Advanced Molecular Frameworks for Sodium Battery Electrode Applications. This project aims to develop new molecular materials capable of high capacity sodium-ion insertion. Through an innovative interdisciplinary approach that targets the synthesis and detailed characterisation of an extensive family of materials this project expects to generate major advances in the understanding of how the chemical, physical and structural attributes of the materials relate to their electrical charge/discharge ....Advanced Molecular Frameworks for Sodium Battery Electrode Applications. This project aims to develop new molecular materials capable of high capacity sodium-ion insertion. Through an innovative interdisciplinary approach that targets the synthesis and detailed characterisation of an extensive family of materials this project expects to generate major advances in the understanding of how the chemical, physical and structural attributes of the materials relate to their electrical charge/discharge behaviours. Significant anticipated outcomes and benefits include the development of new material design approaches that optimise battery electrode performance across a diverse parameter space, and the generation of advanced new materials worthy of commercial development in low-cost, large-scale battery applications.Read moreRead less
Linkage Infrastructure, Equipment And Facilities - Grant ID: LE0346515
Funder
Australian Research Council
Funding Amount
$507,000.00
Summary
Fluorescence Detector for the Australian National Beamline Facility. X-ray absorption spectroscopy (XAS) is an extremely important synchrotron radiation tool for determining the local structure around an X-ray absorbing atom. This has many applications in the study of materials, minerals, metal complexes, and metalloproteins and can often be used to obtain information that is not available by other techniques, because structural information can be obtained in the solid or solution state and in ....Fluorescence Detector for the Australian National Beamline Facility. X-ray absorption spectroscopy (XAS) is an extremely important synchrotron radiation tool for determining the local structure around an X-ray absorbing atom. This has many applications in the study of materials, minerals, metal complexes, and metalloproteins and can often be used to obtain information that is not available by other techniques, because structural information can be obtained in the solid or solution state and in mixtures. The current proposal is aimed at introducing new technology into the Australian National Beamline Facility that will greatly improve the quality and quantity of experiments that can be performed and extend studies into dilute solutions and protein samples.Read moreRead less
Nanoporous Molecular Frameworks: Chirality, Host-Guest Chemistry and Nanoscale Templation. Molecular frameworks are a new class of nanoporous material that promise a range of applications due to their reversible, selective guest-exchange and their great structural and chemical versatility. This project addresses three points of focus within this area: 1) the use of homochiral (handed) frameworks for molecular enantioseparations, 2) the mechanisms of guest-exchange in these systems, and 3) the us ....Nanoporous Molecular Frameworks: Chirality, Host-Guest Chemistry and Nanoscale Templation. Molecular frameworks are a new class of nanoporous material that promise a range of applications due to their reversible, selective guest-exchange and their great structural and chemical versatility. This project addresses three points of focus within this area: 1) the use of homochiral (handed) frameworks for molecular enantioseparations, 2) the mechanisms of guest-exchange in these systems, and 3) the use of these materials as porous templates within which other nanostructured materials may be grown. In addition to having considerable fundamental interest, the work promises a number of significant commercial benefits in the areas of drug purification and nanomaterials.Read moreRead less
Novel Photo-Catalysts for Water Oxidation: Linking Nature to New Technologies. Photosynthesis is the catalytic process used by biology to convert the sun's light into energy. This project aims to mimic photosynthesis with cheap and robust molecules. The approach has great potential for development of renewable energy production and benign industrial chemical processes. The project will bring Australia to the international forefront of this field. It will provide excellent research training in a ....Novel Photo-Catalysts for Water Oxidation: Linking Nature to New Technologies. Photosynthesis is the catalytic process used by biology to convert the sun's light into energy. This project aims to mimic photosynthesis with cheap and robust molecules. The approach has great potential for development of renewable energy production and benign industrial chemical processes. The project will bring Australia to the international forefront of this field. It will provide excellent research training in a range of scientific skills for Australian research students. Read moreRead less
Smart Molecular Materials for Sensors, Displays and Nanodevices. The aims of this project are to synthesise new smart molecular materials and elucidate the chemical origin of the physical properties they exhibit. Exposure of these transition metal-based compounds to heat or light will induce changes in colour and magnetic behaviour, affording potential roles as the smallest possible electronic components or addressable entities for high density data storage. It is expected that the materials wil ....Smart Molecular Materials for Sensors, Displays and Nanodevices. The aims of this project are to synthesise new smart molecular materials and elucidate the chemical origin of the physical properties they exhibit. Exposure of these transition metal-based compounds to heat or light will induce changes in colour and magnetic behaviour, affording potential roles as the smallest possible electronic components or addressable entities for high density data storage. It is expected that the materials will also exhibit tunable thermochromic and photochromic properties, which are important for applications in photoresponsive devices or temperature sensors. The structure-function relationships determined will inform the development of molecular materials for future nanodevices, sensors or displays.Read moreRead less
