New Polymers for Cellulose-based Bioplastics. We will design new cellulose derivatives by combining carefully engineered synthetic polymers to cellulose. We will explore the fundamental science underpinning the manufacture of these bioplastics, and apply the concept to the design of two new materials, with (super)hydrophobic and antibacterial properties. These materials have the potential to replace synthetic plastics, which comprise one of the major outputs of the chemical industry worldwide. P ....New Polymers for Cellulose-based Bioplastics. We will design new cellulose derivatives by combining carefully engineered synthetic polymers to cellulose. We will explore the fundamental science underpinning the manufacture of these bioplastics, and apply the concept to the design of two new materials, with (super)hydrophobic and antibacterial properties. These materials have the potential to replace synthetic plastics, which comprise one of the major outputs of the chemical industry worldwide. Plastic is present everywhere in human life, but its manufacture and disposal have a strong negative impact on the environment; the new materials manufactured in this project are viable alternatives to plastics, and are sustainable from a production and disposal point of view.Read moreRead less
New Transparent Polymer Nanocomposite Coatings Using Multireactive Inorganic Cages. New polymeric nanocomposite coatings are proposed with enhanced abrasion resistance, toughness and optical functionality, suitable for the coating of optical plastic substrates. These composites contain inorganic cages, dispersed and chemically-coupled within the crosslinked organic matrix. In addition to good mechanical behaviour, high value properties such as colorisation on exposure to light and resistance to ....New Transparent Polymer Nanocomposite Coatings Using Multireactive Inorganic Cages. New polymeric nanocomposite coatings are proposed with enhanced abrasion resistance, toughness and optical functionality, suitable for the coating of optical plastic substrates. These composites contain inorganic cages, dispersed and chemically-coupled within the crosslinked organic matrix. In addition to good mechanical behaviour, high value properties such as colorisation on exposure to light and resistance to damage from high energy lasers will be achieved by attachment to the cages of chemical units with optical activity. These cages are of nanometre size and an important aspect of the project involves probing the resultant structure at the molecular level, using advanced characterisation techniques.Read moreRead less
Novel Lanthanide Complexes and Polymeric Luminescent Chelates for Biomedical Imaging and Bioassay. The development of advanced materials and frontier technologies such as the luminescent chelates proposed here is essential for Australia's evolution as a competitive nation in fields such as biomedical imaging and clinical diagnostics. For example, the total expenditure on fluorescent reagents in 2004 exceeded US$1.5 billion, with an estimated 25% annual growth. With proven applications in diagnos ....Novel Lanthanide Complexes and Polymeric Luminescent Chelates for Biomedical Imaging and Bioassay. The development of advanced materials and frontier technologies such as the luminescent chelates proposed here is essential for Australia's evolution as a competitive nation in fields such as biomedical imaging and clinical diagnostics. For example, the total expenditure on fluorescent reagents in 2004 exceeded US$1.5 billion, with an estimated 25% annual growth. With proven applications in diagnostic immunoassay and high throughput screening, the use of luminescent lanthanide complexes allows significant improvements over traditional fluorophores, facilitating miniaturisation and ultimately leading to reduced costs for the consumer.Read moreRead less
Dynamics of Photon-Induced Processes in Engineered Polymer Systems. This project will investigate photo-induced energy and electron transport in innovative polymer systems of well defined structure. New functionalised, aromatic and conjugated polymers will be synthesised and studied by ultrafast laser spectroscopic techniques. Information on the dynamics of light energy dissipation processes in these polymers on time-scales down to the femtosecond regime and at a single molecule level will be ....Dynamics of Photon-Induced Processes in Engineered Polymer Systems. This project will investigate photo-induced energy and electron transport in innovative polymer systems of well defined structure. New functionalised, aromatic and conjugated polymers will be synthesised and studied by ultrafast laser spectroscopic techniques. Information on the dynamics of light energy dissipation processes in these polymers on time-scales down to the femtosecond regime and at a single molecule level will be obtained. The results will provide the basic information required to develop novel photon-active materials and devices.Read moreRead less
New Electron Field Emission Films Based on Aligned Carbon Nanotube Guests in Liquid Crystalline Polymer Hosts. This project seeks to develop a new class of electron field emitting nanocomposite consisting of nanotubes in liquid crystalline polymers. Electron emitting materials are in much demand in x-ray and microwave generation, computer displays and low-energy lighting. We utilise the ready alignability of liquid crystalline units in magnetic fields to cause realignment of incorporated carbon ....New Electron Field Emission Films Based on Aligned Carbon Nanotube Guests in Liquid Crystalline Polymer Hosts. This project seeks to develop a new class of electron field emitting nanocomposite consisting of nanotubes in liquid crystalline polymers. Electron emitting materials are in much demand in x-ray and microwave generation, computer displays and low-energy lighting. We utilise the ready alignability of liquid crystalline units in magnetic fields to cause realignment of incorporated carbon nanotubes, followed by polymer solidification to maintain orientation. It involves low temperature processing, contrasting very favourably with current problematic, high temperature processes. This allows materials to be cast on flexible polymer substrates, potentially enabling construction of cathode tubes to replace existing mercury-containing fluorescent lighting.Read moreRead less
