Biomolecular optoelectronic materials and devices. The melanins are the molecules in our skin, eyes and hair that provide colour and protection from the sun. In addition to being important bio-molecules, they have properties which make them useful for high tech applications especially in electronics and optoelectronics. Unfortunately, our current understanding of these fascinating materials is poor. In our project we aim to solve this limiting problem. We will develop new science to explain thei ....Biomolecular optoelectronic materials and devices. The melanins are the molecules in our skin, eyes and hair that provide colour and protection from the sun. In addition to being important bio-molecules, they have properties which make them useful for high tech applications especially in electronics and optoelectronics. Unfortunately, our current understanding of these fascinating materials is poor. In our project we aim to solve this limiting problem. We will develop new science to explain their behaviour, and use this knowledge to create bio-compatible hi-tech materials and devices. We anticipate significant benefits from the perspectives of basic science and utilisation of biomaterials for new green technologies.Read moreRead less
Naturally Photoactive Biopolymers. The basic aim of this project is to assess the viability of using semiconducting biopolymers from the melanin family of macromolecules in photoactive device based applications. In order to do this, key optical, structural, electronic, and photochemical properties will be assessed on thin films in the solid state. The melanins are the only known semiconducting biopolymers, and are non-toxic, biocompatible and biodegradable. Their use as ?active? materials in ....Naturally Photoactive Biopolymers. The basic aim of this project is to assess the viability of using semiconducting biopolymers from the melanin family of macromolecules in photoactive device based applications. In order to do this, key optical, structural, electronic, and photochemical properties will be assessed on thin films in the solid state. The melanins are the only known semiconducting biopolymers, and are non-toxic, biocompatible and biodegradable. Their use as ?active? materials in solid state or photo-electrochemical devices has never before been suggested. Specifically, these materials could be used as the light harvesting components in dye sensitised Gratzel cells, or, as the donor material in soft solid photovoltaic junctions. The melanins are also a key class of biomolecules (their involvement in skin cancers is well documented), and hence, any advancement in our understanding of their functions and properties could have biological importance.Read moreRead less
Photoactive Semiconducting Biopolymers. The basic aims of this project are to elucidate, manipulate, and utilise the unique chemical and physical properties of a class of biopolymers called the melanins. These materials are the only known solid state semiconducting biopolymers, and are non-toxic, biocompatible, and biodegradable. Their use as active components in biomimetic soft electonic, optoelectronic or photovoltaic devices, has not hitherto been demonstrated. It is anticipated that the k ....Photoactive Semiconducting Biopolymers. The basic aims of this project are to elucidate, manipulate, and utilise the unique chemical and physical properties of a class of biopolymers called the melanins. These materials are the only known solid state semiconducting biopolymers, and are non-toxic, biocompatible, and biodegradable. Their use as active components in biomimetic soft electonic, optoelectronic or photovoltaic devices, has not hitherto been demonstrated. It is anticipated that the key outcomes from the project will be a demonstration of biopolymer-based photoelectrochemical and solid-state p-i-n solar cells, and an improved understanding of the physics and chemistry of these important biological macromolecules.Read moreRead less
Macromolecular Materials for Organic Solar Cells. The world is in the midst of a climate crisis driven by mankind's insatiable demand for fossil-fuel energy. Renewable technologies such as solar and wind will undoubtedly form part of our future energy mix. Solar cells in particular have great potential- especially in sunny countries like Australia. The uptake of solar cell technology is hampered by their current high cost and long payback time. This project concerns the development of new solar ....Macromolecular Materials for Organic Solar Cells. The world is in the midst of a climate crisis driven by mankind's insatiable demand for fossil-fuel energy. Renewable technologies such as solar and wind will undoubtedly form part of our future energy mix. Solar cells in particular have great potential- especially in sunny countries like Australia. The uptake of solar cell technology is hampered by their current high cost and long payback time. This project concerns the development of new solar cells based upon novel organic materials called dendrimers. These materials can be solution processed and will dramatically reduce cost and payback time in next generation devices.Read moreRead less
High Performance Monolithic Perovskite Photocapacitors. Monolithic perovskite photocapacitor (MPPC) consisted of integrated energy harvesting perovskite solar cell and energy storage supercapacitor through an internally shared electrode can deliver stable electricity by harnessing solar energy. The performance of MPPC is dependent of properties of the shared electrode materials. This project aims to synthesis carbon materials with tailored surface, electrical and structure properties that are re ....High Performance Monolithic Perovskite Photocapacitors. Monolithic perovskite photocapacitor (MPPC) consisted of integrated energy harvesting perovskite solar cell and energy storage supercapacitor through an internally shared electrode can deliver stable electricity by harnessing solar energy. The performance of MPPC is dependent of properties of the shared electrode materials. This project aims to synthesis carbon materials with tailored surface, electrical and structure properties that are required to make a highly functioning shared electrode in MPPC. The goal is to fabricate stable, high performance MPPC. Successful achievement of the outcomes will enable cost-effective, reliable, solar electricity, placing Australia at the forefront of exploiting photovoltaics technologies.Read moreRead less
