Porphyrin-Based Supramolecular Assemblies and Arrays - Model Systems for the Construction of Photosynthetic Mimics. Crown ether-based multichromophoric systems will be used to mimic the steps through which plants convert light into chemical energy. The crown bridging units allow a variety of metal and organic cations, which provide electronic and structural roles, to be non-covalently bound within their cavities. These systems are advantageous over other photosynthetic models in that a variety ....Porphyrin-Based Supramolecular Assemblies and Arrays - Model Systems for the Construction of Photosynthetic Mimics. Crown ether-based multichromophoric systems will be used to mimic the steps through which plants convert light into chemical energy. The crown bridging units allow a variety of metal and organic cations, which provide electronic and structural roles, to be non-covalently bound within their cavities. These systems are advantageous over other photosynthetic models in that a variety of electron transfer mediators can be examined in a readily controlled and systematic way simply through the choice of cation. In this way, the role played by molecular recognition in the modulation of long-range electron transfer can be evaluated. This work will lead to designing better artificial solar energy converters and molecular electronic devices.Read moreRead less
Characterization and design of new soft electrolyte materials. The use of fossil fuels for energy generation contributes heavily to global warming. The development of new types of energy sources (e.g. fuel cells) and energy storage devices (e.g. batteries) is of crucial importance to ease this pressure on the environment. The search for new, high energy-density electrolyte materials for these applications is intense. Recently, plastic crystal materials have been identified as potential electroly ....Characterization and design of new soft electrolyte materials. The use of fossil fuels for energy generation contributes heavily to global warming. The development of new types of energy sources (e.g. fuel cells) and energy storage devices (e.g. batteries) is of crucial importance to ease this pressure on the environment. The search for new, high energy-density electrolyte materials for these applications is intense. Recently, plastic crystal materials have been identified as potential electrolytes in a variety of electrochemical devices. These materials show high conductivity at ambient temperatures in their plastic (or soft) phase. This project aims to further investigate and develop these novel materials.Read moreRead less
Porphyrin Based Supramolecular Assemblies and Arrays III - Model Systems for the Construction of Photosynthetic Mimics and Devices. Solar cells that convert light to electricity are an excellent solution to bringing energy to remote locations with abundant sunlight. This research proposal aims to provide an intellectual grounding in the development of molecular systems and supramolecular arrays that are capable of such solar energy conversion (photovoltaics & artificial photosynthesis) or that ....Porphyrin Based Supramolecular Assemblies and Arrays III - Model Systems for the Construction of Photosynthetic Mimics and Devices. Solar cells that convert light to electricity are an excellent solution to bringing energy to remote locations with abundant sunlight. This research proposal aims to provide an intellectual grounding in the development of molecular systems and supramolecular arrays that are capable of such solar energy conversion (photovoltaics & artificial photosynthesis) or that have potential applications in photonics. Developments in this project may also lead to breakthroughs in areas such as nano-scale computing and cleaner and more sustainable energy productionRead moreRead less
Linkage Infrastructure, Equipment And Facilities - Grant ID: LE0989127
Funder
Australian Research Council
Funding Amount
$400,000.00
Summary
A High-Throughput Neutron Spectrometer for The Study of Atomic and Molecular Motion at ANSTO. Neutron scattering enables new science across a broad range of disciplines, and for this reason it is undergoing major expansion in the USA, Europe, Japan and Australia. Various diffactometers and spectrometers have recently been built at ANSTO, but an instrumental option for a high-throughput cross-discipline spectroscopy is urgently needed. Fortunately, it is fairly straightforward to add this type of ....A High-Throughput Neutron Spectrometer for The Study of Atomic and Molecular Motion at ANSTO. Neutron scattering enables new science across a broad range of disciplines, and for this reason it is undergoing major expansion in the USA, Europe, Japan and Australia. Various diffactometers and spectrometers have recently been built at ANSTO, but an instrumental option for a high-throughput cross-discipline spectroscopy is urgently needed. Fortunately, it is fairly straightforward to add this type of option to an existing spectrometer that will broaden its user-base from specialised applications in physics to more general applications in physics, chemistry, materials-science and biology. This additional option provides a totally new way for Australian scientists to study atomic and molecular motions. Read moreRead less
Porphyrin-Based Supramolecular Assemblies and Arrays II: Model Systems for the Construction of Photosynthetic Mimics and Devices. Solar cells that convert light to electricity are an excellent solution to bringing energy to remote locations with abundant sunlight. This research proposal aims to provide an intellectual grounding in the development of molecular systems and supramolecular arrays that are capable of such solar energy conversion (photovoltaics & artificial photosynthesis) or that ha ....Porphyrin-Based Supramolecular Assemblies and Arrays II: Model Systems for the Construction of Photosynthetic Mimics and Devices. Solar cells that convert light to electricity are an excellent solution to bringing energy to remote locations with abundant sunlight. This research proposal aims to provide an intellectual grounding in the development of molecular systems and supramolecular arrays that are capable of such solar energy conversion (photovoltaics & artificial photosynthesis) or that have potential applications in photonics. Developments in this project may also lead to breakthroughs in areas such as nano-scale computing and cleaner and more sustainable energy production.Read moreRead less
