Tailoring metal-organic framework catalysts for carbon dioxide conversion. Reducing the greenhouse gas, CO2, into valuable fuels would be beneficial for relieving energy shortage and improving global sustainability. This project aims to synthesise high-performance heterogeneous catalysts for CO2 conversion by periodic ordering photo-redox metalloligand and thermal-catalytically active metal oxide clusters in metal-organic frameworks (MOFs). This approach is expected to deliver a unique single-si ....Tailoring metal-organic framework catalysts for carbon dioxide conversion. Reducing the greenhouse gas, CO2, into valuable fuels would be beneficial for relieving energy shortage and improving global sustainability. This project aims to synthesise high-performance heterogeneous catalysts for CO2 conversion by periodic ordering photo-redox metalloligand and thermal-catalytically active metal oxide clusters in metal-organic frameworks (MOFs). This approach is expected to deliver a unique single-site metal-organic framework catalyst with high reaction-activity and chemo-selectivity in converting CO2 into valuable chemicals. This advancement will provide significant benefits for Australia’s emerging chemical manufacturing industry, and ultimately leading to a carbon-neutral energy economy and environment.Read moreRead less
Novel Hybrid Nanotechnologies by Infiltration of Functional Polymers. Hybrid inorganic-organic materials have important applications in energy, environmental and health technologies. Sequential infiltration synthesis (SIS) of polymers is a recently introduced approach to preparing such hybrid structures. Advancement in the field is however hampered by lack of fundamental understanding of the mechanisms of interactions of SIS molecules with polymers, and the narrow range of polymers studied so fa ....Novel Hybrid Nanotechnologies by Infiltration of Functional Polymers. Hybrid inorganic-organic materials have important applications in energy, environmental and health technologies. Sequential infiltration synthesis (SIS) of polymers is a recently introduced approach to preparing such hybrid structures. Advancement in the field is however hampered by lack of fundamental understanding of the mechanisms of interactions of SIS molecules with polymers, and the narrow range of polymers studied so far. This project aims to build a fundamental framework for the development of SIS through systematic studies of interactions of polymers and SIS molecules. Expected outcomes include new methods for constructing nanostructures using functional polymers and novel fabrication processes exploiting polymer self-assembly.Read moreRead less
Carbon fibre thermoplastics as next-generation carbon fibre composites. By combining sizing, chemical grafting, and nano-reinforcement strategies, this project develops chemically and thermally robust thermoplastic interfacial sizing for carbon fiber/thermoplastic composites for rapid manufacturing. Thermostamped carbon fiber/thermoplastic composite prototypes will be used to verify the sizing. In order to demonstrate industrial viability, recyclability and reprocessability analyses will be cond ....Carbon fibre thermoplastics as next-generation carbon fibre composites. By combining sizing, chemical grafting, and nano-reinforcement strategies, this project develops chemically and thermally robust thermoplastic interfacial sizing for carbon fiber/thermoplastic composites for rapid manufacturing. Thermostamped carbon fiber/thermoplastic composite prototypes will be used to verify the sizing. In order to demonstrate industrial viability, recyclability and reprocessability analyses will be conducted. This sizing method can enable high-performance thermoplastic composites in nonaerospace applications with its atomistic level modelling and comprehensive characterisation routine. A key objective of this study is to produce sustainably manufactured composite materials that are also commercially relevant.Read moreRead less
Next-generation lithography: photo-directing assembly of block copolymers. This project aims to introduce a novel approach to organising block polymers through the photochemical modification of the surface of a photo-sensitive polymer. Chemo-epitaxy is the science of organising materials on a surface decorated with chemical patterns. The process has the potential to revolutionise the manufacture of integrated circuits, enabling faster processors. This project expects to introduce innovative conc ....Next-generation lithography: photo-directing assembly of block copolymers. This project aims to introduce a novel approach to organising block polymers through the photochemical modification of the surface of a photo-sensitive polymer. Chemo-epitaxy is the science of organising materials on a surface decorated with chemical patterns. The process has the potential to revolutionise the manufacture of integrated circuits, enabling faster processors. This project expects to introduce innovative concepts in polymer chemistry and nanoscale assembly with the potential to advance a multi-billion-dollar industry.Read moreRead less
Fluid Transport in Materials of Nanoscale Dimensions. This project aims to transform the modelling of fluid transport in materials of nanoscale dimension by determining the coupled interfacial heat and mass-transfer barriers, which critically influence the transport. The outcome will not only be new knowledge on the effects of inherent structural distortion and of the barriers on the fluid flow, but also cutting-edge techniques to estimate system size-dependent transport coefficients in nanoscal ....Fluid Transport in Materials of Nanoscale Dimensions. This project aims to transform the modelling of fluid transport in materials of nanoscale dimension by determining the coupled interfacial heat and mass-transfer barriers, which critically influence the transport. The outcome will not only be new knowledge on the effects of inherent structural distortion and of the barriers on the fluid flow, but also cutting-edge techniques to estimate system size-dependent transport coefficients in nanoscale systems. These will be achieved through a combination of targeted molecular dynamics simulations and experiment, and will have far-reaching implications for nanotechnology and emerging processes in catalysis, gas separation, human health and nanofluidics, and enable design of more efficient systems.Read moreRead less