Reactivity and Spectroscopy of Gas Phase Metal Oxide Cluster Ions: Structure-Reactivity Correlations and Fundamental Insights into Heterogeneous Catalysis. This project will make use of world class ARC funded instrumentation to carry out breakthrough science. The research will contribute fundamental insights into chemical bond activation relevant to industrial catalytic processes important to national manufacturing industries. These insights will improve the efficiency and selectivity of catal ....Reactivity and Spectroscopy of Gas Phase Metal Oxide Cluster Ions: Structure-Reactivity Correlations and Fundamental Insights into Heterogeneous Catalysis. This project will make use of world class ARC funded instrumentation to carry out breakthrough science. The research will contribute fundamental insights into chemical bond activation relevant to industrial catalytic processes important to national manufacturing industries. These insights will improve the efficiency and selectivity of catalytic processes and lead to increased profitability and/or a reduction in unwanted side products and pollution. The project will train young scientists in important experimental and theoretical chemical techniques, and will enhance and contribute to Australia's international research profile.Read moreRead less
Metal-Based Molecular Materials: From Electronic Structure to Functionality. This project aims to develop and explore new metal-based molecular materials, focusing on molecules that can act as magnets or be switched between multiple states by heating/cooling. This project expects to deliver an improved understanding of how the molecular electronic structure engenders desired physical properties in the target species. This insight will allow development of design principles for robust systems for ....Metal-Based Molecular Materials: From Electronic Structure to Functionality. This project aims to develop and explore new metal-based molecular materials, focusing on molecules that can act as magnets or be switched between multiple states by heating/cooling. This project expects to deliver an improved understanding of how the molecular electronic structure engenders desired physical properties in the target species. This insight will allow development of design principles for robust systems for nanodevices or advanced materials. As well as achieving important advances in fundamental chemistry, this project is anticipated to help lay the foundations for development of novel materials for high density data storage, quantum computing, molecular electronics/spintronics, optical displays or temperature/solvent sensors.Read moreRead less
Molecular Spin Switching with Earth Abundant Metals. This project aims to develop molecular materials based on non-precious metals that respond to stimuli, including heat or light, by switching between forms with different properties, such as colour and electrical conductivity. The project expects to deliver enhanced control over the switching characteristics and incorporation of the materials into responsive thin films, ready for integration into devices. These molecular switches are promising ....Molecular Spin Switching with Earth Abundant Metals. This project aims to develop molecular materials based on non-precious metals that respond to stimuli, including heat or light, by switching between forms with different properties, such as colour and electrical conductivity. The project expects to deliver enhanced control over the switching characteristics and incorporation of the materials into responsive thin films, ready for integration into devices. These molecular switches are promising for molecular electronics, spintronics and colour-based sensing and display devices. Their fast response time and small component size imply less heat to dissipate and therefore less electricity required for cooling upon implementation in information communications and other technologies.Read moreRead less
Harnessing redox-active ligands in functional metal complexes. This project aims to synthesise and investigate metal-based molecules that can be reversibly switched between forms with different physical properties, such as colour or electrical conductivity, upon exposure to heat, light or electrical potential. The project expects to develop compounds that offer physical properties relevant for deployment in advanced materials or nanodevices. Expected outcomes of this project include elucidation ....Harnessing redox-active ligands in functional metal complexes. This project aims to synthesise and investigate metal-based molecules that can be reversibly switched between forms with different physical properties, such as colour or electrical conductivity, upon exposure to heat, light or electrical potential. The project expects to develop compounds that offer physical properties relevant for deployment in advanced materials or nanodevices. Expected outcomes of this project include elucidation of chemical routes to tuning the switchability and candidate compounds for future applications. As well as achieving important advances in fundamental chemistry, this project should provide significant benefits, such as novel materials for molecular electronics/spintronics, photoresponsive devices or sensors.Read moreRead less
Advanced Dynamic Function in Metal-Organic Framework Materials. This project targets the strategic incorporation of three important high-order functionalities into metal-organic framework materials. These are nanoporosity, that is the reversible inclusion of molecules and ions; anomalous mechanical response to changes in temperature, pressure and included guests; and electronic/magnetic function, specifically electron transfer and magnetic alignment. Examination of the unique interplay between ....Advanced Dynamic Function in Metal-Organic Framework Materials. This project targets the strategic incorporation of three important high-order functionalities into metal-organic framework materials. These are nanoporosity, that is the reversible inclusion of molecules and ions; anomalous mechanical response to changes in temperature, pressure and included guests; and electronic/magnetic function, specifically electron transfer and magnetic alignment. Examination of the unique interplay between these properties will address key questions in the science of nanoscale systems and may lead to the discovery of exciting new emergent phenomena. This will underpin the development of advanced new technologies, spanning gas separations, rechargeable batteries, high precision componentry and molecular electronic devices.Read moreRead less