Nanostructure Design and Toughening Mechanisms of Novel Thermosets. The research will enable a new technology to manufacture a class of novel nanostructured thermosets that will impact many application areas in Australia, such as protective surface coatings, structural adhesives and composite matrix materials for aerospace and automotive, and microelectronic devices, etc. The intellectual properties and patents generated will contribute to the overall competitiveness and productivity of Australi ....Nanostructure Design and Toughening Mechanisms of Novel Thermosets. The research will enable a new technology to manufacture a class of novel nanostructured thermosets that will impact many application areas in Australia, such as protective surface coatings, structural adhesives and composite matrix materials for aerospace and automotive, and microelectronic devices, etc. The intellectual properties and patents generated will contribute to the overall competitiveness and productivity of Australia~{!/~}s R&D. They will also provide business opportunities to develop niche markets for these new and high-value added materials on a large scale in Australia so as to maximise return and create jobs. Read moreRead less
Toughening thermosets by highly ordered nanostructures. This research will develop a new technology to manufacture a class of novel ordered nanostructured thermosets. The outcome of this project will enable many existing and new engineering applications in the transportation, construction and microelectronics industries in Australia.
Biomimetic templating radical polymerisation in nanoreactors. The aim is to develop methodology for synthesis of polymer with hitherto inaccessible control of the microstructure by free radical means, that is the molecular weight distribution and monomer sequences. This will be achieved by combining the two concepts of biomimetic templated radical polymerisation and polymerisation in nanoreactors in the form of submicron-sized micelles or droplets. Scale-up of the methodology will be developed b ....Biomimetic templating radical polymerisation in nanoreactors. The aim is to develop methodology for synthesis of polymer with hitherto inaccessible control of the microstructure by free radical means, that is the molecular weight distribution and monomer sequences. This will be achieved by combining the two concepts of biomimetic templated radical polymerisation and polymerisation in nanoreactors in the form of submicron-sized micelles or droplets. Scale-up of the methodology will be developed based on an environmentally friendly approach whereby miniemulsions are generated using carbon dioxide. Increased ability to control the polymer microstructure will enable advanced design of functional polymers with far-reaching applications in materials science, nanotechnology and nanomedicine. Read moreRead less
NANOSCALE NETWORKS OF ORGANIC POLYMER/C60 FULLERENE BLENDS FOR HIGH EFFICIENCY SOLAR CELLS. Recent demonstrations of increased efficiencies in polymer-fullerene blend plastic films provide the prospect of low cost photovoltaic elements with the potential for widespread application. Further progress with these materials is strongly indicated. We will characterise these materials at the nanoscale to make further improvements in film morphology and employ our expertise in experimental investigation ....NANOSCALE NETWORKS OF ORGANIC POLYMER/C60 FULLERENE BLENDS FOR HIGH EFFICIENCY SOLAR CELLS. Recent demonstrations of increased efficiencies in polymer-fullerene blend plastic films provide the prospect of low cost photovoltaic elements with the potential for widespread application. Further progress with these materials is strongly indicated. We will characterise these materials at the nanoscale to make further improvements in film morphology and employ our expertise in experimental investigation of transport properties to gain a more complete understanding of the electronic and photonic processes underlying photovoltaic efficiency. Australia is ideally situated geographically and has a strong tradition of inventive engineering from which we can benefit and capitalise significantly on further improvements in the materials to be investigated.Read moreRead less
Non-polyamide-based polymer membranes for efficient water processing. This project aims to develop an innovative, two-dimensional nanosheet scaffold polymerisation technique for the fabrication of advanced membranes. Membrane technology plays a key role in wastewater treatment and water desalination and purification. However, current membranes are not stable in an oxidation environment such as chlorine, which leads to significant membrane replacement costs. Through the development of new membran ....Non-polyamide-based polymer membranes for efficient water processing. This project aims to develop an innovative, two-dimensional nanosheet scaffold polymerisation technique for the fabrication of advanced membranes. Membrane technology plays a key role in wastewater treatment and water desalination and purification. However, current membranes are not stable in an oxidation environment such as chlorine, which leads to significant membrane replacement costs. Through the development of new membrane fabrication technology the project aims to produce non-polyamide-based polymer membranes with outstanding oxidation tolerance and separation properties. This will potentially simplify membrane processes, and improve water processing efficiency in wastewater treatment for power generation, and clean drinking water production.
