A new methodology for the measurement of transition metals ions in complex, high temperature oxide systems relevant to non-ferrous metal production. Complex multi-component molten oxide phases, known commonly as slags, are used in the high temperature production and refining of metals. The slag systems of commercial interest contain transition metals species, such as, Fe2+, Fe3+. Each of these species behaves as if it were a separate chemical component. Researchers at the University of Queensla ....A new methodology for the measurement of transition metals ions in complex, high temperature oxide systems relevant to non-ferrous metal production. Complex multi-component molten oxide phases, known commonly as slags, are used in the high temperature production and refining of metals. The slag systems of commercial interest contain transition metals species, such as, Fe2+, Fe3+. Each of these species behaves as if it were a separate chemical component. Researchers at the University of Queensland have developed a new methodolgy, which enables the concentrations of these transition metal ions to be measured.
These types of measurements cannot be made with any of the techniques currently in use. The study will provide data on high temperature slags in a number of industrially and scientifically important systems. This approach will be applicable to a wide range of chemical systems in the fields of extractive metallurgy, materials science and geology; systems which could not previously be characterised.Read moreRead less
Step Change Technologies in Ironmaking - Slag Compositions for Use in the New Low Energy Blast Furnace Practice. The world's current iron and steelmaking production capacity is over 200 million tonnes annually; this is set to rapidly rise with the increasing production in China and in India. Australia is a major exporter and supplier of iron ores and coal and coke to the South East Asian region. It is in Australia's National interest to encourage improvements in these technologies not only to in ....Step Change Technologies in Ironmaking - Slag Compositions for Use in the New Low Energy Blast Furnace Practice. The world's current iron and steelmaking production capacity is over 200 million tonnes annually; this is set to rapidly rise with the increasing production in China and in India. Australia is a major exporter and supplier of iron ores and coal and coke to the South East Asian region. It is in Australia's National interest to encourage improvements in these technologies not only to increase export income but also to contribute to improved environmental performance. The proposed project will assist in the development of a modified iron blast furnace, and in so doing substantially reduce the energy consumption and CO2 emissions from the process.Read moreRead less
The Physicochemical Properties of Complex Silicate Melts - Application of a New Quasichemical Model to Surface Tension Prediction. Most chemical reactions occur at surfaces or interfaces. The contact area and ease in which fluids spread or cover surfaces depends critically on the surface tension or surface energy of the fluid.
In the processing of metals and advanced ceramic materials the behaviour of molten oxides can greatly influence the rates of reactions, the quality of the interfaces bet ....The Physicochemical Properties of Complex Silicate Melts - Application of a New Quasichemical Model to Surface Tension Prediction. Most chemical reactions occur at surfaces or interfaces. The contact area and ease in which fluids spread or cover surfaces depends critically on the surface tension or surface energy of the fluid.
In the processing of metals and advanced ceramic materials the behaviour of molten oxides can greatly influence the rates of reactions, the quality of the interfaces between phases and therefore mechanical and other key properties of advanced materials produced.
This project provides a means of predicting the surface tensions of molten oxides, making it possible to design, control and improve metal and material manufacturing processes.Read moreRead less
ECOLOGICALLY SAFE RECYCLING OF ELECTRONIC SCRAP - CHEMICAL THERMODYNAMICS OF NOVEL HIGH TEMPERATURE PROCESSING TECHNOLOGY. As a developed industrialized society we are faced with increasing problems associated with the obsolete electronic materials. These materials are classed as hazardous wastes because they contain heavy metals and other elements that must be removed or made chemically inert before they can be disposed of safely. Electronic components however also represent a source of valuabl ....ECOLOGICALLY SAFE RECYCLING OF ELECTRONIC SCRAP - CHEMICAL THERMODYNAMICS OF NOVEL HIGH TEMPERATURE PROCESSING TECHNOLOGY. As a developed industrialized society we are faced with increasing problems associated with the obsolete electronic materials. These materials are classed as hazardous wastes because they contain heavy metals and other elements that must be removed or made chemically inert before they can be disposed of safely. Electronic components however also represent a source of valuable elements that can be recovered and reused. The project will assist in finding safe, cost-efficient ways in which we can process these materials and, at the same time, recover the valuable metals contained within them. The project will thus contribute to the sustainable use of our raw materials and a cleaner environment.Read moreRead less
Development of an efficient oxygen-thiosulfate process for the recovery of gold from ores. Gold is currently recovered from the ore by a cyanide leaching process. This high risk procedure is used because there is currently no safe alternative. The research we propose to undertake will investigate a novel thiosulfate-oxygen process to dissolve gold. Successful completion of the project will identify the mechanism of the process and could lead to the replacement of the highly toxic cyanide with th ....Development of an efficient oxygen-thiosulfate process for the recovery of gold from ores. Gold is currently recovered from the ore by a cyanide leaching process. This high risk procedure is used because there is currently no safe alternative. The research we propose to undertake will investigate a novel thiosulfate-oxygen process to dissolve gold. Successful completion of the project will identify the mechanism of the process and could lead to the replacement of the highly toxic cyanide with the non toxic thiosulfate. Thus the proposed project has the potential to substantially alter the gold recovery process, particularly in an era where environmental and public concerns exist over the use of cyanide.Read moreRead less
