Discovery Early Career Researcher Award - Grant ID: DE150101306
Funder
Australian Research Council
Funding Amount
$365,000.00
Summary
Porous Metal Phosphonate Ion Exchange Membranes for Redox Flow Batteries. The high-performance storage and utilisation of renewable energy, such as solar and wind energy, will provide a direct response to Australia's energy and climate issues. This project aims to develop porous metal phosphonate ion exchange membranes, which can be used in the redox flow battery, one of the most powerful, large-scale energy storage devices, with large capacity, high efficiency, long life and low cost. The proje ....Porous Metal Phosphonate Ion Exchange Membranes for Redox Flow Batteries. The high-performance storage and utilisation of renewable energy, such as solar and wind energy, will provide a direct response to Australia's energy and climate issues. This project aims to develop porous metal phosphonate ion exchange membranes, which can be used in the redox flow battery, one of the most powerful, large-scale energy storage devices, with large capacity, high efficiency, long life and low cost. The project aims to improve the overall performance and fabrication of redox flow batteries, promote capacity and efficiency, and reduce the cost of renewable energy storage thereby benefiting the Australian economy and environment.Read moreRead less
Mapping new cathode materials for aqueous rechargeable batteries: The mechanism of intercalation of lithium in aqueous solutions. This technology could power electric vehicles of the future. With the aid of using advanced oxide and phosphate materials for an aqueous battery, the project will establish a widespread use of green energy for national benefit. This will help us to reduce the current emission observed in transport and energy conversion. The project will facilitate an understanding the ....Mapping new cathode materials for aqueous rechargeable batteries: The mechanism of intercalation of lithium in aqueous solutions. This technology could power electric vehicles of the future. With the aid of using advanced oxide and phosphate materials for an aqueous battery, the project will establish a widespread use of green energy for national benefit. This will help us to reduce the current emission observed in transport and energy conversion. The project will facilitate an understanding the electrochemical energy storage technology. The challenging and significant results from this project will contribute to the energy industries to build non-pollutant high energy storage equipments and productivity of Australia's research and development.Read moreRead less
Energy transforming polymers: from single molecules to devices. Climate control and the rapidly increasing demand for energy is driving the search for alternative sustainable energy sources. Flexible plastics will be a primary component of the new generation of solar harvesting and energy conversion materials. The objective of this project is to gain an understanding of the way polymers interact with light and can convert absorbed solar energy into electrical power and other useful forms of ene ....Energy transforming polymers: from single molecules to devices. Climate control and the rapidly increasing demand for energy is driving the search for alternative sustainable energy sources. Flexible plastics will be a primary component of the new generation of solar harvesting and energy conversion materials. The objective of this project is to gain an understanding of the way polymers interact with light and can convert absorbed solar energy into electrical power and other useful forms of energy. The outcomes of the project will allow the improved design of plastics for applications in solar energy conversion.Read moreRead less
Polyoxometalate Clusters: Catalytic Chemistry in Solution and Condensed States. Polyoxometalate cluster anions are soluble metal-oxygen clusters that are cheap, robust and non-toxic.
Conditions for systematic tuning of redox potentials over the range +2 to -3 V have become accessible via certain photo-active polyoxometalates. The same system can provide powerful oxidants (that rival chlorine) and powerful reductants (that rival potassium).
The program will take advantage of this unique ....Polyoxometalate Clusters: Catalytic Chemistry in Solution and Condensed States. Polyoxometalate cluster anions are soluble metal-oxygen clusters that are cheap, robust and non-toxic.
Conditions for systematic tuning of redox potentials over the range +2 to -3 V have become accessible via certain photo-active polyoxometalates. The same system can provide powerful oxidants (that rival chlorine) and powerful reductants (that rival potassium).
The program will take advantage of this unique range of properties to explore:-
(i) coupling of photo- and electro-chemical processes into effective catalytic cycles;
(ii) photo- and electro-chemical processes in ionic liquid solvents;
(iii) synthesis and redox reactivity of nanoparticles stabilised by polyoxometalates.
