Advanced Materials from Automated Synthesis of Sequence-Defined Polymers. The project aims to develop industrially scalable and environmentally friendly methods for synthesis of sequence-defined multiblock copolymers (polymer chains containing segments of different polymer types) using automated synthesis methods. The materials to be explored will be largely based on renewable biomass-derived monomeric building blocks. Such polymers are able to undergo microphase separation into spatially period ....Advanced Materials from Automated Synthesis of Sequence-Defined Polymers. The project aims to develop industrially scalable and environmentally friendly methods for synthesis of sequence-defined multiblock copolymers (polymer chains containing segments of different polymer types) using automated synthesis methods. The materials to be explored will be largely based on renewable biomass-derived monomeric building blocks. Such polymers are able to undergo microphase separation into spatially periodic compositional patterns, thereby providing access to a vast range of nano-engineered materials. This would enable design and synthesis of new advanced materials, making use of renewable resources and supporting the circular economy, with diverse potential applications ranging from nanomedicine to materials science.Read moreRead less
4D Printed Origami Structures: Deformation Mechanisms and Mechanics. This project aims to understand the physics and self-folding mechanisms of 4D printed origami structures and materials by utilising interdisciplinary approaches. This project expects to generate new knowledge in the areas of origami engineering and structural mechanics. The success of this project will form a foundation for studying shape-shifting and sequential control of smart origamis. The fundamental mechanics will be appli ....4D Printed Origami Structures: Deformation Mechanisms and Mechanics. This project aims to understand the physics and self-folding mechanisms of 4D printed origami structures and materials by utilising interdisciplinary approaches. This project expects to generate new knowledge in the areas of origami engineering and structural mechanics. The success of this project will form a foundation for studying shape-shifting and sequential control of smart origamis. The fundamental mechanics will be applied to characterise and design novel smart materials/structures with tuneable shape-morphing and mechanical performance. This should provide significant benefits to improvement of their safety, stability and reliability performance in applications such as space engineering, wearable technology and smart robotics.Read moreRead less
Multilayer Graphene Based Anti-Corrosion Polymer Coated Structures. This project aims to develop a novel multilayer graphene/polymer coating for structures exposed to corrosive environment with graphene concentration varying layer-wise to eliminate galvanic corrosion yet maintain all unique advantages owing to graphene inclusion, thus offering a cost-effective design solution with significantly improved anti-corrosion performance and remarkably enhanced safety and durability for structures. Expe ....Multilayer Graphene Based Anti-Corrosion Polymer Coated Structures. This project aims to develop a novel multilayer graphene/polymer coating for structures exposed to corrosive environment with graphene concentration varying layer-wise to eliminate galvanic corrosion yet maintain all unique advantages owing to graphene inclusion, thus offering a cost-effective design solution with significantly improved anti-corrosion performance and remarkably enhanced safety and durability for structures. Expected outcomes of this project include an innovative design, experimental data on corrosion prevention, development of reliable simulation techniques and design procedures for the proposed coating. This should provide huge benefits to Australian civil, offshore and marine engineering industry and national economy.Read moreRead less
A Novel Approach to Polymer/Nanosheet Composites and Their Fundamentals. Multifunctional Polymer/nanosheet composites have not yet been widely scaled up in polymer processing and composite industries mainly due to cost and inhaling hazard. This project proposes a novel methodology which embeds nanosheet preparation within polymer melt to both remove the inhaling hazard and lower the cost; the key is to develop two groups of nanosheet intercalation compounds which can expand at the polymer proces ....A Novel Approach to Polymer/Nanosheet Composites and Their Fundamentals. Multifunctional Polymer/nanosheet composites have not yet been widely scaled up in polymer processing and composite industries mainly due to cost and inhaling hazard. This project proposes a novel methodology which embeds nanosheet preparation within polymer melt to both remove the inhaling hazard and lower the cost; the key is to develop two groups of nanosheet intercalation compounds which can expand at the polymer processing temperature, to exfoliate and disperse nanosheets in polymers. It is expected to generate new knowledge of the structure-property relationships and fracture mechanisms of these composites, for industry to scale up this technology and to develop new product.Read moreRead less
