Janus particles and nanorattles: new materials for paint technology. This project will pave the way for self cleaning paints that achieve opacity with greatly reduced titanium dioxide levels. Painted surfaces will maintain their clean and new look for longer and a clean town look will be much more readily maintained. More efficient use of titanium dioxide will reduce the need for sand mining and reduce the cost of quality paint.
Polymer micro-capsules for stain-resistant paint. This project aims to create an advanced micro-capsule system to be used in the manufacturing of high-performance waterborne paints on a large scale. Surface coatings seal, strengthen, and decorate the majority of surfaces in the building industry. Despite their importance, advances in paint science have only been incremental and a truly stain-resistant, robust and environmentally friendly coating has yet to be developed. This project will use pol ....Polymer micro-capsules for stain-resistant paint. This project aims to create an advanced micro-capsule system to be used in the manufacturing of high-performance waterborne paints on a large scale. Surface coatings seal, strengthen, and decorate the majority of surfaces in the building industry. Despite their importance, advances in paint science have only been incremental and a truly stain-resistant, robust and environmentally friendly coating has yet to be developed. This project will use polymer Janus nanoparticles to radically redesign architectural coatings, with the goal to reduce the use of non-renewable components, and increase stain-resistance and durability. This new technology will lead to less disruption for the environment, and important economic and technological benefits for Australia.Read moreRead less
Key Functional Additives in Paint Technology. The goal of this project is to create two novel advanced particle systems with complex architecture that can be manufactured on a large scale, which aim to lead to high-performance waterborne paints. It is intended that these paints will have three functional characteristics: provide more efficient use of titanium dioxide; display pronounced water-resistance; and contribute to removing the need for organic solvents from the gloss paint sector. This r ....Key Functional Additives in Paint Technology. The goal of this project is to create two novel advanced particle systems with complex architecture that can be manufactured on a large scale, which aim to lead to high-performance waterborne paints. It is intended that these paints will have three functional characteristics: provide more efficient use of titanium dioxide; display pronounced water-resistance; and contribute to removing the need for organic solvents from the gloss paint sector. This research aims to provide the means to create paint films with greatly improved properties at reduced cost, with reduced requirement for non-renewable resources and reduced environmental footprint.Read moreRead less
Vesicles stabilised by compressed carbon dioxide as nanoreactors and templates for radical polymerisation. A new environmentally friendly method for synthesis of surfactant vesicles involving stabilisation using low pressure carbon dioxide will be applied to the synthesis of hollow polymeric nanoparticles and polymer of well-defined structure. The resulting polymeric structures will have applications in drug delivery and nano-engineered materials.
Linkage Infrastructure, Equipment And Facilities - Grant ID: LE0347258
Funder
Australian Research Council
Funding Amount
$170,000.00
Summary
Polymer Analysis Facility. The aim of this application is to establish a facility for polymer analysis. The infra-red spectrometer will be used primarily for analysis of polymerisation reactions whilst the thermal analysis equipment is essential for the characterisation of polymers and thin polymer coatings. The facility will contribute an essential analysis capability for three strong research groups who work in different aspects of polymer science. The main outcomes will improved productivity ....Polymer Analysis Facility. The aim of this application is to establish a facility for polymer analysis. The infra-red spectrometer will be used primarily for analysis of polymerisation reactions whilst the thermal analysis equipment is essential for the characterisation of polymers and thin polymer coatings. The facility will contribute an essential analysis capability for three strong research groups who work in different aspects of polymer science. The main outcomes will improved productivity within the current projects together with new collaborations, particularly between the Steel Institute (ISPP) at Wollongong and the Centre of Advanced Molecular Design (CAMD) at UNSW.Read moreRead less
Polymer nanoparticles with gradient morphology for environmentally friendly aqueous coatings applications. The commercial and practical importance of coatings (paints) in today’s society can hardly be overstated. With the ongoing drive towards more environmentally friendly coating systems, there is a strong desire to replace traditionally employed solvent-based coatings with entirely waterborne systems. Waterborne coatings are a key measure by which the coating industry can meet requirements to ....Polymer nanoparticles with gradient morphology for environmentally friendly aqueous coatings applications. The commercial and practical importance of coatings (paints) in today’s society can hardly be overstated. With the ongoing drive towards more environmentally friendly coating systems, there is a strong desire to replace traditionally employed solvent-based coatings with entirely waterborne systems. Waterborne coatings are a key measure by which the coating industry can meet requirements to reduce emission of volatile organic compounds. However, maximum performance cannot be achieved currently using waterborne coatings, which in turn limits applications. The overall aim of this project is to develop environmentally friendly high-performance waterborne coatings that will enable replacement of currently employed solvent-based systems.Read moreRead less
