Integrated composite electrodes for electrochemical synthesis of ammonia. This project aims to develop multifunctional composite electrodes for electrochemical synthesis of ammonia from water, nitrogen gas and renewable energy under ambient conditions. Hydrophobic subnanometre water channels will be integrated with an electrocatalyst to control supply of water as vapour, thereby effectively minimising hydrogen evolution reaction and enabling high-efficiency ammonia synthesis. Expected outcomes i ....Integrated composite electrodes for electrochemical synthesis of ammonia. This project aims to develop multifunctional composite electrodes for electrochemical synthesis of ammonia from water, nitrogen gas and renewable energy under ambient conditions. Hydrophobic subnanometre water channels will be integrated with an electrocatalyst to control supply of water as vapour, thereby effectively minimising hydrogen evolution reaction and enabling high-efficiency ammonia synthesis. Expected outcomes include enhanced capacity in developing electrochemical reaction systems, and new fundamental knowledge of electrocatalyst design and reaction engineering. This should provide significant economic and environmental benefits by developing a sustainable manufacturing technology to transform the century-old ammonia industry.Read moreRead less
Special Research Initiatives - Grant ID: SR180100023
Funder
Australian Research Council
Funding Amount
$940,000.00
Summary
Thermal decomposition of PFAS. This project aims to investigate the thermal decomposition of per- and poly-fluroalkyl substances (PFAS). The project will focus on the catalytic destruction of PFAS reactions at elevated temperatures, which is expected to transform PFAS in a controlled and predictable way into benign products. By understanding the fate of these compounds during thermal decomposition, the project will allow the development of a new technology aimed at treating materials which have ....Thermal decomposition of PFAS. This project aims to investigate the thermal decomposition of per- and poly-fluroalkyl substances (PFAS). The project will focus on the catalytic destruction of PFAS reactions at elevated temperatures, which is expected to transform PFAS in a controlled and predictable way into benign products. By understanding the fate of these compounds during thermal decomposition, the project will allow the development of a new technology aimed at treating materials which have been contaminated with or have been used as absorbants for PFAS. The project will provide the technical underpinning of a new technology developed to treat fluorochemical-contaminated material and, in doing so, reduce the environmental impact of these contaminants.Read moreRead less
Tailoring metal-organic framework catalysts for carbon dioxide conversion. Reducing the greenhouse gas, CO2, into valuable fuels would be beneficial for relieving energy shortage and improving global sustainability. This project aims to synthesise high-performance heterogeneous catalysts for CO2 conversion by periodic ordering photo-redox metalloligand and thermal-catalytically active metal oxide clusters in metal-organic frameworks (MOFs). This approach is expected to deliver a unique single-si ....Tailoring metal-organic framework catalysts for carbon dioxide conversion. Reducing the greenhouse gas, CO2, into valuable fuels would be beneficial for relieving energy shortage and improving global sustainability. This project aims to synthesise high-performance heterogeneous catalysts for CO2 conversion by periodic ordering photo-redox metalloligand and thermal-catalytically active metal oxide clusters in metal-organic frameworks (MOFs). This approach is expected to deliver a unique single-site metal-organic framework catalyst with high reaction-activity and chemo-selectivity in converting CO2 into valuable chemicals. This advancement will provide significant benefits for Australia’s emerging chemical manufacturing industry, and ultimately leading to a carbon-neutral energy economy and environment.Read moreRead less
Catalytic conversion of Australia's natural gas to value added products. While natural gas (of which methane is the primary component) is an abundant source of energy, it is normally found in remote areas and for its successful exploitation it needs to be processed. The processing usually requires significant energy and resources input. In this project we will develop a fundamental understanding to a single step catalytic process that can utilise natural gas and nitrous oxide (both potent greenh ....Catalytic conversion of Australia's natural gas to value added products. While natural gas (of which methane is the primary component) is an abundant source of energy, it is normally found in remote areas and for its successful exploitation it needs to be processed. The processing usually requires significant energy and resources input. In this project we will develop a fundamental understanding to a single step catalytic process that can utilise natural gas and nitrous oxide (both potent greenhouse gases) and oxygen to produce selectively methanol and hydrocarbons from a natural gas feedstream in a controlled manner. A single step process for natural gas conversion utilising waste green-house gases is expected to be of great benefit to the Australian economy, environment and energy securityRead moreRead less
Discovery Early Career Researcher Award - Grant ID: DE220100429
Funder
Australian Research Council
Funding Amount
$406,177.00
Summary
Bioinspired Photocatalysts for Solar-Driven Hydrogen Peroxide Production. This project aims to develop advanced photocatalysts that can efficiently produce hydrogen peroxide from just water, air, and sunlight. By mimicking the structure and function of the natural photosynthetic apparatus, the key innovations are expected in the design of reaction-oriented conjugated polymer-based photocatalysts at the atomic and molecular nanostructure levels. It expects to generate new knowledge in artificial ....Bioinspired Photocatalysts for Solar-Driven Hydrogen Peroxide Production. This project aims to develop advanced photocatalysts that can efficiently produce hydrogen peroxide from just water, air, and sunlight. By mimicking the structure and function of the natural photosynthetic apparatus, the key innovations are expected in the design of reaction-oriented conjugated polymer-based photocatalysts at the atomic and molecular nanostructure levels. It expects to generate new knowledge in artificial photosynthesis and rational design of functional materials, and sustainable technology for hydrogen peroxide production. This cross-disciplinary research will benefit Australia by the development of biomimetic catalysts for advancing solar energy conversion and enabling sustainable manufacturing of commodity chemicals. Read moreRead less