Development of High Performance Nanostructured (Bi, Sb)2Te3 Nanomaterials. The direct energy conversion between heat and electricity, based on thermoelectric effects without moving parts, has been considered as a green and sustainable solution to the global energy dilemma. This project aims to develop novel band-engineered (Bi, Sb)2Te3 nanomaterials for high-efficiency energy conversion using novel microwave assisted wet chemistry approach, coupled with nanostructure and band engineering strateg ....Development of High Performance Nanostructured (Bi, Sb)2Te3 Nanomaterials. The direct energy conversion between heat and electricity, based on thermoelectric effects without moving parts, has been considered as a green and sustainable solution to the global energy dilemma. This project aims to develop novel band-engineered (Bi, Sb)2Te3 nanomaterials for high-efficiency energy conversion using novel microwave assisted wet chemistry approach, coupled with nanostructure and band engineering strategies. The key breakthrough is to design high performance (Bi, Sb)2Te3 thermoelectrics for satisfying the high efficiency solid-state devices. The expected outcomes will lead to an innovative technology that waste heat recovery and refrigeration, which will place Australia at the forefront of practical energy technologies.Read moreRead less
Modelling quantum dynamics of electronic excited states in complex molecular materials. Understanding new materials that are the basis of new sources of renewable energy sources represents a major scientific challenge. Many of these materials are composed of large organic molecules containing hundreds of atoms. Their properties and the concepts needed to understand these materials are distinctly different from semiconductors such as silicon. This research will enhance our ability to design bett ....Modelling quantum dynamics of electronic excited states in complex molecular materials. Understanding new materials that are the basis of new sources of renewable energy sources represents a major scientific challenge. Many of these materials are composed of large organic molecules containing hundreds of atoms. Their properties and the concepts needed to understand these materials are distinctly different from semiconductors such as silicon. This research will enhance our ability to design better materials and optimize the performance of organic solar cells and LEDs. Australia's capacity for research and development in this scientifically challenging and technologically important field will be enhanced by this project. Read moreRead less
Interplay of superconductivity and magnetism in layered molecular crystals. The most interesting new electronic materials discovered in the past decade are built from layers of atoms or molecules. Many exhibit a subtle competition between magnetism and superconductivity.
This project will develop new theoretical concepts and models for the electronic properties of organic molecular crystals. The theoretical predictions will be tested experimentally at the USA National High Magnetic Field Labo ....Interplay of superconductivity and magnetism in layered molecular crystals. The most interesting new electronic materials discovered in the past decade are built from layers of atoms or molecules. Many exhibit a subtle competition between magnetism and superconductivity.
This project will develop new theoretical concepts and models for the electronic properties of organic molecular crystals. The theoretical predictions will be tested experimentally at the USA National High Magnetic Field Laboratory.
The outcome will be a better understanding of a wide range of materials (including high-temperature superconductors, giant magnetoresistance and plastic electronic materials) that could be the
basis of much of the electronic technology of the twenty-first century.Read moreRead less
Probing new physics with atomic parity violation. This project aims to provide a new level of rigour in tests of the standard model of particle physics at low energies, and to reveal or more tightly constrain new particles or forces. This will involve the development of state-of-the-art atomic theory techniques and collaboration with world-leading experimental groups. The expected outcomes and benefits include a breakthrough in the precision of atomic theory calculations, new insights into nucle ....Probing new physics with atomic parity violation. This project aims to provide a new level of rigour in tests of the standard model of particle physics at low energies, and to reveal or more tightly constrain new particles or forces. This will involve the development of state-of-the-art atomic theory techniques and collaboration with world-leading experimental groups. The expected outcomes and benefits include a breakthrough in the precision of atomic theory calculations, new insights into nuclear magnetic structure, improved determination of fundamental particle physics parameters, stronger ties with the international experimental community, enhancing Australian leadership and expertise, and high-level training of the next generation of scientists.Read moreRead less
Green synthesis of organometal perovskite solar cells. This project aims to understand the mechanism that governs the formation and crystallisation process of organic-inorganic lead halide perovskite films from non-toxic, environmentally friendly, protic ionic liquids. The project will develop new ionic liquid solvent systems that deliver appropriate morphology, and electrical and optical properties to fabricate high performance perovskite solar cells using environmentally friendly, low-toxicity ....Green synthesis of organometal perovskite solar cells. This project aims to understand the mechanism that governs the formation and crystallisation process of organic-inorganic lead halide perovskite films from non-toxic, environmentally friendly, protic ionic liquids. The project will develop new ionic liquid solvent systems that deliver appropriate morphology, and electrical and optical properties to fabricate high performance perovskite solar cells using environmentally friendly, low-toxicity processes. Successful achievement of the outcomes will enable environmentally-friendly, industrial scale processing of perovskite materials, placing Australia at the forefront of organometallic perovskite materials processing with applications in renewable energy and other electro-optical applications.Read moreRead less