Electronic-vibrational spectroscopy: A new probe for structure and function. This project aims to solve a major challenge in ultrafast spectroscopy: to identify and quantify competing reaction pathways in complex photochemical systems. Ultrafast Spectroscopy provides information on excited-state processes of photochemical reactions, however, unravelling heterogeneous systems with competing parallel processes remains difficult. Multidimensional electronic-vibrational spectroscopy, sensitive to el ....Electronic-vibrational spectroscopy: A new probe for structure and function. This project aims to solve a major challenge in ultrafast spectroscopy: to identify and quantify competing reaction pathways in complex photochemical systems. Ultrafast Spectroscopy provides information on excited-state processes of photochemical reactions, however, unravelling heterogeneous systems with competing parallel processes remains difficult. Multidimensional electronic-vibrational spectroscopy, sensitive to electronic dynamics and molecular structure, is expected to overcome this barrier. This new level of detail will profoundly enhance our understanding of energy and chemical conversion in complex systems and will reveal design targets for optimising next-generation light-energy harvesting, conducting, and emitting materials.Read moreRead less
Advanced framework materials for hydrogen storage applications. This project aims to develop new molecular materials capable of the highly efficient storage of hydrogen gas. Through an innovative interdisciplinary approach that targets the synthesis and detailed characterisation of two classes of molecular material this project expects to generate step-change advances in the understanding of how hydrogen gas uptake relates to the chemical and physical attributes of porous molecular systems. Sign ....Advanced framework materials for hydrogen storage applications. This project aims to develop new molecular materials capable of the highly efficient storage of hydrogen gas. Through an innovative interdisciplinary approach that targets the synthesis and detailed characterisation of two classes of molecular material this project expects to generate step-change advances in the understanding of how hydrogen gas uptake relates to the chemical and physical attributes of porous molecular systems. Significant anticipated outcomes and benefits include the development of new material design approaches that optimise performance across a diverse parameter space, and the generation of advanced new materials worthy of commercial development, spanning small scale mobile to large scale stationary storage applications.Read moreRead less
Metal-Based Molecular Materials: From Electronic Structure to Functionality. This project aims to develop and explore new metal-based molecular materials, focusing on molecules that can act as magnets or be switched between multiple states by heating/cooling. This project expects to deliver an improved understanding of how the molecular electronic structure engenders desired physical properties in the target species. This insight will allow development of design principles for robust systems for ....Metal-Based Molecular Materials: From Electronic Structure to Functionality. This project aims to develop and explore new metal-based molecular materials, focusing on molecules that can act as magnets or be switched between multiple states by heating/cooling. This project expects to deliver an improved understanding of how the molecular electronic structure engenders desired physical properties in the target species. This insight will allow development of design principles for robust systems for nanodevices or advanced materials. As well as achieving important advances in fundamental chemistry, this project is anticipated to help lay the foundations for development of novel materials for high density data storage, quantum computing, molecular electronics/spintronics, optical displays or temperature/solvent sensors.Read moreRead less
Molecular Spin Switching with Earth Abundant Metals. This project aims to develop molecular materials based on non-precious metals that respond to stimuli, including heat or light, by switching between forms with different properties, such as colour and electrical conductivity. The project expects to deliver enhanced control over the switching characteristics and incorporation of the materials into responsive thin films, ready for integration into devices. These molecular switches are promising ....Molecular Spin Switching with Earth Abundant Metals. This project aims to develop molecular materials based on non-precious metals that respond to stimuli, including heat or light, by switching between forms with different properties, such as colour and electrical conductivity. The project expects to deliver enhanced control over the switching characteristics and incorporation of the materials into responsive thin films, ready for integration into devices. These molecular switches are promising for molecular electronics, spintronics and colour-based sensing and display devices. Their fast response time and small component size imply less heat to dissipate and therefore less electricity required for cooling upon implementation in information communications and other technologies.Read moreRead less
Discovery Early Career Researcher Award - Grant ID: DE210101627
Funder
Australian Research Council
Funding Amount
$447,625.00
Summary
