All-solid-state Z-scheme photocatalysts for water treatment. The project aims to develop high-performance Z-scheme photocatalysts by using two-dimensional (2D) semiconductors as building blocks for low-cost, highly-efficient pathogen inactivation and emerging pollutant degradation in stormwater treatment. The project expects to generate new fundamental knowledge in the area of photocatalyst design and Z-scheme photocatalytic system, and advance the application of photocatalytic oxidation in wate ....All-solid-state Z-scheme photocatalysts for water treatment. The project aims to develop high-performance Z-scheme photocatalysts by using two-dimensional (2D) semiconductors as building blocks for low-cost, highly-efficient pathogen inactivation and emerging pollutant degradation in stormwater treatment. The project expects to generate new fundamental knowledge in the area of photocatalyst design and Z-scheme photocatalytic system, and advance the application of photocatalytic oxidation in water treatment. The expected outcomes of the project include novel 2D Z-scheme photocatalysts and enhanced capacity in stormwater management.Read moreRead less
Special Research Initiatives - Grant ID: SR180100023
Funder
Australian Research Council
Funding Amount
$940,000.00
Summary
Thermal decomposition of PFAS. This project aims to investigate the thermal decomposition of per- and poly-fluroalkyl substances (PFAS). The project will focus on the catalytic destruction of PFAS reactions at elevated temperatures, which is expected to transform PFAS in a controlled and predictable way into benign products. By understanding the fate of these compounds during thermal decomposition, the project will allow the development of a new technology aimed at treating materials which have ....Thermal decomposition of PFAS. This project aims to investigate the thermal decomposition of per- and poly-fluroalkyl substances (PFAS). The project will focus on the catalytic destruction of PFAS reactions at elevated temperatures, which is expected to transform PFAS in a controlled and predictable way into benign products. By understanding the fate of these compounds during thermal decomposition, the project will allow the development of a new technology aimed at treating materials which have been contaminated with or have been used as absorbants for PFAS. The project will provide the technical underpinning of a new technology developed to treat fluorochemical-contaminated material and, in doing so, reduce the environmental impact of these contaminants.Read moreRead less
Tailoring metal-organic framework catalysts for carbon dioxide conversion. Reducing the greenhouse gas, CO2, into valuable fuels would be beneficial for relieving energy shortage and improving global sustainability. This project aims to synthesise high-performance heterogeneous catalysts for CO2 conversion by periodic ordering photo-redox metalloligand and thermal-catalytically active metal oxide clusters in metal-organic frameworks (MOFs). This approach is expected to deliver a unique single-si ....Tailoring metal-organic framework catalysts for carbon dioxide conversion. Reducing the greenhouse gas, CO2, into valuable fuels would be beneficial for relieving energy shortage and improving global sustainability. This project aims to synthesise high-performance heterogeneous catalysts for CO2 conversion by periodic ordering photo-redox metalloligand and thermal-catalytically active metal oxide clusters in metal-organic frameworks (MOFs). This approach is expected to deliver a unique single-site metal-organic framework catalyst with high reaction-activity and chemo-selectivity in converting CO2 into valuable chemicals. This advancement will provide significant benefits for Australia’s emerging chemical manufacturing industry, and ultimately leading to a carbon-neutral energy economy and environment.Read moreRead less
Catalytic conversion of Australia's natural gas to value added products. While natural gas (of which methane is the primary component) is an abundant source of energy, it is normally found in remote areas and for its successful exploitation it needs to be processed. The processing usually requires significant energy and resources input. In this project we will develop a fundamental understanding to a single step catalytic process that can utilise natural gas and nitrous oxide (both potent greenh ....Catalytic conversion of Australia's natural gas to value added products. While natural gas (of which methane is the primary component) is an abundant source of energy, it is normally found in remote areas and for its successful exploitation it needs to be processed. The processing usually requires significant energy and resources input. In this project we will develop a fundamental understanding to a single step catalytic process that can utilise natural gas and nitrous oxide (both potent greenhouse gases) and oxygen to produce selectively methanol and hydrocarbons from a natural gas feedstream in a controlled manner. A single step process for natural gas conversion utilising waste green-house gases is expected to be of great benefit to the Australian economy, environment and energy securityRead moreRead less
Discovery Early Career Researcher Award - Grant ID: DE190101618
Funder
Australian Research Council
Funding Amount
$389,000.00
Summary
Tailoring multifunctional single site catalysts for carbon dioxide conversion. This project aims to develop multifunctional single site catalysts and collaborative surface sites to complete multi-step reactions using carbon dioxide (CO2) hydrogenation to higher alcohols with enhanced selectivity for large-chain alcohols. CO2 is an abundant and renewable carbon source for use as a feedstock, and closing the carbon cycle in an energy efficient manner has the potential for significant environmental ....Tailoring multifunctional single site catalysts for carbon dioxide conversion. This project aims to develop multifunctional single site catalysts and collaborative surface sites to complete multi-step reactions using carbon dioxide (CO2) hydrogenation to higher alcohols with enhanced selectivity for large-chain alcohols. CO2 is an abundant and renewable carbon source for use as a feedstock, and closing the carbon cycle in an energy efficient manner has the potential for significant environmental benefits. The project is expected to advance the knowledge in rational design of new catalysts for CO2 conversion and understanding the catalyst structure-property induced reaction mechanism. This will result in an improved understanding of the reaction kinetics of utilising CO2 as a feedstock.Read moreRead less
