Controllable Synthesis of Defects in Catalysts for Electrocatalysis . This project aims to address the most critical issue of electrocatalysis: identification of active sites for carbon-based metal free catalysts (CMFCs). Through the development of new methodologies, this proposal will, for the first time, controllably synthesise the vacancy defects that are the major active sites for CMFCs. The expected outcomes from this project include in-depth understanding of the fundamentals of electrocata ....Controllable Synthesis of Defects in Catalysts for Electrocatalysis . This project aims to address the most critical issue of electrocatalysis: identification of active sites for carbon-based metal free catalysts (CMFCs). Through the development of new methodologies, this proposal will, for the first time, controllably synthesise the vacancy defects that are the major active sites for CMFCs. The expected outcomes from this project include in-depth understanding of the fundamentals of electrocatalysis: the reactivity of active sites and the catalytic performance with the number of active sites; which will not only significantly advance knowledge but also achieve breakthrough technologies that greatly benefit to the society and economy both for Australia and worldwide.Read moreRead less
Targeted synthesis of porous materials towards gas sorption and separation. Targeted synthesis, using a building block strategy and computational design, is an efficient method for controlled synthesis of porous materials. This project uses this method to synthesise porous materials with permanent functional pores for separating and storing fuels and greenhouse gases, addressing demanding energy and environmental problems.
Improving solar energy utilisation by splitting water with visible light. The project seeks to improve solar-hydrogen fuel production via water splitting by addressing a fundamental scientific roadblock. By engineered nanostructures with controlled charge transfer abilities, the most desirable route to water splitting will be promoted; granting Australia an opportunity to develop a solar-based renewable fuel.
All-Metal Nanoporous Materials as Highly Active Electrocatalysts. This project aims to create new avenues for well-controlled large-scale synthesis of hierarchical nanoporous platinum-based architectures, and develop applications for the resultant new electrocatalysts. Developing novel high-performance, low-cost, and long-life electrode catalysts can improve the efficiency, cost, and durability of energy conversion technology. The project plans to use the unique properties of well-defined nanoar ....All-Metal Nanoporous Materials as Highly Active Electrocatalysts. This project aims to create new avenues for well-controlled large-scale synthesis of hierarchical nanoporous platinum-based architectures, and develop applications for the resultant new electrocatalysts. Developing novel high-performance, low-cost, and long-life electrode catalysts can improve the efficiency, cost, and durability of energy conversion technology. The project plans to use the unique properties of well-defined nanoarchitectures to reduce platinum content and to improve electrocatalytic performance. Nanoporous systems in electrocatalysts can provide more active sites and effective surface permeability, which should enhance catalytic activity. Project outcomes may also contribute to our understanding of the relationships among morphologies, pore structures, surface atomic structures and catalytic activities to guide the development of other kinds of high performance nanoporous catalysts.Read moreRead less
New high performance zinc bromine batteries with novel electrode/electrolyte systems. Renewable sources of energy are of particular interest in the era of diminishing fossil fuels. Efficient energy storage is a missing link for renewable energy. Zinc-bromine batteries have great potential as energy storage. This project will aim to fundamentally re-design the existing first generation systems to improve power density by 300-400 per cent.
