Engineered materials for future energy technologies. The development of new technologies to be applied in fuel generation, energy conversion and environmental remediation will have wide national and international impact. The cross-disciplinary and cross-institution research program proposed will draw on expertise within Australia and in Europe for the fabrication of materials for next generation energy devices. In the future, there is the potential that these materials could be fabricated within ....Engineered materials for future energy technologies. The development of new technologies to be applied in fuel generation, energy conversion and environmental remediation will have wide national and international impact. The cross-disciplinary and cross-institution research program proposed will draw on expertise within Australia and in Europe for the fabrication of materials for next generation energy devices. In the future, there is the potential that these materials could be fabricated within Australia and therefore lead to employment nationally, and income generated through the export of advanced catalysts, solar cells and sequestration materials.Read moreRead less
Designing reactivity of homogeneous and heterogeneous water-splitting catalysts using muti-dimensional site-selective spectroscopies. New classes of heterogeneous manganese-calcium water splitting catalysts analogous to the unique biological water splitting cofactor have recently emerged but with far lower catalytic rates than seen for the biological system. These new materials are promising targets for large-scale hydrogen fuel production with low cost, high efficiency and ease of manufacture. ....Designing reactivity of homogeneous and heterogeneous water-splitting catalysts using muti-dimensional site-selective spectroscopies. New classes of heterogeneous manganese-calcium water splitting catalysts analogous to the unique biological water splitting cofactor have recently emerged but with far lower catalytic rates than seen for the biological system. These new materials are promising targets for large-scale hydrogen fuel production with low cost, high efficiency and ease of manufacture. To achieve this, the performance gap between these materials and the homogenous biological catalyst must be bridged. Multi-dimensional site-selective spectroscopies, including magneto/optical resonance methods which are aimed to be developed in this project are expected to provide new, atomic level understanding of properties needed to achieve high catalytic efficiency, thus guiding rational catalyst design.Read moreRead less
Probing gold in hot ore fluids: experiments and molecular dynamics simulations. In order to efficiently discover vital new mineral resources for Australia, explorers must understand the fundamental controls on ore formation. The lack of data for soluble metal behaviour in hot fluids at high pressure is a significant impediment to our understanding of deposit formation and for the application of industrial processes, such as hydrometallurgy. This project will gain molecular-level understanding of ....Probing gold in hot ore fluids: experiments and molecular dynamics simulations. In order to efficiently discover vital new mineral resources for Australia, explorers must understand the fundamental controls on ore formation. The lack of data for soluble metal behaviour in hot fluids at high pressure is a significant impediment to our understanding of deposit formation and for the application of industrial processes, such as hydrometallurgy. This project will gain molecular-level understanding of the fundamental chemistry of gold transport and deposition in high temperature, high-pressure, carbon dioxide-rich fluids and gold colloid systems, using multiple novel experimental techniques and molecular dynamics simulations that make use of Australia’s cutting-edge experimental and computational facilities.Read moreRead less
Representations of arithmetic groups and their associated zeta functions. This project aims to investigate deep connections between number theory and group theory by studying linear actions of arithmetic groups. Arithmetic groups are used in geometry, dynamics, number theory and other areas of pure mathematics. This project will study their representations from two perspectives. First, it will establish properties of the associated zeta functions to resolve open problems about the asymptotic beh ....Representations of arithmetic groups and their associated zeta functions. This project aims to investigate deep connections between number theory and group theory by studying linear actions of arithmetic groups. Arithmetic groups are used in geometry, dynamics, number theory and other areas of pure mathematics. This project will study their representations from two perspectives. First, it will establish properties of the associated zeta functions to resolve open problems about the asymptotic behaviour of the dimensions of the irreducible representations. Second, it will explore the evolution of representations across families of groups under new induction and restriction functors, in analogy with creation and annihilation operators in physics. The project will enhance Australia's capacity in representation theory and group theory, the mathematics that underline symmetry in nature.Read moreRead less
Next generation supramolecular frameworks. This project aims to prepare new supramolecular frameworks assembled by hydrogen or halogen bonds. It is anticipated that this work will increase fundamental understanding of supramolecular self-assembly processes and the dynamic processes that are possible within these rearrangeable systems. The project aims to prepare a family of related frameworks, which will allow a detailed comparison of the stability, porosity and biotechnological applicability of ....Next generation supramolecular frameworks. This project aims to prepare new supramolecular frameworks assembled by hydrogen or halogen bonds. It is anticipated that this work will increase fundamental understanding of supramolecular self-assembly processes and the dynamic processes that are possible within these rearrangeable systems. The project aims to prepare a family of related frameworks, which will allow a detailed comparison of the stability, porosity and biotechnological applicability of new supramolecular materials. The expected outcomes are the development of lightweight and benign organic systems that will have applications in the removal of toxic organic and heavy metal pollutants from water, and in the encapsulation and stabilisation of catalytically-active enzymes.Read moreRead less
Specific-ion effects in non-aqueous solvents. A test for Hofmeister. A colloidal solution is a liquid that contains a finely dispersed material. The properties of these solutions are critical in many industrially important practices and in the everyday processes of life. Though not understood, it is observed that the type of salt in solution controls how the colloid behaves. Through a series of very careful experiments we seek to learn precisely how different salts influence the properties of a ....Specific-ion effects in non-aqueous solvents. A test for Hofmeister. A colloidal solution is a liquid that contains a finely dispersed material. The properties of these solutions are critical in many industrially important practices and in the everyday processes of life. Though not understood, it is observed that the type of salt in solution controls how the colloid behaves. Through a series of very careful experiments we seek to learn precisely how different salts influence the properties of a colloidal solution. This world-leading research will enable us to improve our fundamental understanding of colloids and thereby facilitate advances in topics as diverse as enzymatic action and minerals purification, ensuring Australia remains at the forefront of science in this field.Read moreRead less
Springer fibres, nilpotent cones and representation theory. This project will address new ideas and famous unsolved problems in the field of algebra known as representation theory, by studying the geometry of spaces called Springer fibres and nilpotent cones. This will keep Australian mathematics in the forefront of developments in this internationally active field, which is central to modern mathematics.
Complementary pairs for next generation self-assembled systems . This project will employ a set of complementary pairings where separate sites fit together at metal ions in a specific fashion orthogonal to other pairings, like two jigsaw pieces, while forming a poor fit with other pairings. These pairings will allow retention and transfer of structural information. In this way, the bulk combination of relatively simple precursors will lead to self-assembled structures with well-defined seque ....Complementary pairs for next generation self-assembled systems . This project will employ a set of complementary pairings where separate sites fit together at metal ions in a specific fashion orthogonal to other pairings, like two jigsaw pieces, while forming a poor fit with other pairings. These pairings will allow retention and transfer of structural information. In this way, the bulk combination of relatively simple precursors will lead to self-assembled structures with well-defined sequence identity. This program will make and use complex abiotic molecules, enhancing outcomes in molecular information storage and transfer, molecular recognition and sensing, chemical transformations, and energy transport events, leading to economic and environmental benefits for Australia in industry and manufacturing.Read moreRead less
Understanding and controlling the stereochemistry of free-radical polymerisation. The stereochemistry of a molecule, which relates to the relative spatial arrangement of its atoms, can have a profound effect on its physical and chemical properties. This project will use a computer-guided experimental approach to design new methods for controlling the stereochemistry of the polymers formed in free-radical polymerisation.
Geological applications of synchrotron radiation: magmas, fluids, ores and minerals. This project will use the Australian synchrotron facility to study magmas and minerals to improve our understanding of the formation of ore-deposits and the evolution of the continents.