Discovery Early Career Researcher Award - Grant ID: DE130100770
Funder
Australian Research Council
Funding Amount
$325,375.00
Summary
Lignin in ionic liquids: electrochemical approaches towards delignification and depolymerisation. Wood contains a wealth of biomaterials, such as cellulose which can be used to make biofuel and lignin which can be used to make pharmaceuticals. Separating out the cellulose is essential yet difficult, plus lignin must be broken up into smaller fragments; this project will look at using electrochemistry to achieve these processes more efficiently.
Discovery Early Career Researcher Award - Grant ID: DE210100053
Funder
Australian Research Council
Funding Amount
$428,710.00
Summary
Computational Discovery & Design of New Catalytic Halogenophilic Reactions. Computational chemistry will be used to discover and predict new halogenophilic (halogeno = halogen; philic = like) substitution reactions (SN2X) catalysed by positively charged (cationic) catalysts. SN2X is a less known substitution reaction compared to accepted textbook nucleophilic (nucleo = electron-rich) substitution reactions. This proposal capitalises on previous theoretical-experimental understanding of a cation- ....Computational Discovery & Design of New Catalytic Halogenophilic Reactions. Computational chemistry will be used to discover and predict new halogenophilic (halogeno = halogen; philic = like) substitution reactions (SN2X) catalysed by positively charged (cationic) catalysts. SN2X is a less known substitution reaction compared to accepted textbook nucleophilic (nucleo = electron-rich) substitution reactions. This proposal capitalises on previous theoretical-experimental understanding of a cation-catalysed SN2X to develop new chemical reactions using SN2X synthetic strategies to access difficult-to-make molecules of potential medicinal relevance with heavily substituted carbon-carbon and carbon heteroatom bonds. Read moreRead less
On-water catalysis for green chemistry. The on-water effect enables acid-catalysed organic reactions to be conducted as emulsions in water, instead of dissolved in expensive and often toxic organic solvents. This research will define the scope and limitations of the effect, allowing predictions about the extent of its applicability in green chemistry using water and renewable feedstocks.