Reactivity and Spectroscopy of Gas Phase Metal Oxide Cluster Ions: Structure-Reactivity Correlations and Fundamental Insights into Heterogeneous Catalysis. This project will make use of world class ARC funded instrumentation to carry out breakthrough science. The research will contribute fundamental insights into chemical bond activation relevant to industrial catalytic processes important to national manufacturing industries. These insights will improve the efficiency and selectivity of catal ....Reactivity and Spectroscopy of Gas Phase Metal Oxide Cluster Ions: Structure-Reactivity Correlations and Fundamental Insights into Heterogeneous Catalysis. This project will make use of world class ARC funded instrumentation to carry out breakthrough science. The research will contribute fundamental insights into chemical bond activation relevant to industrial catalytic processes important to national manufacturing industries. These insights will improve the efficiency and selectivity of catalytic processes and lead to increased profitability and/or a reduction in unwanted side products and pollution. The project will train young scientists in important experimental and theoretical chemical techniques, and will enhance and contribute to Australia's international research profile.Read moreRead less
Coinage metal nanoclusters: synthesis, structure and reactivity. Metal catalysts play important roles in the multi-billion dollar production of many industrial and fine chemicals used in wide-ranging applications including pharmaceuticals, insecticides and polymers. Despite the importance of metal catalysed reactions, the molecular details of such processes remain poorly understood. Breakthrough studies highlight that reactions previously thought to be catalysed by discrete metal catalysts are i ....Coinage metal nanoclusters: synthesis, structure and reactivity. Metal catalysts play important roles in the multi-billion dollar production of many industrial and fine chemicals used in wide-ranging applications including pharmaceuticals, insecticides and polymers. Despite the importance of metal catalysed reactions, the molecular details of such processes remain poorly understood. Breakthrough studies highlight that reactions previously thought to be catalysed by discrete metal catalysts are in fact catalysed by metal nanoclusters. This project involves the application of advanced mass spectrometric and computational methods to explore the formation and reactivity of copper, silver and gold nanoclusters. Identification of key reactive intermediates will inform the design of next generation catalysts.Read moreRead less
A Midas touch for electrophiles in new reaction development. This project aims to address the lack of knowledge about how high-value organic molecules are formed in gold-catalysed reactions by advancing a novel mode of catalysis. This project expects to generate new knowledge about these gold-catalysed reactions using an innovative, interdisciplinary approach incorporating computational and synthetic techniques. Expected outcomes of this project include the optimisation and development of import ....A Midas touch for electrophiles in new reaction development. This project aims to address the lack of knowledge about how high-value organic molecules are formed in gold-catalysed reactions by advancing a novel mode of catalysis. This project expects to generate new knowledge about these gold-catalysed reactions using an innovative, interdisciplinary approach incorporating computational and synthetic techniques. Expected outcomes of this project include the optimisation and development of important organic reactions and enhancing collaboration nationally and internationally between computational and synthetic chemists. This should provide significant benefits in the form of improved chemical reactions for chemists to prepare new pharmaceuticals, agrochemicals and materials.Read moreRead less
Nanostructured solid acid catalysts for sustainable chemical manufacturing. This project aims to develop next-generation solid acid catalysts for energy- and atom-efficient transformations of waste biomass and carbon dioxide to sustainable chemicals and fuels. Catalysis is a transformative technology, key to both life and lifestyle, contributing to 90% of chemical manufacturing processes and >20% of all industrial products, and will be a key enabler for the emerging Australian bioeconomy. The ex ....Nanostructured solid acid catalysts for sustainable chemical manufacturing. This project aims to develop next-generation solid acid catalysts for energy- and atom-efficient transformations of waste biomass and carbon dioxide to sustainable chemicals and fuels. Catalysis is a transformative technology, key to both life and lifestyle, contributing to 90% of chemical manufacturing processes and >20% of all industrial products, and will be a key enabler for the emerging Australian bioeconomy. The expected development of new high performance catalysts for the production of renewable transportation fuels and sustainable chemical feedstocks will underpin commercially viable low carbon technologies using waste resources, and should provide significant benefits to Australian science, industry, and the environment.
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Spatially orthogonal multifunctional materials for catalytic cascades. This project aims to develop and implement new strategies to create, visualise, and apply multifunctional catalysts in which the location of (and communication between) active sites is precisely controlled to unlock ultraselective cascade reactions. Catalysis is a key enabling technology contributing to 35 % of the global economy, with new catalysts underpinning socioeconomic advancement through fuels, chemicals, and pharmace ....Spatially orthogonal multifunctional materials for catalytic cascades. This project aims to develop and implement new strategies to create, visualise, and apply multifunctional catalysts in which the location of (and communication between) active sites is precisely controlled to unlock ultraselective cascade reactions. Catalysis is a key enabling technology contributing to 35 % of the global economy, with new catalysts underpinning socioeconomic advancement through fuels, chemicals, and pharmaceuticals production, and environmental depollution. This interdisciplinary project expects to discover next-generation nanoengineered catalysts, and to develop innovative energy- and resource-efficient chemical processes, which should offer significant benefits to Australian science, industry, and the environment.Read moreRead less
Advanced chemical recycling of mixed plastics for monomer recovery. This project aims to develop innovative catalytic routes to the chemical recycling of mixed plastics for recovery of their molecular building blocks. Plastic pollution poses a significant threat to the Australian ecosystem. Efficient recycling technologies are urgently needed as Australia only recycles ~4% of its 3.4 million tons of mixed waste plastics. This project expects to design highly efficient catalysts for the stepwise ....Advanced chemical recycling of mixed plastics for monomer recovery. This project aims to develop innovative catalytic routes to the chemical recycling of mixed plastics for recovery of their molecular building blocks. Plastic pollution poses a significant threat to the Australian ecosystem. Efficient recycling technologies are urgently needed as Australia only recycles ~4% of its 3.4 million tons of mixed waste plastics. This project expects to design highly efficient catalysts for the stepwise breakdown of mixed polyolefin plastics into monomers for the subsequent manufacturing of virgin plastics in a circular economy, and to elucidate fundamental underpinning reaction mechanisms. Outcomes will stimulate the Australian waste plastic recycling industry, and minimise plastic accumulation in the environment.Read moreRead less
Ambient Electrochemical C-N Coupling via Co-electrolysis of N2 and CO2. To overcome the hurdles in N2 fixation (massive energy consumption and CO2 emission), investigators creatively hypothesize that the simultaneous electrocatalytic coupling of N2 and CO2 would enable the selective formation of N-products and thus realize their conversion into N--fertilizers and acetamides. Based on the CI's recent discoveries, this project will develop an innovative / sustainable system, which could promote th ....Ambient Electrochemical C-N Coupling via Co-electrolysis of N2 and CO2. To overcome the hurdles in N2 fixation (massive energy consumption and CO2 emission), investigators creatively hypothesize that the simultaneous electrocatalytic coupling of N2 and CO2 would enable the selective formation of N-products and thus realize their conversion into N--fertilizers and acetamides. Based on the CI's recent discoveries, this project will develop an innovative / sustainable system, which could promote the N2 fixation along with CO2 conversion process, a significant alternative approach to simplify the pathways of C-N bond formation. It will thereby contribute to mitigation of greenhouse emissions and create an ecofriendly protocol/technology for distributed production of C-N products under ambient conditions. Read moreRead less