THEORETICAL AND EXPERIMENTAL STUDIES OF BLOCK COPOLYMER MELTS AS NANO-MATERIALS. We shall theoretically study and predict the possible morphologies of a wide range of block copolymer architectures with a combination of simulations and accurate numerical theories. These block copolymer melts are of great technological importance because they can self-assemble into morphological patterns which are periodic on a nano-scale. Hence they are now being intensively investigated for uses in applications ....THEORETICAL AND EXPERIMENTAL STUDIES OF BLOCK COPOLYMER MELTS AS NANO-MATERIALS. We shall theoretically study and predict the possible morphologies of a wide range of block copolymer architectures with a combination of simulations and accurate numerical theories. These block copolymer melts are of great technological importance because they can self-assemble into morphological patterns which are periodic on a nano-scale. Hence they are now being intensively investigated for uses in applications as diverse as lithographic templates for electronic and optical devices, nano-porous membranes and photonic band gap materials. We shall verify our theoretical predictions by carrying out experiments on the various molecular architectures that we have studied theoretically.Read moreRead less
New Types of Biomimetic Nanostructured Adhesives. Adhesives are one of the main ways in which we join materials, and have many advantages over other methods of joining. In this work we will make a new class of adhesive using nanotechnology that attempts to copy the very fine-haired feet of animals such as geckos who can stick to almost any surface, under most conditions. We will make these adhesives over large surface areas, and thus they will have commercial possibilities in a range of high tec ....New Types of Biomimetic Nanostructured Adhesives. Adhesives are one of the main ways in which we join materials, and have many advantages over other methods of joining. In this work we will make a new class of adhesive using nanotechnology that attempts to copy the very fine-haired feet of animals such as geckos who can stick to almost any surface, under most conditions. We will make these adhesives over large surface areas, and thus they will have commercial possibilities in a range of high technology industries, as well as in harsh environments. Because we will be able to manipulate the structure and observe property changes, it should also give us a greater insight into the adhesion mechanisms used by many small animals and bugs.Read moreRead less
Nanofabrication of Organic (Plastic) Semiconductor and Superconductor Devices. Organic crystals and thin-films are the first known materials to display all four regimes of electrical conduction - insulator, semiconductor, metal and superconductor. Additional properties such as self-assembly, biocompatibility, molecular level control over properties and flexibility give them exceptional prospects for future industrial applications. We will fabricate organic transistors and conduct detailed invest ....Nanofabrication of Organic (Plastic) Semiconductor and Superconductor Devices. Organic crystals and thin-films are the first known materials to display all four regimes of electrical conduction - insulator, semiconductor, metal and superconductor. Additional properties such as self-assembly, biocompatibility, molecular level control over properties and flexibility give them exceptional prospects for future industrial applications. We will fabricate organic transistors and conduct detailed investigations of their electrical and magnetic properties to develop a fundamental understanding of these new materials. Most significantly, we will make the first use of an atomic force microscope-based oxidation lithography technique to fabricate nanoscale quantum devices that exploit the full range of conduction in a single material.Read moreRead less
Tailoring metal-organic framework catalysts for carbon dioxide conversion. Reducing the greenhouse gas, CO2, into valuable fuels would be beneficial for relieving energy shortage and improving global sustainability. This project aims to synthesise high-performance heterogeneous catalysts for CO2 conversion by periodic ordering photo-redox metalloligand and thermal-catalytically active metal oxide clusters in metal-organic frameworks (MOFs). This approach is expected to deliver a unique single-si ....Tailoring metal-organic framework catalysts for carbon dioxide conversion. Reducing the greenhouse gas, CO2, into valuable fuels would be beneficial for relieving energy shortage and improving global sustainability. This project aims to synthesise high-performance heterogeneous catalysts for CO2 conversion by periodic ordering photo-redox metalloligand and thermal-catalytically active metal oxide clusters in metal-organic frameworks (MOFs). This approach is expected to deliver a unique single-site metal-organic framework catalyst with high reaction-activity and chemo-selectivity in converting CO2 into valuable chemicals. This advancement will provide significant benefits for Australia’s emerging chemical manufacturing industry, and ultimately leading to a carbon-neutral energy economy and environment.Read moreRead less
The development of super-toughened epoxies using a novel nanomaterial. Epoxy resins are widely used as structural adhesives and coatings in engineering structures. This project will address the problem of the intrinsic brittleness of epoxy by making it significantly tougher with superior performance and cost-effectiveness. Our technology for producing super-toughened epoxy will lead to a wide range of applications for new and existing products in the construction, automotive, aerospace, adhesive ....The development of super-toughened epoxies using a novel nanomaterial. Epoxy resins are widely used as structural adhesives and coatings in engineering structures. This project will address the problem of the intrinsic brittleness of epoxy by making it significantly tougher with superior performance and cost-effectiveness. Our technology for producing super-toughened epoxy will lead to a wide range of applications for new and existing products in the construction, automotive, aerospace, adhesive and microelectronics industries.Read moreRead less