High Efficiency Electrochemical Cells. This project will study a recently developed, energy efficient ‘capillary-fed’ electrochemical cell architecture in the facilitation of various electro-energy and electro-synthetic transformations. The new cell architecture will be examined as a hydrogen-oxygen fuel cell and as a cell for extracting pure hydrogen from a 5-10% mixture of hydrogen in methane (natural gas), amongst others. The work seeks to improve upon the electrochemical performance of the b ....High Efficiency Electrochemical Cells. This project will study a recently developed, energy efficient ‘capillary-fed’ electrochemical cell architecture in the facilitation of various electro-energy and electro-synthetic transformations. The new cell architecture will be examined as a hydrogen-oxygen fuel cell and as a cell for extracting pure hydrogen from a 5-10% mixture of hydrogen in methane (natural gas), amongst others. The work seeks to improve upon the electrochemical performance of the best commercial and academic cells of such types, if possible. In increasing the efficiency with which renewable electricity can be converted into renewable hydrogen and back, this project will support the national priority of net-zero carbon emissions by 2050.Read moreRead less
Discovery Early Career Researcher Award - Grant ID: DE220100583
Funder
Australian Research Council
Funding Amount
$445,000.00
Summary
Engineering of biocatalysis in metal-organic frameworks for CO2 conversion. Transforming the greenhouse gas carbon dioxide (CO2) into valuable fuels would be beneficial for relieving energy shortage and improving global sustainability. This project aims to architect a biocascade system in metal-organic frameworks (MOFs) for artificial CO2 conversion. Learned from the living organisms, a whole biocatalysis unit including enzymes and cofactors will be encased and protected in an artificial porous ....Engineering of biocatalysis in metal-organic frameworks for CO2 conversion. Transforming the greenhouse gas carbon dioxide (CO2) into valuable fuels would be beneficial for relieving energy shortage and improving global sustainability. This project aims to architect a biocascade system in metal-organic frameworks (MOFs) for artificial CO2 conversion. Learned from the living organisms, a whole biocatalysis unit including enzymes and cofactors will be encased and protected in an artificial porous polymeric MOF coating. This approach is expected to deliver robust biocatalysts with high reaction-activity and chemo-selectivity in converting CO2 into methanol under the industrial operating condition, involving thermal, pH, and chemical stressors. This advancement will contribute to a carbon-neutral industry and society.Read moreRead less
Advanced chemical recycling of mixed plastics for monomer recovery. This project aims to develop innovative catalytic routes to the chemical recycling of mixed plastics for recovery of their molecular building blocks. Plastic pollution poses a significant threat to the Australian ecosystem. Efficient recycling technologies are urgently needed as Australia only recycles ~4% of its 3.4 million tons of mixed waste plastics. This project expects to design highly efficient catalysts for the stepwise ....Advanced chemical recycling of mixed plastics for monomer recovery. This project aims to develop innovative catalytic routes to the chemical recycling of mixed plastics for recovery of their molecular building blocks. Plastic pollution poses a significant threat to the Australian ecosystem. Efficient recycling technologies are urgently needed as Australia only recycles ~4% of its 3.4 million tons of mixed waste plastics. This project expects to design highly efficient catalysts for the stepwise breakdown of mixed polyolefin plastics into monomers for the subsequent manufacturing of virgin plastics in a circular economy, and to elucidate fundamental underpinning reaction mechanisms. Outcomes will stimulate the Australian waste plastic recycling industry, and minimise plastic accumulation in the environment.Read moreRead less
Covalently immobilised molecular catalysts for carbon dioxide reduction. This project aims to develop innovative catalytic systems on semiconductor surfaces, to use sunlight for conversion of carbon dioxide (CO2) into high energy-content products. Sustainable chemical transformation of CO2 into valuable products, especially fuels, is one of the most important chemical processing challenges. This project will use innovative molecular engineering to covalently fix light-harvester to semiconductors ....Covalently immobilised molecular catalysts for carbon dioxide reduction. This project aims to develop innovative catalytic systems on semiconductor surfaces, to use sunlight for conversion of carbon dioxide (CO2) into high energy-content products. Sustainable chemical transformation of CO2 into valuable products, especially fuels, is one of the most important chemical processing challenges. This project will use innovative molecular engineering to covalently fix light-harvester to semiconductors. The expected outcome will be an efficient system to enhance CO2 conversion, which will not only reduce the environmental impact but also generate a cheap source of energy by closing the carbon loop. Using this approach, existing high carbon-emitting processes will be able to be replaced by new carbon-neutral or even carbon-negative ones for much-reduced environmental impact on our society.Read moreRead less
Scale-up of catalytic furandicarboxylic acid production at room temperature. This project will use new knowledge acquired from our laboratory-scale discoveries to develop a new process feasible for industrial-scale production of 2,5-furandicarboxylic acid (FDCA). The method makes FDCA, a platform chemical for future chemical industry, from a completely renewable source derived from plant sugars, 5-hydroxymethyl-furfural. This is an essential process for production of biodegradable plastic from s ....Scale-up of catalytic furandicarboxylic acid production at room temperature. This project will use new knowledge acquired from our laboratory-scale discoveries to develop a new process feasible for industrial-scale production of 2,5-furandicarboxylic acid (FDCA). The method makes FDCA, a platform chemical for future chemical industry, from a completely renewable source derived from plant sugars, 5-hydroxymethyl-furfural. This is an essential process for production of biodegradable plastic from sugar that has not been commercialised. This technology will realise sizeable industrial-scale production of FDCA at low costs and without heating. The production development of this valuable commodity from renewable plant sugars will provide high-quality postgraduate training in future green chemical production methods.Read moreRead less