Organotin based hybrid materials as selective catalysts. Hybrid organic-inorganic materials offer potential applications in a variety of fields ranging from photonics to selective catalysts. This pilot project brings together the expertise in four international research laboratories to focus on elaboration of new nanocomposites as highly selective Lewis acid catalysts for fine chemicals synthesis.
Organotin Oxo-clusters Based Hybrid Materials. Hybrid materials are composites which contain both organic and inorganic components, intimately mixed at the microscopic (nanometer) scale. They have applications in areas ranging from recoverable chemical catalysts to micro-chip technology. We will provide new oganometallic components of suitable architecture for assessment as new materials.
Cooperativity in Spin Crossover Systems: Memory, Magnetism and Microporosity. Spin-crossover centres are a well known form of inorganic electronic switch for which variation of temperature, pressure and irradiation leads to a change in d-electron configuration and therefore changes to structure, colour and magnetism. Here we aim to synthesise and study a wide variety of new spin-crossover systems where cooperativitiy between centres, induced by careful supramolecular design, will lead to molecul ....Cooperativity in Spin Crossover Systems: Memory, Magnetism and Microporosity. Spin-crossover centres are a well known form of inorganic electronic switch for which variation of temperature, pressure and irradiation leads to a change in d-electron configuration and therefore changes to structure, colour and magnetism. Here we aim to synthesise and study a wide variety of new spin-crossover systems where cooperativitiy between centres, induced by careful supramolecular design, will lead to molecules and materials having memory retention, magnetic ordering and/or microporosity. The significance of these aims covers several fundamental questions in the science of electronic systems. We also identify a number of potential nanochemical switching applications for the unique systems proposed.Read moreRead less
ENHANCED PERFORMANCE OF AUTOMOTIVE SHEET ALLOYS VIA CONTROL OF COMPOSITION, THERMAL PROCESSING AND NANOSTRUCTURE. This project involves characterisation using modern facilities of the form and identity of atomic-scale clusters of alloying elements in selected automotive sheet alloys that have been subjected to single and multiple ageing treatments and examination and modelling of deformation mechanisms and behaviour in such alloys. The aim is to establish the precise role of clusters of solute a ....ENHANCED PERFORMANCE OF AUTOMOTIVE SHEET ALLOYS VIA CONTROL OF COMPOSITION, THERMAL PROCESSING AND NANOSTRUCTURE. This project involves characterisation using modern facilities of the form and identity of atomic-scale clusters of alloying elements in selected automotive sheet alloys that have been subjected to single and multiple ageing treatments and examination and modelling of deformation mechanisms and behaviour in such alloys. The aim is to establish the precise role of clusters of solute atoms and vacancies in the formation of precipitate phases that control the final strength and deformation behaviour of the alloys, and to provide useful guidelines for further improvements in strength of these alloys via the control of alloy composition and of multiple ageing treatments.Read moreRead less
Development of Creep Resistant TiAl Alloys for High Temperature Structural Applications. TiAl based alloys are being developed as high temperature structural materials for aerospace and automotive applications and thus their creep resistance (long-term strength at elevated temperatures) is critical. This project aims at developing creep resistant TiAl alloys through a combination of addition of rare earth and severe plastic deformation. It is expected that a refined and stablised microstructure ....Development of Creep Resistant TiAl Alloys for High Temperature Structural Applications. TiAl based alloys are being developed as high temperature structural materials for aerospace and automotive applications and thus their creep resistance (long-term strength at elevated temperatures) is critical. This project aims at developing creep resistant TiAl alloys through a combination of addition of rare earth and severe plastic deformation. It is expected that a refined and stablised microstructure consisting of submicron lamellar grains and nanosized lamellae be obtained. This will result in a highly creep resistant prototype TiAl material and leads eventually to the development of commercial TiAl alloys.Read moreRead less
Design of Welded Steel Tubular Connections. Steel tubes are widely used in building, road transportation, defence, recreation, and agriculture industries. The proposed program will develop static design procedures for welded tubular connections to ensure safe and economic structures. The program will also investigate the behaviour of a popular tubular connection utilizing very high strength steel tubes to extend the existing design scope and enhance the utilization of Australian produced innovat ....Design of Welded Steel Tubular Connections. Steel tubes are widely used in building, road transportation, defence, recreation, and agriculture industries. The proposed program will develop static design procedures for welded tubular connections to ensure safe and economic structures. The program will also investigate the behaviour of a popular tubular connection utilizing very high strength steel tubes to extend the existing design scope and enhance the utilization of Australian produced innovative tubular sections. The notch toughness of steel tubes will also be investigated to avoid fracture failure of welded connections under dynamic loading. The program will build strong ongoing collaboration between University of Toronto and Monash University.Read moreRead less