Heterogeneous hydrophilic catalysts for green oxidation in bio-refining. The project aims to address one significant global challenge of developing green processes for producing high value chemicals from biomass, to enhance the environmental performance and cost-efficiency of bio-refining. This project aims to develop a new class of heterogeneous nanocatalysts with hydrophilic Co (salen) complexes for biomass oxidation in water rather than toxic solvent. This project will use this to devise prac ....Heterogeneous hydrophilic catalysts for green oxidation in bio-refining. The project aims to address one significant global challenge of developing green processes for producing high value chemicals from biomass, to enhance the environmental performance and cost-efficiency of bio-refining. This project aims to develop a new class of heterogeneous nanocatalysts with hydrophilic Co (salen) complexes for biomass oxidation in water rather than toxic solvent. This project will use this to devise practical routes for the production of targeted industrial components for flavours, fragrances, fine chemicals, and petrochemicals. The development of heterogeneous hydrophilic catalysts by which they will oxidise hydrophilic biomasses in a continuous flow system will dramatically improve the sustainability of the chemical industry.Read moreRead less
Next generation easy-clean lenses by robust liquid-repellent nanotextures. This project aims to produce better performing self-cleaning lenses, which are less likely to get dirty and are easy to clean. It will develop water and oil repellent coatings with superior optical transparency and mechanical, solvent and UV stability for both hard coated and anti-reflection coated optical lenses. Engineering of stable, ultra-liquid repellent nanomaterials on transparent surfaces will create a foundation ....Next generation easy-clean lenses by robust liquid-repellent nanotextures. This project aims to produce better performing self-cleaning lenses, which are less likely to get dirty and are easy to clean. It will develop water and oil repellent coatings with superior optical transparency and mechanical, solvent and UV stability for both hard coated and anti-reflection coated optical lenses. Engineering of stable, ultra-liquid repellent nanomaterials on transparent surfaces will create a foundation of knowledge for the industrial development of the future generation of easy care coatings, with vast application potential.Read moreRead less
Characterisation and Modelling of Nanostructured Soft Magnetic Materials for Advanced Electromagnetic Applications. This project bridges the gap between nanomagnetic materials and practical applications. The knowledge generated and the international collaborations with world class scientists established through this cutting-edge research project will strengthen the leading status of Australia in the field of nanoscience and nanotechnology. The research outcomes will stimulate the growth of world ....Characterisation and Modelling of Nanostructured Soft Magnetic Materials for Advanced Electromagnetic Applications. This project bridges the gap between nanomagnetic materials and practical applications. The knowledge generated and the international collaborations with world class scientists established through this cutting-edge research project will strengthen the leading status of Australia in the field of nanoscience and nanotechnology. The research outcomes will stimulate the growth of world class Australian industries and hence the national economy through the commercial manufacturing of hi-tech nanomagnetic materials and innovative smart devices and systems. High quality PhD and honours project students will be trained.Read moreRead less
Self-organised complex ionised gas systems for ordered nanometre-scale assemblies. This proposal is to develop the physical principles of nano-scale assembly processes in complex plasmas. Novel approaches for tailoring the plasma-grown building blocks and controllable deposition of ordered nanoparticle arrays on nanopatterned solids are targeted. The fundamentals of the multi-scale dynamic processes will be elucidated and existing techniques for developing new materials and electronic/photonic d ....Self-organised complex ionised gas systems for ordered nanometre-scale assemblies. This proposal is to develop the physical principles of nano-scale assembly processes in complex plasmas. Novel approaches for tailoring the plasma-grown building blocks and controllable deposition of ordered nanoparticle arrays on nanopatterned solids are targeted. The fundamentals of the multi-scale dynamic processes will be elucidated and existing techniques for developing new materials and electronic/photonic devices will be advanced. The expected outcomes are highly relevant for the nano-materials and optoelectronic technologies, rapidly emerging areas of high-tech industries worldwide.Read moreRead less
CNTs-modified polymer composites for tribological applications. The growth of the Australian economy relies on continuous improvements in all sectors of production, manufacturing, operation and management where tribology is playing a significant role. System failure relevant to wear and friction over years and its impact on the Australian economy have continued to be a challenge for the community in the new century. The project is at the forefront of materials research, and the outcomes will pro ....CNTs-modified polymer composites for tribological applications. The growth of the Australian economy relies on continuous improvements in all sectors of production, manufacturing, operation and management where tribology is playing a significant role. System failure relevant to wear and friction over years and its impact on the Australian economy have continued to be a challenge for the community in the new century. The project is at the forefront of materials research, and the outcomes will provide (1) novel technical ways to optimise tribological performance of industrial contacting components, and (2) development of new wear resistant materials. The project will give Australia a competitive edge in the advances of tribology and nanotechnologyRead moreRead less