a secondary phase of task-specific ionic liquids to promote carbon dioxide reduction. An expected outcome of the project is an und ....Nanoconfined ionic liquids for electrochemical reduction of carbon dioxide. This project aims to develop ionic liquid-based nanoporous composite catalysts for efficient electrochemical reduction of carbon dioxide into value-added chemicals and fuels using electricity generated from renewable sources. Novel nanoporous catalysts will be constructed and impregnated with a secondary phase of task-specific ionic liquids to promote carbon dioxide reduction. An expected outcome of the project is an understanding of the fundamental physicochemical and electrochemical behaviour of the nanoconfined ionic liquid/catalyst interfaces which will allow optimisation and enhancement of their properties. This project is expected to contribute to clean energy and sustainable environments.Read moreRead less
Three-dimensional, precious-metal-free electrolysis of water. The project plans to develop an efficient water electrolyser prototype made of nonprecious materials. The recent breakthrough in developing cost-effective catalysts for water electrolysis has opened enormous opportunities for large-scale production of hydrogen fuels and storage of electricity generated from clean energy sources such as solar and wind. This project aims to develop a new generation of three-dimensional, nanostructured e ....Three-dimensional, precious-metal-free electrolysis of water. The project plans to develop an efficient water electrolyser prototype made of nonprecious materials. The recent breakthrough in developing cost-effective catalysts for water electrolysis has opened enormous opportunities for large-scale production of hydrogen fuels and storage of electricity generated from clean energy sources such as solar and wind. This project aims to develop a new generation of three-dimensional, nanostructured electrodes made of nonprecious metals for water electrolysis, which match or outperform the benchmark electrodes based on precious metals. In making these electrodes, the project plans to explore the fundamental behaviours of hierarchical nanoporous electrode architectures and discover new catalyst materials.Read moreRead less
Pioneering stable copper carbanions for new C-C bond forming paradigms. The stabilisation of highly reactive carbanions underpins advances in chemical synthesis of new compounds including polymers, agrichemicals and pharmaceuticals. This project aims to deliver an innovative chemical reactivity platform, underpinned by copper carbanion complexes accessed via synthetic electrochemistry. Carbanions are essential components of carbon-carbon bond forming reactions but their high reactivity can be pr ....Pioneering stable copper carbanions for new C-C bond forming paradigms. The stabilisation of highly reactive carbanions underpins advances in chemical synthesis of new compounds including polymers, agrichemicals and pharmaceuticals. This project aims to deliver an innovative chemical reactivity platform, underpinned by copper carbanion complexes accessed via synthetic electrochemistry. Carbanions are essential components of carbon-carbon bond forming reactions but their high reactivity can be problematic. Expected outcomes of this project are an understanding of why these novel copper compounds are stable and how they can be utilised as synthetic reagents. This should provide significant benefits in unlocking the synthetic potential of a new class of chemical compound that has until now remained unexplored.Read moreRead less
Nanoscale liquid interfaces: properties and molecular sensitivity. Challenges facing society in health and environment need new molecular measurements that are accurate, sensitive and fast. By use of nanoscale oil-water junctions, the project will develop new chemical and biological sensors that hold great promise for solving molecular measurement problems, including the ability to detect single molecules.
Discovery Early Career Researcher Award - Grant ID: DE220101577
Funder
Australian Research Council
Funding Amount
$446,639.00
Summary
Two-Dimensional Covalent Organic Framework for Next-Generation Batteries. This project aims to develop advanced two-dimensional (2D) covalent organic framework (COF) materials for sodium and potassium-ion batteries. It expects to generate a new family of few-layered 2D COF materials and their 2D-2D heterostructured composites with improved electrochemical properties, and develop processing technologies and fundamental understanding of COF-based electrodes for flexible sodium and potassium-ion ba ....Two-Dimensional Covalent Organic Framework for Next-Generation Batteries. This project aims to develop advanced two-dimensional (2D) covalent organic framework (COF) materials for sodium and potassium-ion batteries. It expects to generate a new family of few-layered 2D COF materials and their 2D-2D heterostructured composites with improved electrochemical properties, and develop processing technologies and fundamental understanding of COF-based electrodes for flexible sodium and potassium-ion batteries. Expected outcomes include novel materials, technologies, and energy-storage options for Australia. Significant economic and environmental benefits are expected from developing advanced sodium and potassium-ion batteries with low cost, high energy density, and improved safety for renewable energy storage.Read moreRead less
Miniaturised Ionic Liquid Systems: Design, Electrochemistry and Application. The project aims to develop a new generation of miniature electrochemical devices based on ionic liquids, salts that are liquid at room temperature. In making these devices the project will study the fundamental physicochemical and electrochemical behaviour of the ionic liquid microinterfaces formed, and this will allow optimisation and enhancement of their properties. A gas sensor made of a micro-pattern of ionic liqui ....Miniaturised Ionic Liquid Systems: Design, Electrochemistry and Application. The project aims to develop a new generation of miniature electrochemical devices based on ionic liquids, salts that are liquid at room temperature. In making these devices the project will study the fundamental physicochemical and electrochemical behaviour of the ionic liquid microinterfaces formed, and this will allow optimisation and enhancement of their properties. A gas sensor made of a micro-pattern of ionic liquid drops will be designed to detect gaseous toxic amines, which are released from numerous anthropogenic sources including waste water, sewage treatment, farms and industry. These sensors will be small, specific to the target gas, sensitive, fast in response and portable.Read moreRead less
Nanoporous nanorods with improved electrochemical properties. This project applies the latest nanotechnology to produce new nanomaterials for energy storage applications. The aim is to significantly improve supercapacitor performance for use in the storage of clean energy and harvesting of wasted energy which will contribute to a clean energy economy.
On-water electrochemistry: redox catalysis at the water surface. From plastics to pharamaceuticals, chemists rely extensively on expensive and environmentally damaging solvents and reactants. In water, greener and cheaper electricity-driven reactions currently suffer from low velocity and poor selectivity. The project aims to develop the science of on-water electrochemistry, to make electricity-driven organic reactions in water viable. Demonstrating that for electrochemical reactions, rates and ....On-water electrochemistry: redox catalysis at the water surface. From plastics to pharamaceuticals, chemists rely extensively on expensive and environmentally damaging solvents and reactants. In water, greener and cheaper electricity-driven reactions currently suffer from low velocity and poor selectivity. The project aims to develop the science of on-water electrochemistry, to make electricity-driven organic reactions in water viable. Demonstrating that for electrochemical reactions, rates and selectivities increase on water’s surface rather than in its bulk will remove fundamental constraints on the viability of aqueous electro-synthesis – moving beyond current reactor designs to transform our view of electrochemistry and improve the sustainability of the chemical industry.Read moreRead less
Discovery Early Career Researcher Award - Grant ID: DE130101168
Funder
Australian Research Council
Funding Amount
$364,900.00
Summary
Enhancement of light-driven electricity generation by cyanobacteria: en route to biosolar panels. Some species of naturally occurring cyanobacteria (blue-green algae) exhibit a special metabolic feature, which enables them to convert sunlight into electricity. This project will unveil the chemical and biological secrets behind this process and will lead to the creation of the first entirely biological solar panel.