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Functionalised biopolymers - a new class of renewable nano-engineered materials. Licella is an Australian start-up company, focusing on developing uses for the renewable resource lignocellulosic biomass; a fibrous material sourced principally from waste, such as that generated by forestry and agricultural operations. It is possible to use such waste and process it to separate the biomass components. This project proposes to modify these biomass fractions with living radical polymerisation (LPR) ....Functionalised biopolymers - a new class of renewable nano-engineered materials. Licella is an Australian start-up company, focusing on developing uses for the renewable resource lignocellulosic biomass; a fibrous material sourced principally from waste, such as that generated by forestry and agricultural operations. It is possible to use such waste and process it to separate the biomass components. This project proposes to modify these biomass fractions with living radical polymerisation (LPR) polymers to impart functionalities, such as antimicrobial properties, high tensile strengths and/or in-built photodegrability. New, high-performance sustainable materials like these will be the back-bone of the polymer/plastics industry of the future, replacing common plastics, sourced from non-renewable petrochemicals, with benign, sustainable plastics.Read moreRead less
Multiblock copolymer synthesis for nano-engineered materials. This project aims to develop methodology for environmentally friendly and industrially applicable synthesis of new types of advanced polymeric materials comprising multiblock copolymers. Polymeric materials play an important role in society with applications from bulk plastics to advanced technological applications. This would enable the creation of advanced materials with specific engineering targets and applications ranging from nan ....Multiblock copolymer synthesis for nano-engineered materials. This project aims to develop methodology for environmentally friendly and industrially applicable synthesis of new types of advanced polymeric materials comprising multiblock copolymers. Polymeric materials play an important role in society with applications from bulk plastics to advanced technological applications. This would enable the creation of advanced materials with specific engineering targets and applications ranging from nanomedicine to materials science.Read moreRead less
Linkage Infrastructure, Equipment And Facilities - Grant ID: LE0668038
Funder
Australian Research Council
Funding Amount
$175,000.00
Summary
From Fundamentals to Complex Architecture in Free-Radical Polymerisation: Designing Future Generations of Macromolecular Materials. This research will help maintain the profile of Australia as a serious player in the important field of polymer chemistry. It will lay the groundwork for the preparation of novel materials of commercial value. These materials will enable more effective use of Australia's natural resources, support the development of high value-added Australian manufacturing industri ....From Fundamentals to Complex Architecture in Free-Radical Polymerisation: Designing Future Generations of Macromolecular Materials. This research will help maintain the profile of Australia as a serious player in the important field of polymer chemistry. It will lay the groundwork for the preparation of novel materials of commercial value. These materials will enable more effective use of Australia's natural resources, support the development of high value-added Australian manufacturing industries, and find application in human and animal medicine. They will enhance the health and well-being of the Australian community and engender a sense of wonder in susceptible members of this community.Read moreRead less
Novel Complex Architecture Polymers via a Combination of RAFT Chemistry and Pericyclic Reactions: Synthesis and Characterization. The project aims at advancing the synthetic limits and broadening the synthetic scope of living free radical polymerization and thus enhancing the library of polymer structures available for applications ranging from drug delivery to opto-electronics. Current material design for these applications is yet to reach its full potential through innovative synthetic approac ....Novel Complex Architecture Polymers via a Combination of RAFT Chemistry and Pericyclic Reactions: Synthesis and Characterization. The project aims at advancing the synthetic limits and broadening the synthetic scope of living free radical polymerization and thus enhancing the library of polymer structures available for applications ranging from drug delivery to opto-electronics. Current material design for these applications is yet to reach its full potential through innovative synthetic approaches. The proposal critically underpins and further advances Australia's leading position in both breakthrough science as well as advanced materials. Due to its significant scientific breadth and large coverage of both synthetic and physical aspects of polymer science, the project also provides a significant platform for research training at both honours and PhD level.Read moreRead less