Linking topology and rheology for designing supramolecular polymer networks. This project aims to develop a foundation for understanding how microscopic topology and intermolecular interactions control the flow behaviour of supramolecular polymer networks. Brownian dynamics algorithms will be developed to unravel the complex dynamics of the network and calibrated by comparison with carefully designed experiments. The expected outcome of the project is a quantitative framework for connecting the ....Linking topology and rheology for designing supramolecular polymer networks. This project aims to develop a foundation for understanding how microscopic topology and intermolecular interactions control the flow behaviour of supramolecular polymer networks. Brownian dynamics algorithms will be developed to unravel the complex dynamics of the network and calibrated by comparison with carefully designed experiments. The expected outcome of the project is a quantitative framework for connecting the molecular structure and energy landscape with resulting macroscopic properties. This project should yield significant benefit in the rational design of supramolecular systems in which the thermorheological properties can be tuned over a wide range of force/time scales with applications spanning from enhanced oil recovery to injectable hydrogels.Read moreRead less
Chiral synthetic macromolecules - control of sequence and stereochemistry. This project aims to assemble a library of novel chiral polymers mimicking natural peptides with precisely controlled primary structures using emerging synthetic technologies. A systematic investigation of these synthetic materials will provide an in-depth understanding of how sequence and stereochemistry influence chemical and physical properties. Employing rational design principles, desired functionality could be optim ....Chiral synthetic macromolecules - control of sequence and stereochemistry. This project aims to assemble a library of novel chiral polymers mimicking natural peptides with precisely controlled primary structures using emerging synthetic technologies. A systematic investigation of these synthetic materials will provide an in-depth understanding of how sequence and stereochemistry influence chemical and physical properties. Employing rational design principles, desired functionality could be optimised through the selective modification of polymer structure. These materials should be able to emulate the unique properties and functionality of natural peptides/proteins, making them invaluable for biochemical applications, such as molecular recognition and asymmetric catalysis.Read moreRead less
Sustainable Reversible Polymerisation. This project aims to address the problem of the current lack of efficient chemical recyclability of polymers. For the majority of polymers, no methods exist so far that are scalable and economic at the same time. To reach this aim, we will utilise a mixture of clever chemical concepts with continuous flow engineering. This project expects to generate new knowledge in the area of depolymerisation and chemical recycling methods. The expected outcome of this p ....Sustainable Reversible Polymerisation. This project aims to address the problem of the current lack of efficient chemical recyclability of polymers. For the majority of polymers, no methods exist so far that are scalable and economic at the same time. To reach this aim, we will utilise a mixture of clever chemical concepts with continuous flow engineering. This project expects to generate new knowledge in the area of depolymerisation and chemical recycling methods. The expected outcome of this project is a scalable process and its practical demonstration for full chemical recycling of various polymers used in everyday applications. This will provide a benefit to society as it allows to tackle plastic pollution problems, and creates avenues to green methods in plastic recycling.
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Data Driven Polymer Synthesis. This project aims at full digitalization of the synthesis of high-added-value materials via combination of chemistry with data science and by constructing a fully automated robotic synthesis machine. The project expects to provide the data basis for advanced artificial intelligence application and its implementation. If successful, this will enable the prediction and automatic optimization of chemical reactions, providing rapid and more precise development of new m ....Data Driven Polymer Synthesis. This project aims at full digitalization of the synthesis of high-added-value materials via combination of chemistry with data science and by constructing a fully automated robotic synthesis machine. The project expects to provide the data basis for advanced artificial intelligence application and its implementation. If successful, this will enable the prediction and automatic optimization of chemical reactions, providing rapid and more precise development of new materials. This project will provide the benefit of significantly increasing the ability of Australian industry to use novel digital chemistry tools and to create revenue by faster product development, aiding in securing the over 60 000 jobs in this industry in Australia.Read moreRead less
A platform technology for developing mesoporous polymer particles. This project aims to apply polymerisation-induced self-assembly process to develop triggerable mesoporous polymer particles as advanced functional materials for various applications. By combining this scalable process and automated synthesis technique, mesoporous polymer particles that can disassemble in response to external triggers, such as light, redox conditions and enzymes, will be developed. The knowledge gained from this r ....A platform technology for developing mesoporous polymer particles. This project aims to apply polymerisation-induced self-assembly process to develop triggerable mesoporous polymer particles as advanced functional materials for various applications. By combining this scalable process and automated synthesis technique, mesoporous polymer particles that can disassemble in response to external triggers, such as light, redox conditions and enzymes, will be developed. The knowledge gained from this research will allow researchers to fully understand the formation and evolution mechanism of inverse bicontinuous structures observed in nature and produced in synthetic labs. Importantly, the applications of these novel stimuli-responsive particles as nano-carriers and templating scaffolds will be investigated.Read moreRead less