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Development of Nanocrystalline Transition Metal Oxide and Polymer-Transition Metal Oxide Composite Materials for Rechargeable Lithium Battery Applications. Recent work by the applicants has shown that nanocrystalline titanates and aluminates hold considerable promise as lithium battery electrodes. Nanocrystalline anatase materials showed considerably greater lithium intercalation ratios compared with their microcrystalline counterparts, and doping with vanadium showed further improvements in ....Development of Nanocrystalline Transition Metal Oxide and Polymer-Transition Metal Oxide Composite Materials for Rechargeable Lithium Battery Applications. Recent work by the applicants has shown that nanocrystalline titanates and aluminates hold considerable promise as lithium battery electrodes. Nanocrystalline anatase materials showed considerably greater lithium intercalation ratios compared with their microcrystalline counterparts, and doping with vanadium showed further improvements in capacity. Sol-gel synthesised V-doped anatase materials produced an initial discharge capacity of 428 Ah/kg compared with only 280 mAh/kg for the undoped anatase electrode in the same Li test cell.In this project different dopants and preparation conditions will be investigated to produce nanocrystalline rutile and aluminate materials as potential candidates for high capacity lithium battery applications.Read moreRead less
Synthesis of Unique Mesoporous Graphitic Carbons and their Application to Fundamental Problems in Adsorption Science. The development of synthesis techniques to create porous graphitic carbons with highly ordered pore structures, easily accessible pore volume and good electrical conductivity can underpin technological advancements in many industrial applications such as energy storage, removal of pollutants from exhaust streams, direct-methanol fuel cells and lithium ion batteries. Techniques de ....Synthesis of Unique Mesoporous Graphitic Carbons and their Application to Fundamental Problems in Adsorption Science. The development of synthesis techniques to create porous graphitic carbons with highly ordered pore structures, easily accessible pore volume and good electrical conductivity can underpin technological advancements in many industrial applications such as energy storage, removal of pollutants from exhaust streams, direct-methanol fuel cells and lithium ion batteries. Techniques developed in this project are also applicable to creating other materials important to advanced sensors and optoelectronics. The fundamental study of water adsorption and hysteresis using these carbons will help us create better models for adsorption. This will underpin theoretical studies, characterisation and optimisation of carbon materials into the future. Read moreRead less
Linkage Infrastructure, Equipment And Facilities - Grant ID: LE130100158
Funder
Australian Research Council
Funding Amount
$200,000.00
Summary
Supercontinuum fibre laser consortium for the chemical and materials sciences. A supercontinuum fibre laser facility will be established across nodes at The University of Adelaide and The University of Melbourne, and used to probe the chemical basis of photosynthesis, explore the properties of organic solar cell materials and biomaterials, develop efficient metal catalysts, and detect metal vapours in gases.
Future electrochemical energy storage technologies. New rechargeable batteries will be developed through the use of breakthrough electrolytes based on liquid salts. These batteries are vital for the widespread use of renewables in Australia's electricity grid. They will also enable new generations of environmental sensor technology.
TAILORING OF CARBON MATERIALS FOR USE IN DIRECT CARBON FUEL CELLS. This project aims to develop a fundamental understanding of and methods for tailoring carbon materials to be used in high efficiency (80-85%) direct carbon fuel cells (DCFC). This project addresses an important area in clean and efficient energy supply to meet the World's long-term energy and environmental requirements. Specifically, we aim to focus on the carbon particulates based on carbon black materials with a turbostratic st ....TAILORING OF CARBON MATERIALS FOR USE IN DIRECT CARBON FUEL CELLS. This project aims to develop a fundamental understanding of and methods for tailoring carbon materials to be used in high efficiency (80-85%) direct carbon fuel cells (DCFC). This project addresses an important area in clean and efficient energy supply to meet the World's long-term energy and environmental requirements. Specifically, we aim to focus on the carbon particulates based on carbon black materials with a turbostratic structure, and to investigate the relationship between the microstructures of synthetic carbon black materials and their efficacy in DCFC systems. Ultimately, we aim to engineer novel carbon particulates for use in DCFCs.Read moreRead less
Charge storage mechanism and transport behaviour in nanoporous carbons: implications on developing next-generation electric double-layer capacitors. This project aims to investigate the charge storage mechanism and ion transport behaviours in nanoporous carbons of different pore geometries. Such understandings will have profound implications on designing innovative electrode materials with tailored pore structure for new-generation electric double-layer capacitors.