Controllable Synthesis of Defects in Catalysts for Electrocatalysis . This project aims to address the most critical issue of electrocatalysis: identification of active sites for carbon-based metal free catalysts (CMFCs). Through the development of new methodologies, this proposal will, for the first time, controllably synthesise the vacancy defects that are the major active sites for CMFCs. The expected outcomes from this project include in-depth understanding of the fundamentals of electrocata ....Controllable Synthesis of Defects in Catalysts for Electrocatalysis . This project aims to address the most critical issue of electrocatalysis: identification of active sites for carbon-based metal free catalysts (CMFCs). Through the development of new methodologies, this proposal will, for the first time, controllably synthesise the vacancy defects that are the major active sites for CMFCs. The expected outcomes from this project include in-depth understanding of the fundamentals of electrocatalysis: the reactivity of active sites and the catalytic performance with the number of active sites; which will not only significantly advance knowledge but also achieve breakthrough technologies that greatly benefit to the society and economy both for Australia and worldwide.Read moreRead less
Advanced separators for lithium-sulphur batteries. This project aims to develop new membranes for use as separators in lithium-sulphur batteries. Currently diffusion of polysulphides within these batteries reduces battery power and lifetime. The new membranes are intended to block polysulphide diffusion over an extended lifetime, while transporting the other ions needed for the battery to function. The project is expected to generate new membrane materials and further knowledge about the design, ....Advanced separators for lithium-sulphur batteries. This project aims to develop new membranes for use as separators in lithium-sulphur batteries. Currently diffusion of polysulphides within these batteries reduces battery power and lifetime. The new membranes are intended to block polysulphide diffusion over an extended lifetime, while transporting the other ions needed for the battery to function. The project is expected to generate new membrane materials and further knowledge about the design, synthesis and larger-scale production of membranes for electrochemical applications. This project will provide significant benefits by producing potentially lighter, longer-lasting and cheaper batteries than existing lithium-ion technologies, with the potential to accelerate the adoption of electric cars.Read moreRead less
Programming the Microstructure of 3D Printed Objects . This project aims to apply state-of-the-art living polymerisation techniques to 3D printing to efficiently produce customised polymer materials that are tailored at the molecular level. By combining computational modeling and experimental approach, fast and oxygen tolerant photoliving radical polymerisation will be developed and applied to 3D printing. These new systems will produce highly structured polymer materials with remarkable mechani ....Programming the Microstructure of 3D Printed Objects . This project aims to apply state-of-the-art living polymerisation techniques to 3D printing to efficiently produce customised polymer materials that are tailored at the molecular level. By combining computational modeling and experimental approach, fast and oxygen tolerant photoliving radical polymerisation will be developed and applied to 3D printing. These new systems will produce highly structured polymer materials with remarkable mechanical properties. The effect of nanostructure on the macroscopic material properties will be investigated. The intended outcome of this project will produce advanced materials with tailored mechanical properties via streamlined and accessible approaches.Read moreRead less
Manufacturing Nanostructured Polymer Thin Films using Visible Light. This research aims the development of selective photochemical tools driven by different colours of light for the fabrication of nanostructured polymer brush thin films. By using different wavelengths to selectively activate specific chemical reactions, this will enable multiple reactions to be performed simultaneously, significantly streamlining fabrication. Additionally, the increased selectivity offers pathways to more sophis ....Manufacturing Nanostructured Polymer Thin Films using Visible Light. This research aims the development of selective photochemical tools driven by different colours of light for the fabrication of nanostructured polymer brush thin films. By using different wavelengths to selectively activate specific chemical reactions, this will enable multiple reactions to be performed simultaneously, significantly streamlining fabrication. Additionally, the increased selectivity offers pathways to more sophisticated nanoarchitectures in comparison to existing methods. This research will lead to the fabrication of 3D polymer brush architectures with unparalleled precision, which will be of high scientific and industrial value for a diverse range of applications, such as optoelectronics, nanoactuation, and sensing.Read moreRead less
Engineering two dimensional polymers for membrane-based chemical separation. This project aims to develop novel two-dimensional polymers with precisely controlled pore-sizes for preparing membrane materials which can efficiently separate these gaseous chemicals at ambient temperatures. Key industrial chemical mixtures with similar size and boiling points are difficult to separate by conventional distillation methods. Currently, purification of olefins alone accounts for 0.3% of global energy use ....Engineering two dimensional polymers for membrane-based chemical separation. This project aims to develop novel two-dimensional polymers with precisely controlled pore-sizes for preparing membrane materials which can efficiently separate these gaseous chemicals at ambient temperatures. Key industrial chemical mixtures with similar size and boiling points are difficult to separate by conventional distillation methods. Currently, purification of olefins alone accounts for 0.3% of global energy use. The expected outcomes of the project will have a huge impact on industrial purification processing by providing a disruptive membrane technology, and will significantly reduce energy consumption and open up new routes for resources.Read moreRead less