Heterogeneous hydrophilic catalysts for green oxidation in bio-refining. The project aims to address one significant global challenge of developing green processes for producing high value chemicals from biomass, to enhance the environmental performance and cost-efficiency of bio-refining. This project aims to develop a new class of heterogeneous nanocatalysts with hydrophilic Co (salen) complexes for biomass oxidation in water rather than toxic solvent. This project will use this to devise prac ....Heterogeneous hydrophilic catalysts for green oxidation in bio-refining. The project aims to address one significant global challenge of developing green processes for producing high value chemicals from biomass, to enhance the environmental performance and cost-efficiency of bio-refining. This project aims to develop a new class of heterogeneous nanocatalysts with hydrophilic Co (salen) complexes for biomass oxidation in water rather than toxic solvent. This project will use this to devise practical routes for the production of targeted industrial components for flavours, fragrances, fine chemicals, and petrochemicals. The development of heterogeneous hydrophilic catalysts by which they will oxidise hydrophilic biomasses in a continuous flow system will dramatically improve the sustainability of the chemical industry.Read moreRead less
High Efficiency Electrochemical Cells. This project will study a recently developed, energy efficient ‘capillary-fed’ electrochemical cell architecture in the facilitation of various electro-energy and electro-synthetic transformations. The new cell architecture will be examined as a hydrogen-oxygen fuel cell and as a cell for extracting pure hydrogen from a 5-10% mixture of hydrogen in methane (natural gas), amongst others. The work seeks to improve upon the electrochemical performance of the b ....High Efficiency Electrochemical Cells. This project will study a recently developed, energy efficient ‘capillary-fed’ electrochemical cell architecture in the facilitation of various electro-energy and electro-synthetic transformations. The new cell architecture will be examined as a hydrogen-oxygen fuel cell and as a cell for extracting pure hydrogen from a 5-10% mixture of hydrogen in methane (natural gas), amongst others. The work seeks to improve upon the electrochemical performance of the best commercial and academic cells of such types, if possible. In increasing the efficiency with which renewable electricity can be converted into renewable hydrogen and back, this project will support the national priority of net-zero carbon emissions by 2050.Read moreRead less
A novel route to produce olefin feedstock for Australia. This project aims to develop a new process to produce longer chain hydrocarbons usable in Australia's olefin and polymer industries. Besides their use as a fuel, hydrocarbons are major industrial chemicals used for the production of polymeric materials and as refrigerants. Olefins are precursors to polymers and conventionally are produced from saturated hydrocarbons through the process of steam cracking. The major precursors for monomers a ....A novel route to produce olefin feedstock for Australia. This project aims to develop a new process to produce longer chain hydrocarbons usable in Australia's olefin and polymer industries. Besides their use as a fuel, hydrocarbons are major industrial chemicals used for the production of polymeric materials and as refrigerants. Olefins are precursors to polymers and conventionally are produced from saturated hydrocarbons through the process of steam cracking. The major precursors for monomers are present in significant quantities in only a few natural gas sources and these sources also undergo significant seasonal variation and are costly. The project aims to develop new catalysts and process conditions to convert low-value feedstock hydrocarbons into feedstock for conventional steam crackers.Read moreRead less
Discovery Early Career Researcher Award - Grant ID: DE220100583
Funder
Australian Research Council
Funding Amount
$445,000.00
Summary
Engineering of biocatalysis in metal-organic frameworks for CO2 conversion. Transforming the greenhouse gas carbon dioxide (CO2) into valuable fuels would be beneficial for relieving energy shortage and improving global sustainability. This project aims to architect a biocascade system in metal-organic frameworks (MOFs) for artificial CO2 conversion. Learned from the living organisms, a whole biocatalysis unit including enzymes and cofactors will be encased and protected in an artificial porous ....Engineering of biocatalysis in metal-organic frameworks for CO2 conversion. Transforming the greenhouse gas carbon dioxide (CO2) into valuable fuels would be beneficial for relieving energy shortage and improving global sustainability. This project aims to architect a biocascade system in metal-organic frameworks (MOFs) for artificial CO2 conversion. Learned from the living organisms, a whole biocatalysis unit including enzymes and cofactors will be encased and protected in an artificial porous polymeric MOF coating. This approach is expected to deliver robust biocatalysts with high reaction-activity and chemo-selectivity in converting CO2 into methanol under the industrial operating condition, involving thermal, pH, and chemical stressors. This advancement will contribute to a carbon-neutral industry and society.Read moreRead less
Process studies for photocatalytic rejuvenation of spent industrial Bayer liquor. A new low-energy photocatalytic process for the continuous treatment of spent liquor from the Bayer process for alumina production has been demonstrated. This new technology can process up to 1500 litres of industrial caustic effluent per day with a reduction in carbon dioxide release. The photo-treated refinery wastewater also provides water savings of 30 per cent.