Chlorine Evolution Catalysts for Efferent Seawater Electrolysis. Seawater is the most abundant aqueous resource on earth that is readily accessible at very low costs, but yet to be directly utilised for production of hydrogen fuel and commodity chemicals. This project aims to develop cheap and plentiful carbon-based high performance chlorine evolution electrocatalysts for seawater electrolysis powered by renewable electricity to realise the production of hydrogen, chlorine and sodium hydroxide d ....Chlorine Evolution Catalysts for Efferent Seawater Electrolysis. Seawater is the most abundant aqueous resource on earth that is readily accessible at very low costs, but yet to be directly utilised for production of hydrogen fuel and commodity chemicals. This project aims to develop cheap and plentiful carbon-based high performance chlorine evolution electrocatalysts for seawater electrolysis powered by renewable electricity to realise the production of hydrogen, chlorine and sodium hydroxide directly from seawater. The electrolyser can also be used to treat desalination brine while produce hydrogen and chemicals. The success of the project will set a firm technological foundation for seawater utilisation, which will add to Australian capability to meet future energy and environment challenges.Read moreRead less
Plasmonic nanoparticle catalysis for nitrogen-based synthesis. Light can generate an optical force to capture small objects. This requires intense light – a laser, which limits optical trapping in catalysis applications. This project aims to apply plasmonic nanoparticles with normal-intensity light to take advantage of plasmonic-generated optical forces for catalytic chemical synthesis. The optical trapping/releasing of small molecules is highly selective and responsive to molecule structure and ....Plasmonic nanoparticle catalysis for nitrogen-based synthesis. Light can generate an optical force to capture small objects. This requires intense light – a laser, which limits optical trapping in catalysis applications. This project aims to apply plasmonic nanoparticles with normal-intensity light to take advantage of plasmonic-generated optical forces for catalytic chemical synthesis. The optical trapping/releasing of small molecules is highly selective and responsive to molecule structure and so presents a great opportunity to radically alter chemical synthesis pathways, which will be illustrated with reactions on liquid-solid and gas-solid interfaces. This highly innovative strategy will be used to discover new nitrogen-based syntheses which are both fundamentally and industrially important.Read moreRead less
Nanostructured solid acid catalysts for sustainable chemical manufacturing. This project aims to develop next-generation solid acid catalysts for energy- and atom-efficient transformations of waste biomass and carbon dioxide to sustainable chemicals and fuels. Catalysis is a transformative technology, key to both life and lifestyle, contributing to 90% of chemical manufacturing processes and >20% of all industrial products, and will be a key enabler for the emerging Australian bioeconomy. The ex ....Nanostructured solid acid catalysts for sustainable chemical manufacturing. This project aims to develop next-generation solid acid catalysts for energy- and atom-efficient transformations of waste biomass and carbon dioxide to sustainable chemicals and fuels. Catalysis is a transformative technology, key to both life and lifestyle, contributing to 90% of chemical manufacturing processes and >20% of all industrial products, and will be a key enabler for the emerging Australian bioeconomy. The expected development of new high performance catalysts for the production of renewable transportation fuels and sustainable chemical feedstocks will underpin commercially viable low carbon technologies using waste resources, and should provide significant benefits to Australian science, industry, and the environment.
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Discovery Early Career Researcher Award - Grant ID: DE210101102
Funder
Australian Research Council
Funding Amount
$404,748.00
Summary
Single-Atom Catalysts on Atomically Thin Nanomaterials for H2O2 Production. Single-atomic sites supported on graphene analogs is an ideal structural mode for the design of electrocatalysts due to its ultimate small size limit, atomic thickness, and easily tuned electronic properties. This project aims to use a theory-guided approach to develop efficient electrocatalysts for the production of value-added hydrogen peroxide. The structural advantages of graphene analogs will be fully utilised to un ....Single-Atom Catalysts on Atomically Thin Nanomaterials for H2O2 Production. Single-atomic sites supported on graphene analogs is an ideal structural mode for the design of electrocatalysts due to its ultimate small size limit, atomic thickness, and easily tuned electronic properties. This project aims to use a theory-guided approach to develop efficient electrocatalysts for the production of value-added hydrogen peroxide. The structural advantages of graphene analogs will be fully utilised to unlock the catalytic power of single-atomic sites, and consequently achieve high catalytic activity and selectivity. The outcome will set a solid scientific foundation to enable economically viable technologies for eco-friendly hydrogen peroxide production and bring significant socioeconomic benefits to Australia.Read moreRead less
Promoting transition metal complex catalysis with plasmonic antennae. This project aims to apply visible light photocatalysis to a wide range of chemical reactions by utilizing the intriguing effects of intense light absorption by plasmonic metal nanoparticles, such as generating energetic electrons, changing reactant adsorption and the chemical binding of reactant with the catalyst. These effects will promote catalysis at surface-bound metal complex reaction sites under mild reaction conditions ....Promoting transition metal complex catalysis with plasmonic antennae. This project aims to apply visible light photocatalysis to a wide range of chemical reactions by utilizing the intriguing effects of intense light absorption by plasmonic metal nanoparticles, such as generating energetic electrons, changing reactant adsorption and the chemical binding of reactant with the catalyst. These effects will promote catalysis at surface-bound metal complex reaction sites under mild reaction conditions. This is a part of our long-term effort to transform chemical production by heating into green photocatalytic process. This project expects to generate knowledge crucial for developing theories for catalysis, the design of efficient catalysts, green chemical synthesis methods, and enhance international collaboration.Read moreRead less