Anisotropy of strengthening by solid solution and precipitation in concentrated Mg-Al and Mg-Zn alloys. The addition of solute increases the strength of Mg in some crystallographic directions but weakens the material in others. The weakening is called solid solution softening, and it can have profound effects on the mechanical behaviour of the material. Solid solution softening has been observed in the prismatic planes of single crystals of dilute Mg-Al and Mg-Zn alloys. Easier prismatic slip lo ....Anisotropy of strengthening by solid solution and precipitation in concentrated Mg-Al and Mg-Zn alloys. The addition of solute increases the strength of Mg in some crystallographic directions but weakens the material in others. The weakening is called solid solution softening, and it can have profound effects on the mechanical behaviour of the material. Solid solution softening has been observed in the prismatic planes of single crystals of dilute Mg-Al and Mg-Zn alloys. Easier prismatic slip lowers the strain hardening rate and increases the ductility of polycrystalline alloys in comparison with pure Mg. Despite their obvious significance, these effects have not been studied in single crystals of concentrated alloys. This is the main object of this project.Read moreRead less
Hybrid cathode for low temperature solid oxide fuel cells. This project aims to develop molten carbonate-perovskite hybrid cathode materials for low temperature solid oxide fuel cells (LT-SOFCs) possessing both high catalytic activity towards oxygen reduction reaction (ORR) and high tolerance to carbon dioxide poisoning. Carbon dioxide in air can poison nearly all the perovskite cathode materials developed for LT-SOFCs (below 600 degrees C) so far. These materials will not be practically useful ....Hybrid cathode for low temperature solid oxide fuel cells. This project aims to develop molten carbonate-perovskite hybrid cathode materials for low temperature solid oxide fuel cells (LT-SOFCs) possessing both high catalytic activity towards oxygen reduction reaction (ORR) and high tolerance to carbon dioxide poisoning. Carbon dioxide in air can poison nearly all the perovskite cathode materials developed for LT-SOFCs (below 600 degrees C) so far. These materials will not be practically useful until carbon dioxide poisoning can be prevented. This project expects to make these LT-SOFC cathode materials commercially viable, solving a problem for the widespread use of low temperature solid oxide fuel cells.Read moreRead less
High Performance Anode for Direct Ammonia Solid Oxide Fuel Cells. Solid oxygen fuel cells are a clean energy generation device with very high energy efficiency and if with hydrogen as fuel, the emission is zero. However, the utilisation of hydrogen is limited by on-board storage. Ammonia is a promising hydrogen carrier and can be directly fed to solid oxide fuel cells without fuel storage problem, and the products are just hydrogen and nitrogen. For direct ammonia solid oxide fuel cells, the key ....High Performance Anode for Direct Ammonia Solid Oxide Fuel Cells. Solid oxygen fuel cells are a clean energy generation device with very high energy efficiency and if with hydrogen as fuel, the emission is zero. However, the utilisation of hydrogen is limited by on-board storage. Ammonia is a promising hydrogen carrier and can be directly fed to solid oxide fuel cells without fuel storage problem, and the products are just hydrogen and nitrogen. For direct ammonia solid oxide fuel cells, the key challenge is the anode. This project aims to develop a high performance anode for direct ammonia solid oxide fuel cells with both high activity and high stability at low temperature (below 600 degree C), thus addressing a key issue to make the direct ammonia solid oxide fuel cells commercially viable.Read moreRead less
Composites for thermal expansion matched oxygen electrodes. This project aims to develop high performance composite oxygen electrodes by using both negative thermal expansion materials and electrolyte materials to tailor the thermal expansion and activities of the perovskite-based electrodes for use in reduced temperature solid oxide cells. Such composite electrodes will show highly matched thermal expansion with electrolyte without sacrificing high activity at reduced temperatures. This project ....Composites for thermal expansion matched oxygen electrodes. This project aims to develop high performance composite oxygen electrodes by using both negative thermal expansion materials and electrolyte materials to tailor the thermal expansion and activities of the perovskite-based electrodes for use in reduced temperature solid oxide cells. Such composite electrodes will show highly matched thermal expansion with electrolyte without sacrificing high activity at reduced temperatures. This project seeks to address an important practical issue in the operation of solid oxide power cells - thermal expansion compatibility, which causes poor efficiency outside a narrow temperature band.Read moreRead less
A defect mechanism for oxygen reduction reaction. This project aims to use defective carbon to replace expensive platinum as a catalyst for oxygen reduction reaction (ORR) in fuel cells. Defective carbons incorporating non-precious metals are better than platinum in terms of over-potential, current density and number of electron transfer. They reduce the overall fuel cell cost but their better stability and higher open voltage and power density promise huge commercial benefit. This project is ex ....A defect mechanism for oxygen reduction reaction. This project aims to use defective carbon to replace expensive platinum as a catalyst for oxygen reduction reaction (ORR) in fuel cells. Defective carbons incorporating non-precious metals are better than platinum in terms of over-potential, current density and number of electron transfer. They reduce the overall fuel cell cost but their better stability and higher open voltage and power density promise huge commercial benefit. This project is expected to be important for large-scale implementation of fuel cells.Read moreRead less