The Synthesis and Evaluation of White Nano Particles that Reinforce the Mechanical Properties of Elastomers. This project will introduce admicellar polymerization technique to produce a bound polymer layer on the surface of fillers used for reinforcement of elastomers. The novel approach in this project will provide advanced material with excellent mechanical properties. Such composites can be used in various high performance elastomer applications such as rubber for tyres in automotive vehicles ....The Synthesis and Evaluation of White Nano Particles that Reinforce the Mechanical Properties of Elastomers. This project will introduce admicellar polymerization technique to produce a bound polymer layer on the surface of fillers used for reinforcement of elastomers. The novel approach in this project will provide advanced material with excellent mechanical properties. Such composites can be used in various high performance elastomer applications such as rubber for tyres in automotive vehicles. Products based on this new technology will produce significantly improved properties. The development of this new technology will not only advance polymer science, it will also provide great opportunities for new elastomer applications in a number of industries.Read moreRead less
The development of unique cyclic polymers. The project will yield cyclic polymers with a large range of commercial and industrial applications (e.g. drug delivery, contamination clean-up, nano-wires, sensors) that will result in positive economic and social benefits for Australia. The research will lead to increased employment opportunities within the manufacturing industry and R&D, and also underpin and extend Australia's leading position in the development of innovative polymeric and advanced ....The development of unique cyclic polymers. The project will yield cyclic polymers with a large range of commercial and industrial applications (e.g. drug delivery, contamination clean-up, nano-wires, sensors) that will result in positive economic and social benefits for Australia. The research will lead to increased employment opportunities within the manufacturing industry and R&D, and also underpin and extend Australia's leading position in the development of innovative polymeric and advanced materials. The resulting materials will provide new and improved technological innovations for commercial products, delivering benefits direct to the public. Furthermore, there is potential development of spin-off companies - leading to further investment in Australian science and industry.Read moreRead less
Controlled Macromolecular Architectures for Functional Nanomaterials Design. The research involves an exciting and innovative collaboration between two internationally recognized Australian research groups, cementing Australia's position as a leading country for research in polymer science and nanotechnology. Advanced polymer chemistry will be used to make ?smart? polymers that can controllably respond to changes in their surroundings. These will then be assembled to form materials with dimensio ....Controlled Macromolecular Architectures for Functional Nanomaterials Design. The research involves an exciting and innovative collaboration between two internationally recognized Australian research groups, cementing Australia's position as a leading country for research in polymer science and nanotechnology. Advanced polymer chemistry will be used to make ?smart? polymers that can controllably respond to changes in their surroundings. These will then be assembled to form materials with dimensions of the order of millionths of millimeters - forming so-called "smart nanomaterials". The materials prepared are expected to find application in the agricultural and pharmaceutical sectors, contributing to the well-being of Australian citizens and the development of a robust Australian industry.Read moreRead less
Synthesis and Functionalisation of Advanced Polymer Films and Particles. Scientific and technological advances at the frontiers of nano- and biotechnology are poised to revolutionise the scope of treatment and healthcare options. This project will involve the synthesis of engineered polymer building blocks with the capability for multifunctional and intelligent response. These smart polymers will then be assembled into responsive nanostructured materials for drug delivery and biosensing applica ....Synthesis and Functionalisation of Advanced Polymer Films and Particles. Scientific and technological advances at the frontiers of nano- and biotechnology are poised to revolutionise the scope of treatment and healthcare options. This project will involve the synthesis of engineered polymer building blocks with the capability for multifunctional and intelligent response. These smart polymers will then be assembled into responsive nanostructured materials for drug delivery and biosensing applications. These materials are expected to have health benefits for Australian citizens and will contribute to a world-leading nanobiotechnology industry. The project will also provide development opportunities for young scientists and will also foster multidisciplinary collaborations within both Australia and abroad.Read moreRead less
Nanogels: Next Generation Polymeric Particles. The existing knowledge in the formation of polymeric networks limits the technological development of polymer materials. This project will introduce new polymeric particles, called nanogels to open a new area in new polymeric architecture research. A number of new structures based on the nanogels will be developed. These new macromolecules will not only bring the polymer science into a new field, it will provide a great opportunity to discover the ....Nanogels: Next Generation Polymeric Particles. The existing knowledge in the formation of polymeric networks limits the technological development of polymer materials. This project will introduce new polymeric particles, called nanogels to open a new area in new polymeric architecture research. A number of new structures based on the nanogels will be developed. These new macromolecules will not only bring the polymer science into a new field, it will provide a great opportunity to discover the next generation of the polymeric products, particularly for application in automotive paint, drug delivery and bio-molecular separations.Read moreRead less