Flow process and visible-light driven reactions for polymer manufacturing. This project aims to develop rapid, scalable light-driven continuous flow processing techniques that allow the production of value-added synthetic polymers that cannot be achieved by existing technologies. The project will take advantage of the spatio-temporal control of the light mediated polymerisation with flow process to achieve control over the primary structure, the sequential arrangement of monomer units in a polym ....Flow process and visible-light driven reactions for polymer manufacturing. This project aims to develop rapid, scalable light-driven continuous flow processing techniques that allow the production of value-added synthetic polymers that cannot be achieved by existing technologies. The project will take advantage of the spatio-temporal control of the light mediated polymerisation with flow process to achieve control over the primary structure, the sequential arrangement of monomer units in a polymer chain and the molecular weight distribution. The project will result in the preparation of functional polymers containing a specific arrangement of monomers in the polymer chain and a precise distribution of polymer chains. The development of such process will result in the development of advanced materials.Read moreRead less
Manufacturing Nanostructured Polymer Thin Films using Visible Light. This research aims the development of selective photochemical tools driven by different colours of light for the fabrication of nanostructured polymer brush thin films. By using different wavelengths to selectively activate specific chemical reactions, this will enable multiple reactions to be performed simultaneously, significantly streamlining fabrication. Additionally, the increased selectivity offers pathways to more sophis ....Manufacturing Nanostructured Polymer Thin Films using Visible Light. This research aims the development of selective photochemical tools driven by different colours of light for the fabrication of nanostructured polymer brush thin films. By using different wavelengths to selectively activate specific chemical reactions, this will enable multiple reactions to be performed simultaneously, significantly streamlining fabrication. Additionally, the increased selectivity offers pathways to more sophisticated nanoarchitectures in comparison to existing methods. This research will lead to the fabrication of 3D polymer brush architectures with unparalleled precision, which will be of high scientific and industrial value for a diverse range of applications, such as optoelectronics, nanoactuation, and sensing.Read moreRead less
Synthesis of oligomers in dense carbon dioxide. The aim of the project is to develop a novel technique for the synthesis of low molecular weight polymers (oligomers) using dense carbon dioxide as a polymerisation solvent. The use of elevated pressure is the major impediment to the commercialisation of such technology. The technique proposed in this project will enable oligomers to be produced at greatly reduced operating pressures and may lead to a more general procedure for conducting other t ....Synthesis of oligomers in dense carbon dioxide. The aim of the project is to develop a novel technique for the synthesis of low molecular weight polymers (oligomers) using dense carbon dioxide as a polymerisation solvent. The use of elevated pressure is the major impediment to the commercialisation of such technology. The technique proposed in this project will enable oligomers to be produced at greatly reduced operating pressures and may lead to a more general procedure for conducting other types of polymer synthesis in dense carbon dioxide.Read moreRead less
Process for treatment of fluorine-containing synthetic greenhouse gases. It is generally agreed that increasing levels of greenhouse gases in the atmosphere are leading to higher average atmospheric temperatures. This research pursues the development of an energy-efficient, non-destructive process for transforming fluorine-containing greenhouse gases (GHGs) into valuable and environmentally benign products. The application of research will lead to the development of a new non-destructive proce ....Process for treatment of fluorine-containing synthetic greenhouse gases. It is generally agreed that increasing levels of greenhouse gases in the atmosphere are leading to higher average atmospheric temperatures. This research pursues the development of an energy-efficient, non-destructive process for transforming fluorine-containing greenhouse gases (GHGs) into valuable and environmentally benign products. The application of research will lead to the development of a new non-destructive process and will benefit Australia, socially by reducing emission of GHGs and thus protecting the environment, and economically through licensing of the technology for treatment of the growing stockpiles of synthetic GHGs.