Developing ultra adsorbent MOF composites as high performance materials. This project aims to improve the adsorption properties of porous materials through enhancing their selectivity and also creating new composites. This research expects to extend application opportunities to encompass real-life scenarios, in particular hydrogen transfer and carbon capture. Expected outcomes is the enhancement of the adsorbent properties of these porous materials, and an improvement of their selectivity and m ....Developing ultra adsorbent MOF composites as high performance materials. This project aims to improve the adsorption properties of porous materials through enhancing their selectivity and also creating new composites. This research expects to extend application opportunities to encompass real-life scenarios, in particular hydrogen transfer and carbon capture. Expected outcomes is the enhancement of the adsorbent properties of these porous materials, and an improvement of their selectivity and mechanical robustness. This is due to the synergistic strengthening effects of new graphene and nanodiamond composites. The benefit of this research is in bridging the gap between porous material synthesis and industrial application, contributing to Australia's becoming a world leader in clean energy research.Read moreRead less
Discovery Early Career Researcher Award - Grant ID: DE200100279
Funder
Australian Research Council
Funding Amount
$424,198.00
Summary
A nanodiamond voltage sensor: towards real-time, long-term neuronal sensing. This project aims to develop a voltage sensor that may ultimately be used to measure neuronal signals noninvasively in real-time and over hours. The project expects to generate the fundamental science needed to use nanodiamonds for fluorescence-based voltage sensing that can be easily measured using optical microscopy. The expected outcome is a biocompatible sensor that should provide a solution to one of the biggest ch ....A nanodiamond voltage sensor: towards real-time, long-term neuronal sensing. This project aims to develop a voltage sensor that may ultimately be used to measure neuronal signals noninvasively in real-time and over hours. The project expects to generate the fundamental science needed to use nanodiamonds for fluorescence-based voltage sensing that can be easily measured using optical microscopy. The expected outcome is a biocompatible sensor that should provide a solution to one of the biggest challenges in neuroscience; the fast, precise and long-term measurement of neuronal activity. This technology may one day inform our understanding of how the normal brain works and provide major insights into mental health conditions and neurodegenerative diseases.Read moreRead less
Shape-Shifting Molecules: Photoisomerization Action Spectroscopy. This project aims to examine molecules that change shape in response to light in order to gain insight into the biological processes they control. Many biological systems, including the human visual apparatus and bacterial photosynthesis, depend on molecules that change shape in response to light. The project plans to probe shape-shifting molecules with laser light while they are propelled through gas by an electric field. Light-i ....Shape-Shifting Molecules: Photoisomerization Action Spectroscopy. This project aims to examine molecules that change shape in response to light in order to gain insight into the biological processes they control. Many biological systems, including the human visual apparatus and bacterial photosynthesis, depend on molecules that change shape in response to light. The project plans to probe shape-shifting molecules with laser light while they are propelled through gas by an electric field. Light-induced changes in molecular shape produce detectable variations in drift speed. The ensuing knowledge would help calibrate computational approaches for predicting molecular function. It would also establish foundations for understanding essential biological molecules, including retinals, carotenes and peptides, and for developing new light-activated molecular motors and switches.Read moreRead less
Multi-colour ultrashort soft X-ray pulses. This project aims to create multi-colour, ultrashort, highly coherent, bright pulses of soft X-rays based on high-harmonic generation in a table-top multiple-section gas cell. Studying multi-electronic and non-adiabatic processes and other fundamental aspects such as multi-electronic correlations and non-Born-Oppenheimer vibronic couplings in complex molecules is a major challenge in current ultrafast photochemistry research. This project will use multi ....Multi-colour ultrashort soft X-ray pulses. This project aims to create multi-colour, ultrashort, highly coherent, bright pulses of soft X-rays based on high-harmonic generation in a table-top multiple-section gas cell. Studying multi-electronic and non-adiabatic processes and other fundamental aspects such as multi-electronic correlations and non-Born-Oppenheimer vibronic couplings in complex molecules is a major challenge in current ultrafast photochemistry research. This project will use multiple driving pulses with different carrier frequencies to control the spectral properties and time delay of the pulses. It will use the soft X-ray source to develop an ideal platform for studying multi-electronic and non-adiabatic processes, multi-electronic correlations and non-Born-Oppenheimer vibronic couplings in complex molecules. This is expected to advance materials science, paving the way to soft X-ray technologies.Read moreRead less