Development of Nanocrystalline Transition Metal Oxide and Polymer-Transition Metal Oxide Composite Materials for Rechargeable Lithium Battery Applications. Recent work by the applicants has shown that nanocrystalline titanates and aluminates hold considerable promise as lithium battery electrodes. Nanocrystalline anatase materials showed considerably greater lithium intercalation ratios compared with their microcrystalline counterparts, and doping with vanadium showed further improvements in ....Development of Nanocrystalline Transition Metal Oxide and Polymer-Transition Metal Oxide Composite Materials for Rechargeable Lithium Battery Applications. Recent work by the applicants has shown that nanocrystalline titanates and aluminates hold considerable promise as lithium battery electrodes. Nanocrystalline anatase materials showed considerably greater lithium intercalation ratios compared with their microcrystalline counterparts, and doping with vanadium showed further improvements in capacity. Sol-gel synthesised V-doped anatase materials produced an initial discharge capacity of 428 Ah/kg compared with only 280 mAh/kg for the undoped anatase electrode in the same Li test cell.In this project different dopants and preparation conditions will be investigated to produce nanocrystalline rutile and aluminate materials as potential candidates for high capacity lithium battery applications.Read moreRead less
Development of high-temperature superconducting coated conductors by pulsed-laser deposition technique for future long-length applications. The aim of the project is to develop a novel technology for manufacturing flexible coated conductors with the help of a pulsed laser deposition technique, in order to enhance the current-carrying ability of high-temperature superconducting coatings (including multi-layered coatings) for future long-length high power applications. To achieve desirable electr ....Development of high-temperature superconducting coated conductors by pulsed-laser deposition technique for future long-length applications. The aim of the project is to develop a novel technology for manufacturing flexible coated conductors with the help of a pulsed laser deposition technique, in order to enhance the current-carrying ability of high-temperature superconducting coatings (including multi-layered coatings) for future long-length high power applications. To achieve desirable electromagnetic properties governed by the nano-structures of the coatings, a well-balanced combination of world-class "global" and "local" electromagnetic property measurements with advanced structural characterisations is suggested. It is expected that a controlled network of nano-scale pinning centres will allow the development of high performance coated conductors.Read moreRead less
Hydrogen Absorption by Nanostructured Carbons. Carbon-based materials show great promise for clean energy storage through the absorption and desorption of hydrogen. The project aims to use powerful theoretical and experimental methods to resolve the controversy that surrounds reports of massive hydrogen absorption by nanostructured carbons, by understanding why particular structures should or should not absorb hydrogen atoms or molecules. We will particularly study and model intercalated graphit ....Hydrogen Absorption by Nanostructured Carbons. Carbon-based materials show great promise for clean energy storage through the absorption and desorption of hydrogen. The project aims to use powerful theoretical and experimental methods to resolve the controversy that surrounds reports of massive hydrogen absorption by nanostructured carbons, by understanding why particular structures should or should not absorb hydrogen atoms or molecules. We will particularly study and model intercalated graphite and nanotubes made in Australia. Their hydrogen capacity will be compared to the US DOE target of 6.5 weight percent for viable automotive hydrogen fuel storage. Reproducibly exceeding this target would constitute a great advance in the field.Read moreRead less
Development of conductive buffer layers for RABiTS-based coated conductors. YBCO coated conductor has already been identified and developed as far as second generation HTS wire in power applications. Major advances have been made in the last 10 years in coated conductor development mainly in all aspects: substrate, buffer layer and YBCO layer. The research on conductive buffers layer will improve and expand the R&D on coated conductor in Australia. On the economic side, dramatic advantages and s ....Development of conductive buffer layers for RABiTS-based coated conductors. YBCO coated conductor has already been identified and developed as far as second generation HTS wire in power applications. Major advances have been made in the last 10 years in coated conductor development mainly in all aspects: substrate, buffer layer and YBCO layer. The research on conductive buffers layer will improve and expand the R&D on coated conductor in Australia. On the economic side, dramatic advantages and savings could be achieved if the coated conductors can be put to use. Superconductivity can have a significant role in deregulated electricity markets and in lessening CO2 emissions and other environmental impacts.Read moreRead less
Development of Magnesium Diboride Superconductor Wires with High Upper Critical Field for MRI Applications. The aim of the program is to demonstrate the superconducting magnesium diboride (MgB2) wires with improved upper critical field (Hc2,) appropriate for large-scale applications. The basic idea will be based on the two-gap superconductivity to add well-distributed impurities which will act as scatterers, increasing resistivity, and thus Hc2. The core innovation of this proposal is based on t ....Development of Magnesium Diboride Superconductor Wires with High Upper Critical Field for MRI Applications. The aim of the program is to demonstrate the superconducting magnesium diboride (MgB2) wires with improved upper critical field (Hc2,) appropriate for large-scale applications. The basic idea will be based on the two-gap superconductivity to add well-distributed impurities which will act as scatterers, increasing resistivity, and thus Hc2. The core innovation of this proposal is based on the recent breakthrough in MgB2 that was made by the CIs through nano-SiC particle doping, which achieved a record high Hc2 in bulk form and enhancement of critical current density, Jc, in magnetic fields by an order of magnitude. The expected outcome is the development of superconducting MgB2 wires and coils with high Hc2 and Jc for MRI applications.Read moreRead less