Nano-engineered catalysts for sustainable fuel production from waste . This project aims to address two major problems simultaneously-reducing the burden of non-recyclable waste currently going to landfill in Australia, and offsetting Australia’s reliance on imported diesel to support industry and transport needs. While approximately 95% of diesel consumed in Australia is imported, vast quantities of carbon-based waste ends up in landfill. Municipal Solid Waste (MSW) is a mixture of plant-based ....Nano-engineered catalysts for sustainable fuel production from waste . This project aims to address two major problems simultaneously-reducing the burden of non-recyclable waste currently going to landfill in Australia, and offsetting Australia’s reliance on imported diesel to support industry and transport needs. While approximately 95% of diesel consumed in Australia is imported, vast quantities of carbon-based waste ends up in landfill. Municipal Solid Waste (MSW) is a mixture of plant-based waste (including food, garden, paper, and wood) and fossil-fuel derived materials (plastics). Using an innovative and environmentally-sustainable catalytic process, the outcomes of this project are aimed alleviating Australia’s dependence on diesel fuel imports and better waste management solutions in Australia.Read moreRead less
3-D Printed Catalytic Monoliths for Energy Efficient Carbon Conversion. Carbon Capture and Utilisation (CCU) is an essential pathway for reducing carbon in the Earth's atmosphere. However a major hurdle in the carbon utilisation part is that the conversion technologies often rely on energy derived from fossil sources. Electrification of carbon conversion processes can overcome this hurdle by providing this energy via renewables. This project aims to develop an electrically powered energy efficie ....3-D Printed Catalytic Monoliths for Energy Efficient Carbon Conversion. Carbon Capture and Utilisation (CCU) is an essential pathway for reducing carbon in the Earth's atmosphere. However a major hurdle in the carbon utilisation part is that the conversion technologies often rely on energy derived from fossil sources. Electrification of carbon conversion processes can overcome this hurdle by providing this energy via renewables. This project aims to develop an electrically powered energy efficient catalytic process for carbon conversion. A modular 3-D printed monolithic catalytic reactor prototype powered by induction or resistive heating will be developed to minimise energy loss in the carbon conversion process. An expected outcome of this project is translation of this prototype in a CCU pilot scale facility.Read moreRead less
Atomically thin membranes to transform chemical separations. Energy-efficient chemical separation is at the heart of modern resource and manufacturing industries, central to a prosperous and sustainable Australia. This project aims to develop next generation membrane technologies to transform chemical separations by employing recent breakthrough in materials discovery and nanofluidics. Expected outcomes include new fundamental understandings on sub-continuum transport physics and new atomically ....Atomically thin membranes to transform chemical separations. Energy-efficient chemical separation is at the heart of modern resource and manufacturing industries, central to a prosperous and sustainable Australia. This project aims to develop next generation membrane technologies to transform chemical separations by employing recent breakthrough in materials discovery and nanofluidics. Expected outcomes include new fundamental understandings on sub-continuum transport physics and new atomically thin membranes that enable energy-efficient separations for processing challenging streams beyond water purification. This project aims to position Australia at the forefront of sustainable separation technology and make the local resource and manufacturing industries more sustainable and globally competitive.Read moreRead less
Programming anisotropy into responsive soft materials. The project aims to generate viscoelastic soft materials with programmable anisotropy using aqueous suspensions of colloidal rods that have tunable surface coatings. The project expects to generate new knowledge in the rheology and structural characteristics of this unique class of materials. A key innovation is the use of charge-directed polymer self-assembly to control colloidal interactions, suspension rheology and phase behaviour. The in ....Programming anisotropy into responsive soft materials. The project aims to generate viscoelastic soft materials with programmable anisotropy using aqueous suspensions of colloidal rods that have tunable surface coatings. The project expects to generate new knowledge in the rheology and structural characteristics of this unique class of materials. A key innovation is the use of charge-directed polymer self-assembly to control colloidal interactions, suspension rheology and phase behaviour. The intended outcome is spatial control over the orientation of nanostructures, potentially mimicking the structural hierarchy found in nature. This should provide significant benefits to the creation of viscoelastic materials with complex rheology as well as structural, mechanical and optical heterogeneity.Read moreRead less
Regulating guest transport in microporous materials by electric field. This project aims to address the fundamentals and applications of regulating micropore accessibility. It has long been known that some highly adsorbing molecular sieves suddenly become inaccessible to gases below certain temperatures. Following a recent breakthrough in elucidating the mechanism of such temperature-regulated guest admission, this project will explore electrical regulation of micropore accessibility in conjunct ....Regulating guest transport in microporous materials by electric field. This project aims to address the fundamentals and applications of regulating micropore accessibility. It has long been known that some highly adsorbing molecular sieves suddenly become inaccessible to gases below certain temperatures. Following a recent breakthrough in elucidating the mechanism of such temperature-regulated guest admission, this project will explore electrical regulation of micropore accessibility in conjunction with developing new mechanisms, materials, and control tools for applications, including tunable molecular sieves, valves and gas encapsulation devices. The outcomes of this project will generate new knowledge in the active manipulation of the admission and release of guest molecules in/out of microporous materials, and establish new expertise and capabilities that can advance gas separation, storage and sensing technologies. It is expected that this project will contribute to the long term benefit in low emission energy supplies and Australia's natural gas industry, improve the separation efficiency of our chemical industry, and boost the development of the hydrogen economy.Read moreRead less