Unravelling the dominant drivers of ion specificity. This project aims to understand what governs the sensitivity of many technological and biological processes to the precise nature of the salt present in solution. The term ‘ion-specific’ encompasses all the circumstances in which the influence of a salt in solution depends on the precise chemical nature of the salt, not just the electrical charge on the ions that form the salt. As such, ion-specific effects abound and have important consequenc ....Unravelling the dominant drivers of ion specificity. This project aims to understand what governs the sensitivity of many technological and biological processes to the precise nature of the salt present in solution. The term ‘ion-specific’ encompasses all the circumstances in which the influence of a salt in solution depends on the precise chemical nature of the salt, not just the electrical charge on the ions that form the salt. As such, ion-specific effects abound and have important consequences in most situations involving solutions, including cellular functions and battery technology. This project will enable us to understand and control the influence of specific ions, building on our recently described fundamental ion-specific series with colloid science experiments and quantum simulations. This project should overcome current challenges in predicting ion-specific effects leading to progress in a wide variety of applications of colloid and interface science, from sensor interfaces to self-assembly.Read moreRead less
Switchable and stereocontrolled photoredox catalysis. This project aims to develop new catalytic synthetic reactions for the rapid and more direct functionalisation of organic compounds under mild conditions with the use of visible light. An integrated experimental and computational approach will be used to design potent visible-light photocatalysts that retain the advantages of standard photoredox catalysis but with the added ability to intercept and, thus control, reactive intermediates in sit ....Switchable and stereocontrolled photoredox catalysis. This project aims to develop new catalytic synthetic reactions for the rapid and more direct functionalisation of organic compounds under mild conditions with the use of visible light. An integrated experimental and computational approach will be used to design potent visible-light photocatalysts that retain the advantages of standard photoredox catalysis but with the added ability to intercept and, thus control, reactive intermediates in situ. This will enable the control of stereochemistry in photoredox reactions – not possible with standard catalysts - and establish other useful synthetic transformations. These strategies will make it easier to prepare valuable classes of organic molecules – efficiently, safely, and cost-effectively.
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Ubiquity of K-theory and T-duality. An abstract mathematical tool, called K-theory, has recently found application in two, not obviously related, areas of physics: the classification of D-branes in String Theory, and topological phases in Condensed Matter Theory. This project aims to advance the development of K-theory using ideas from physics. In particular, the project aims to generalise previous constructions, such as T-duality, to loop spaces, and to develop the K-theory relevant to the clas ....Ubiquity of K-theory and T-duality. An abstract mathematical tool, called K-theory, has recently found application in two, not obviously related, areas of physics: the classification of D-branes in String Theory, and topological phases in Condensed Matter Theory. This project aims to advance the development of K-theory using ideas from physics. In particular, the project aims to generalise previous constructions, such as T-duality, to loop spaces, and to develop the K-theory relevant to the classification of topological phases in strongly interacting systems. This project involves postgraduate training as a crucial tool in achieving its aims and enhances Australia's position at the forefront of international research.Read moreRead less
Applications of generalised geometry to duality in quantum theory. This project will undertake research into mathematics at the forefront of modern physics. The aim of the project is to develop a mathematical theory of T-duality, a phenomenon in quantum physics, using generalised geometry.
New Horizons in Quinonedimethide Chemistry. Quinonedimethides (QDMs) are organic molecules with a notorious reputation for instability, hence they are poorly understood and an underexploited resource. This project will unite the ideally suited computational and experimental skills of the CIs to perform the first thorough investigation into fundamental QDM chemistry. It aims to map structure-reactivity in QDMs, investigate their ability to rapidly generate complex structures, and demonstrate thei ....New Horizons in Quinonedimethide Chemistry. Quinonedimethides (QDMs) are organic molecules with a notorious reputation for instability, hence they are poorly understood and an underexploited resource. This project will unite the ideally suited computational and experimental skills of the CIs to perform the first thorough investigation into fundamental QDM chemistry. It aims to map structure-reactivity in QDMs, investigate their ability to rapidly generate complex structures, and demonstrate their potential in spintronics and other applications. Anticipated outcomes include powerful and general new synthetic concepts, methods, strategies and tactics. This should provide significant benefits, such as better ways to manufacture important medicines and other materials.Read moreRead less
Supersymmetric quantum field theory, topology and duality. Supersymmetry is universally considered as one of the most fundamental concepts in physics, playing an increasingly central role in recent studies of quantum field theory and string theory. There is a corresponding development of supersymmetry in mathematics and this project will make advances both in 'superphysics' and 'supermathematics'.
Deciphering ion specificity in complex electrolytes . This project aims to understand how ions influence the behaviour and properties of complex electrolytes (solutions containing either multiple ions, solvent mixtures, high electrolyte concentrations or a variety of interfaces, solutes or polymers). Complex electrolytes are ubiquitous in colloidal and particle technologies and underpin industrial and natural processes. Our team will combine experiment, simulation and theory to deliver a univers ....Deciphering ion specificity in complex electrolytes . This project aims to understand how ions influence the behaviour and properties of complex electrolytes (solutions containing either multiple ions, solvent mixtures, high electrolyte concentrations or a variety of interfaces, solutes or polymers). Complex electrolytes are ubiquitous in colloidal and particle technologies and underpin industrial and natural processes. Our team will combine experiment, simulation and theory to deliver a universal framework for understanding and predicting specific ion effects in complex electrolytes. The project outcomes are expected to deliver new understanding for researchers, robust rules of thumb for technologists and a public resource for data-driven solutions in applications utilising salt solutions. Read moreRead less
Design and synthesis of operating molecular machines and solution and solid-state devices. This project involves the construction of machines and other devices engineered at the molecular level, which therefore offer a greater degree of miniaturisation and sophistication than their macro-engineered counterparts. The work is expected to provide fundamental advances in nanotechnology and underpin new industries based on advanced materials.
Responsive nanoporous organic cages. This project will generate advanced materials that are constructed from functional nanoscale building blocks. The general design principles developed in this work will be utilised to synthesise a nanoporous adsorbent system that is able to self regulate its physical properties through dynamic structural responses to its environment.
Foundations of the nuclear force, nuclear structure and dynamics. This project aims to investigate a profound problem in physics: the structure and interactions of atomic nuclei in terms of their microscopic constituents. It is expected to generate new knowledge and improve our understanding of the structure and dynamics of nuclei, their formation in the cosmos, neutron star properties, and underpin future nuclear technologies. The project aims to leverage Australian capacity in nuclear theory t ....Foundations of the nuclear force, nuclear structure and dynamics. This project aims to investigate a profound problem in physics: the structure and interactions of atomic nuclei in terms of their microscopic constituents. It is expected to generate new knowledge and improve our understanding of the structure and dynamics of nuclei, their formation in the cosmos, neutron star properties, and underpin future nuclear technologies. The project aims to leverage Australian capacity in nuclear theory to produce the first predictive model with a modern realistic nuclear interaction. Significant benefits include an enhancement of research training capacity and new international links with the world's major laboratories. Read moreRead less