Optimising catalyst performance by tuning adsorption with light. This project aims to utilize visible light to control reactant adsorption on catalyst surfaces for accelerating reactions and tuning product selectivity. Visible light irradiation of plasmonic metal nanoparticles can generate a force that attracts reactant to the nanoparticles in a catalyst, and causes desorption of other reactant-types from the particles. These compound-selective effects can alter the concentrations of reactants a ....Optimising catalyst performance by tuning adsorption with light. This project aims to utilize visible light to control reactant adsorption on catalyst surfaces for accelerating reactions and tuning product selectivity. Visible light irradiation of plasmonic metal nanoparticles can generate a force that attracts reactant to the nanoparticles in a catalyst, and causes desorption of other reactant-types from the particles. These compound-selective effects can alter the concentrations of reactants at the catalyst surface, a new paradigm for optimising catalytic performance. This project expects to open new capabilities within fields of catalysis and light-matter interaction. The anticipated outcomes include significant advancement of knowledge in catalysis and new approaches for important chemical synthesis.Read moreRead less
Biomass-derived Carbon Dots Enable Flexible, On-Demand Hydrogen Delivery . Methanol is a promising liquid hydrogen carrier for long distance H2 transportation and exportation, because it is rich in hydrogen content, cheap, recyclable between methanol-formaldehyde and easier to manufacture from renewable resources including biomass waste. The critical bottleneck in adopting methanol as the carrier is the demanding dehydrogenation process. The project aims to create a new class of photocatalyst ba ....Biomass-derived Carbon Dots Enable Flexible, On-Demand Hydrogen Delivery . Methanol is a promising liquid hydrogen carrier for long distance H2 transportation and exportation, because it is rich in hydrogen content, cheap, recyclable between methanol-formaldehyde and easier to manufacture from renewable resources including biomass waste. The critical bottleneck in adopting methanol as the carrier is the demanding dehydrogenation process. The project aims to create a new class of photocatalyst based on biomass-derived carbon nanodots grown on transition metal (di)chalcogenide nanosheets that can effectively enable a light-controlled methanol H2 release of desired quantity. The key outcomes will be a new class of photocatalysts and flexible, on-demand hydrogen delivery technology for liquid hydrogen carriers.Read moreRead less
Atomically Thin 3d Transition Metal Electrocatalysts for Water Splitting. The current industrial-scale hydrogen productions are reliant on high temperature steam reforming fossil fuels, consuming large quantity of energy and fossil resources, and emitting huge amounts of CO2. This project aims to develop cheap and plentiful transition metal-based high performance water splitting electrocatalysts, enabling economically viable large-scale water electrolytic hydrogen production driven by renewable ....Atomically Thin 3d Transition Metal Electrocatalysts for Water Splitting. The current industrial-scale hydrogen productions are reliant on high temperature steam reforming fossil fuels, consuming large quantity of energy and fossil resources, and emitting huge amounts of CO2. This project aims to develop cheap and plentiful transition metal-based high performance water splitting electrocatalysts, enabling economically viable large-scale water electrolytic hydrogen production driven by renewable electricity. A theory-guided catalyst approach will be used to guide the efficient design and development of high performance electrocatalysts. The success of the project will lead to a suit of high performance water splitting electrocatalysts, leaping forward water electrolytic hydrogen production technology.Read moreRead less
Australian Laureate Fellowships - Grant ID: FL220100059
Funder
Australian Research Council
Funding Amount
$2,937,786.00
Summary
Digital chemistry and catalysis: redefining reactions in confined systems. This Laureate program aims to initiate a new era of chemical catalysis and reaction manipulation via an entirely novel nanofluidic approach discovered in Australia. By further studying this phenomenon, it aims to deliver new insights into what drives chemical reactions in confined systems controlled by applied electric fields. It will also develop novel technology platforms to miniaturise and enable on-demand software-con ....Digital chemistry and catalysis: redefining reactions in confined systems. This Laureate program aims to initiate a new era of chemical catalysis and reaction manipulation via an entirely novel nanofluidic approach discovered in Australia. By further studying this phenomenon, it aims to deliver new insights into what drives chemical reactions in confined systems controlled by applied electric fields. It will also develop novel technology platforms to miniaturise and enable on-demand software-controlled (digital) chemistry, with broad applications in pharmaceutical, biotechnology and chemical industries. Project success will have a profound impact in many areas of modern society, the environment and the high-tech and manufacturing industry, while further enhancing Australia's sovereign manufacturing capability.Read moreRead less
Linkage Infrastructure, Equipment And Facilities - Grant ID: LE210100100
Funder
Australian Research Council
Funding Amount
$975,934.00
Summary
Multifunctional Platform for Chemical Manufacturing and Energy Materials. We aim to establish the first platform in Australia for the continuous production and in-situ characterisation of molecules and nanomaterials. This project expects to generate new knowledge in the area of functional materials using an interdisciplinary approach. The expected outcomes will be a unique analytical capability for rapid screening of synthetic and operational parameters, and unprecedented fundamental insight int ....Multifunctional Platform for Chemical Manufacturing and Energy Materials. We aim to establish the first platform in Australia for the continuous production and in-situ characterisation of molecules and nanomaterials. This project expects to generate new knowledge in the area of functional materials using an interdisciplinary approach. The expected outcomes will be a unique analytical capability for rapid screening of synthetic and operational parameters, and unprecedented fundamental insight into chemical reactions to inform the design and development of sustainable chemical processes. This proposal will provide significant benefits to cutting-edge research in catalysis, polymer engineering, separation science, CO2 capture and organic synthesis, to positively impact on the energy-manufacturing-environment nexus.Read moreRead less