Efficient ionic liquid-based reduction of nitrogen to ammonia. This project aims to develop a hybrid ionic liquid-nanostructured electrode platform to electrochemically convert nitrogen gas to ammonia. Ammonia production, mostly for fertilisers, consumes more than 1% of the global energy supply and contributes 1.6 % of global carbon dioxide emissions. A process that could convert nitrogen to ammonia using renewable energy would be an important alternative approach. This project will develop a pl ....Efficient ionic liquid-based reduction of nitrogen to ammonia. This project aims to develop a hybrid ionic liquid-nanostructured electrode platform to electrochemically convert nitrogen gas to ammonia. Ammonia production, mostly for fertilisers, consumes more than 1% of the global energy supply and contributes 1.6 % of global carbon dioxide emissions. A process that could convert nitrogen to ammonia using renewable energy would be an important alternative approach. This project will develop a platform for electrochemical conversion of nitrogen gas to ammonia and optimise it for use with surplus renewable energy supplies. The project is expected to contribute to mitigation of greenhouse emissions and create a technology for distributed production of ammonia and ammonium fertilisers.Read moreRead less
Advanced framework materials for hydrogen storage applications. This project aims to develop new molecular materials capable of the highly efficient storage of hydrogen gas. Through an innovative interdisciplinary approach that targets the synthesis and detailed characterisation of two classes of molecular material this project expects to generate step-change advances in the understanding of how hydrogen gas uptake relates to the chemical and physical attributes of porous molecular systems. Sign ....Advanced framework materials for hydrogen storage applications. This project aims to develop new molecular materials capable of the highly efficient storage of hydrogen gas. Through an innovative interdisciplinary approach that targets the synthesis and detailed characterisation of two classes of molecular material this project expects to generate step-change advances in the understanding of how hydrogen gas uptake relates to the chemical and physical attributes of porous molecular systems. Significant anticipated outcomes and benefits include the development of new material design approaches that optimise performance across a diverse parameter space, and the generation of advanced new materials worthy of commercial development, spanning small scale mobile to large scale stationary storage applications.Read moreRead less
Advanced separators for lithium-sulphur batteries. This project aims to develop new membranes for use as separators in lithium-sulphur batteries. Currently diffusion of polysulphides within these batteries reduces battery power and lifetime. The new membranes are intended to block polysulphide diffusion over an extended lifetime, while transporting the other ions needed for the battery to function. The project is expected to generate new membrane materials and further knowledge about the design, ....Advanced separators for lithium-sulphur batteries. This project aims to develop new membranes for use as separators in lithium-sulphur batteries. Currently diffusion of polysulphides within these batteries reduces battery power and lifetime. The new membranes are intended to block polysulphide diffusion over an extended lifetime, while transporting the other ions needed for the battery to function. The project is expected to generate new membrane materials and further knowledge about the design, synthesis and larger-scale production of membranes for electrochemical applications. This project will provide significant benefits by producing potentially lighter, longer-lasting and cheaper batteries than existing lithium-ion technologies, with the potential to accelerate the adoption of electric cars.Read moreRead less
Multifunctional 2D materials for sustainable energy applications. This project seeks to explore the great potential of novel graphene-like two dimensional (2-D) materials for energy applications. 2-D materials, which possess atomic or molecular thickness and infinite planar lengths, are regarded as a building block for many applications due to their unique nanostructures, electronic and mechanical properties. This project is focused on the design and exploration of layered two-dimensional artifi ....Multifunctional 2D materials for sustainable energy applications. This project seeks to explore the great potential of novel graphene-like two dimensional (2-D) materials for energy applications. 2-D materials, which possess atomic or molecular thickness and infinite planar lengths, are regarded as a building block for many applications due to their unique nanostructures, electronic and mechanical properties. This project is focused on the design and exploration of layered two-dimensional artificial graphene and graphene analogues with ‘on-demand’ properties to exploit advanced energy applications. There is now a pressing need to integrate graphene sheets into multidimensional and multifunctional systems with spatially well-defined configurations, and integrated systems with a controllable structure and predictable performance. Project outcomes may lead to next-generation devices in energy storage and other applications.Read moreRead less
Black titanium dioxide-graphene nanoleaves drive solid-gas selective carbon dioxide to solar fuels. This project aims to remove carbon dioxide from the atmosphere as part of a reaction to produce a carbon-neutral solar fuel. People are currently still over reliant on fossil fuels for energy production, which leads to increased greenhouse gases and their detrimental climate effect. This project will develop novel wireless sustainable nano-reactors, which can be scaled to a system working in an am ....Black titanium dioxide-graphene nanoleaves drive solid-gas selective carbon dioxide to solar fuels. This project aims to remove carbon dioxide from the atmosphere as part of a reaction to produce a carbon-neutral solar fuel. People are currently still over reliant on fossil fuels for energy production, which leads to increased greenhouse gases and their detrimental climate effect. This project will develop novel wireless sustainable nano-reactors, which can be scaled to a system working in an ambient environment for high-yield production. The expected outcomes are to synthesise nano-flowers composed of 2D functional nano-leaves, which will be fabricated into a flexible large-area carbon dioxide-to-solar fuel system. This project will also expand knowledge in heterojunctions, surface chemistry and nano-manufacturing of 2D materials. The technology to be developed will only rely on natural solar, atmospheric, and earth-abundant eco-friendly resources, and intends to promote Australia as a key regional solar fuels production and export nation.Read moreRead less