Controlled/living radical polymerization in environmentally friendly miniemulsions induced by compressed carbon dioxide for synthesis of nanoparticles and well-defined polymer. Controlled/living radical polymerization is a technique for precise synthesis of polymer by radical polymerization, which has revolutionized polymer synthesis in terms of accessible polymer structures. However, controlled/living radical polymerization has yet to gain a strong foothold in industry mainly due to problems as ....Controlled/living radical polymerization in environmentally friendly miniemulsions induced by compressed carbon dioxide for synthesis of nanoparticles and well-defined polymer. Controlled/living radical polymerization is a technique for precise synthesis of polymer by radical polymerization, which has revolutionized polymer synthesis in terms of accessible polymer structures. However, controlled/living radical polymerization has yet to gain a strong foothold in industry mainly due to problems associated with its implementation in (aqueous) dispersed systems. The present Proposal addresses this key challenge by a novel environmentally friendly and versatile method for aqueous miniemulsion preparation by use of compressed carbon dioxide. Controlled/living radical polymerization in dispersed systems generates polymeric nanoparticles, which are of importance in many advanced and emerging technologies.Read moreRead less
Polymers for Novel Surfactants. The aim of the proposed research is to develop novel surface-active polymers with complex architectures and more efficient strategies for the synthesis of surface-active polymers in general. We will exploit the polymerization characteristics of the novel catalytic chain transfer and radical addition-fragmentation transfer polymerization techniques to achieve polymerization control that has been virtually impossible hitherto. The proposed research will thus make ....Polymers for Novel Surfactants. The aim of the proposed research is to develop novel surface-active polymers with complex architectures and more efficient strategies for the synthesis of surface-active polymers in general. We will exploit the polymerization characteristics of the novel catalytic chain transfer and radical addition-fragmentation transfer polymerization techniques to achieve polymerization control that has been virtually impossible hitherto. The proposed research will thus make accessible a wide range of novel surface-active polymers that have been impossible to synthesise to date, and which we expect to be more efficient and hence leads to greener technologies.
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Linkage Infrastructure, Equipment And Facilities - Grant ID: LE0453637
Funder
Australian Research Council
Funding Amount
$256,804.00
Summary
Multi-dimensional polymer characterization facility. The microstructure of polymers dominates their physical properties. This integrated facility will create a world-leading means of characterizing in multiple dimensions the microstructure of complex polymers, eg copolymers and branched polymers. The facility will yield information on the distributions of chain end-groups, monomer microstructure, and branches, as functions of molecular weight. The facility will provide otherwise unobtainable dat ....Multi-dimensional polymer characterization facility. The microstructure of polymers dominates their physical properties. This integrated facility will create a world-leading means of characterizing in multiple dimensions the microstructure of complex polymers, eg copolymers and branched polymers. The facility will yield information on the distributions of chain end-groups, monomer microstructure, and branches, as functions of molecular weight. The facility will provide otherwise unobtainable data for a set of projects exploring questions ranging from how new synthetic materials with tailor-made properties can be created, through to how our understanding of natural polymers can be advanced to improve crop utilization.Read moreRead less
Novel Complex Architecture Polymers via a Combination of RAFT Chemistry and Pericyclic Reactions: Synthesis and Characterization. The project aims at advancing the synthetic limits and broadening the synthetic scope of living free radical polymerization and thus enhancing the library of polymer structures available for applications ranging from drug delivery to opto-electronics. Current material design for these applications is yet to reach its full potential through innovative synthetic approac ....Novel Complex Architecture Polymers via a Combination of RAFT Chemistry and Pericyclic Reactions: Synthesis and Characterization. The project aims at advancing the synthetic limits and broadening the synthetic scope of living free radical polymerization and thus enhancing the library of polymer structures available for applications ranging from drug delivery to opto-electronics. Current material design for these applications is yet to reach its full potential through innovative synthetic approaches. The proposal critically underpins and further advances Australia's leading position in both breakthrough science as well as advanced materials. Due to its significant scientific breadth and large coverage of both synthetic and physical aspects of polymer science, the project also provides a significant platform for research training at both honours and PhD level.Read moreRead less