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Optimal Ethylene Oxide Manufacturing via Advanced Process Modelling and Control. This project aims at improving plant efficiency and safety to a world's best level for the Ethylene Oxide (EO) plant of Huntsman Corporation Australia (HCA). EO is a key chemical intermediate for making polyesters (clothing, PET bottles, insulation) and surfactants. To remain globally competitive, it is essential to improve the efficiency of the plant, which has a small capacity and supports important Australian mar ....Optimal Ethylene Oxide Manufacturing via Advanced Process Modelling and Control. This project aims at improving plant efficiency and safety to a world's best level for the Ethylene Oxide (EO) plant of Huntsman Corporation Australia (HCA). EO is a key chemical intermediate for making polyesters (clothing, PET bottles, insulation) and surfactants. To remain globally competitive, it is essential to improve the efficiency of the plant, which has a small capacity and supports important Australian markets. The goals will be achieved by developing advanced operational and control strategies (through computer modeling, process optimisation and intelligent systems approach), which will assist in better understanding the process and in providing optimal HCA plant operation.Read moreRead less
An Intelligent/Smart Framework for Total Process Monitoring And Supervision. Operator failures have an adverse effect on product quality, process safety, occupational health and environmental impact. The management of abnormal operating conditions is a major responsibility and depends critically on information management. A recent report indicates that the total cost attributable to preventable losses in petrochemical companies in U.S. amounts to twenty billion dollars per year. The objective o ....An Intelligent/Smart Framework for Total Process Monitoring And Supervision. Operator failures have an adverse effect on product quality, process safety, occupational health and environmental impact. The management of abnormal operating conditions is a major responsibility and depends critically on information management. A recent report indicates that the total cost attributable to preventable losses in petrochemical companies in U.S. amounts to twenty billion dollars per year. The objective of this project is to develop the theoretical framework and implementation of an Advanced Integrated Support System (ISS) for process monitoring, data analysis and interpretation, event detection and diagnosis, and operations support in chemical and petrochemical processes manufacturing.Read moreRead less
Programming the Microstructure of 3D Printed Objects . This project aims to apply state-of-the-art living polymerisation techniques to 3D printing to efficiently produce customised polymer materials that are tailored at the molecular level. By combining computational modeling and experimental approach, fast and oxygen tolerant photoliving radical polymerisation will be developed and applied to 3D printing. These new systems will produce highly structured polymer materials with remarkable mechani ....Programming the Microstructure of 3D Printed Objects . This project aims to apply state-of-the-art living polymerisation techniques to 3D printing to efficiently produce customised polymer materials that are tailored at the molecular level. By combining computational modeling and experimental approach, fast and oxygen tolerant photoliving radical polymerisation will be developed and applied to 3D printing. These new systems will produce highly structured polymer materials with remarkable mechanical properties. The effect of nanostructure on the macroscopic material properties will be investigated. The intended outcome of this project will produce advanced materials with tailored mechanical properties via streamlined and accessible approaches.Read moreRead less
Unsteady-State Operation of Slurry and Fixed-Bed Fischer-Tropsch Reactors for Improved Process Performance. The development of efficient gas-to-liquid processes via the Fischer-Tropsch reaction is the most economically viable route for the production of non-petroleum based chemicals and environmentally-friendly fuels from abundant natural gas. This investigation proposes the exploitation of both reactor and catalyst dynamics behaviour to obtain higher hydrocarbon synthesis rate and selectivity n ....Unsteady-State Operation of Slurry and Fixed-Bed Fischer-Tropsch Reactors for Improved Process Performance. The development of efficient gas-to-liquid processes via the Fischer-Tropsch reaction is the most economically viable route for the production of non-petroleum based chemicals and environmentally-friendly fuels from abundant natural gas. This investigation proposes the exploitation of both reactor and catalyst dynamics behaviour to obtain higher hydrocarbon synthesis rate and selectivity not attainable under conventional steady-state operation. With current market conditions of about US$30/bbl for crude oil, even modest process improvements of 30-60% will make the process competitive. Whilst individual national energy policy goals are promoted, the research will further strengthen closer economic and technology ties between France and Australia.Read moreRead less
Clean technologies for the synthesis and purification of a biohybrid and biodegradable polymer. The project aims to transform an Australian industry in the forefront of the global market for manufacturing biodegradable polymers and boost export earnings derived from CO2 based biohybrid polymers. The project will develop cost-effective and clean methods for processing CO2 based polymers and demonstrate its potential for packaging and biomedical applications.
Novel Metal Carbide Catalysts For Gas-To-Liquid Conversion Processes. The development of efficient gas-to-liquid fuels processes is driven by the availability of abundant natural gas reserves and environmental advantages of synthetic liquid fuels. In this study, a new molybdenum-tungsten carbide catalyst that with excellent performance but 80 times cheaper than noble metal catalysts is proposed. It is especially attractive for industrial applications because it can be used for steam reforming of ....Novel Metal Carbide Catalysts For Gas-To-Liquid Conversion Processes. The development of efficient gas-to-liquid fuels processes is driven by the availability of abundant natural gas reserves and environmental advantages of synthetic liquid fuels. In this study, a new molybdenum-tungsten carbide catalyst that with excellent performance but 80 times cheaper than noble metal catalysts is proposed. It is especially attractive for industrial applications because it can be used for steam reforming of natural gas to synthesis gas, and subsequent conversion to gasoline. This represents huge cost savings in catalyst and energetically-efficient reactors in the global petrochemical industry where millions of dollars are spent annually on catalyst improvement and rehabilitation.Read moreRead less