Gas phase studies of the interactions of electrons with peptide ions: structure assignment and fundamentals. Electron-induced reactions are fundamental to a wide range of processes that underlie many areas of science and technology, ranging from planetary atmospheres, industrial plasmas to living tissues. Since ionizing radiation is believed to be a major cause of damage to living cells, understanding electron interactions with biological molecules is essential to predict the consequences of ex ....Gas phase studies of the interactions of electrons with peptide ions: structure assignment and fundamentals. Electron-induced reactions are fundamental to a wide range of processes that underlie many areas of science and technology, ranging from planetary atmospheres, industrial plasmas to living tissues. Since ionizing radiation is believed to be a major cause of damage to living cells, understanding electron interactions with biological molecules is essential to predict the consequences of exposure. Structure determination of biomolecules is at the heart of identifying, diagnosing and potentially developing treatments for diseases, and thus another important reason for studying these interactions is the potential to develop new mass spectrometry based analytical methods.Read moreRead less
New Membrane Methods to Extract Lactose From Waste Dairy Streams. Dairy processors throughout the world produce about 145,000,000 t of liquid whey per year. Lactose, the principle component in cheese whey, contributes a significant pollution problem for dairy processors. The aim of this Linkage Award application is to develop membranes that selectively extract the lactose. This requires the preparation of membrane carriers that transport the lactose through the membrane. The development of new a ....New Membrane Methods to Extract Lactose From Waste Dairy Streams. Dairy processors throughout the world produce about 145,000,000 t of liquid whey per year. Lactose, the principle component in cheese whey, contributes a significant pollution problem for dairy processors. The aim of this Linkage Award application is to develop membranes that selectively extract the lactose. This requires the preparation of membrane carriers that transport the lactose through the membrane. The development of new approaches and technologies for the isolation and purification of lactose from feed streams may lead to improved processes for manufacture of purified lactose or new lactose products.Read moreRead less
Development of a Superplastic Forming Capabilities in Magnesium-Based Alloys through Processing using Severe Plastic Deformation. This research will provide a basis for advancing the structural use of magnesium alloys in the building and transportation industries. It is anticipated the project will lower the cost of producing lightweight structures and extend the range of alloys that can be used in such applications. With the growing magnesium industry in Australia, and with the potential for Au ....Development of a Superplastic Forming Capabilities in Magnesium-Based Alloys through Processing using Severe Plastic Deformation. This research will provide a basis for advancing the structural use of magnesium alloys in the building and transportation industries. It is anticipated the project will lower the cost of producing lightweight structures and extend the range of alloys that can be used in such applications. With the growing magnesium industry in Australia, and with the potential for Australia to become a major world supplier of magnesium, the development of advanced processing technology for magnesium-based alloys is of national importance. The project will play a vital role in strengthening the Australian technological position and increasing the opportunities for professional Australians.Read moreRead less
Automated Interaction Technologies for Mobile Hand-held Devices. This project is concerned with developing intelligent technologies that support human interaction through handheld devices, connected to wireless digital networks. Intelligent software assistants running on these devices will interact with one another in order to coordinate the activities of multiple users. Such automated coordination may facilitate scheduling of meetings, collaboration among different members of a team, and negoti ....Automated Interaction Technologies for Mobile Hand-held Devices. This project is concerned with developing intelligent technologies that support human interaction through handheld devices, connected to wireless digital networks. Intelligent software assistants running on these devices will interact with one another in order to coordinate the activities of multiple users. Such automated coordination may facilitate scheduling of meetings, collaboration among different members of a team, and negotiating conflicts that may arise between the activities of different connected users. This will enable context-dependent task support and coordination of workers involved in industrial applications involving mobility and dynamism.Read moreRead less