Self-assembly and complexity: networks and patterns from materials to markets. Self-assembly leads the formation of patterns without external directing agents. It is responsible for the growth of complex multiscale structures found in biology and materials science and is a crucial concept for development of viable nanotechnologies. Complex systems, from biological ecosystems to financial markets and the Internet, are also characterized by spontaneous clustering and linkages that determine their ....Self-assembly and complexity: networks and patterns from materials to markets. Self-assembly leads the formation of patterns without external directing agents. It is responsible for the growth of complex multiscale structures found in biology and materials science and is a crucial concept for development of viable nanotechnologies. Complex systems, from biological ecosystems to financial markets and the Internet, are also characterized by spontaneous clustering and linkages that determine their collective behaviour. The project will investigate in detail the geometry, topology, materials science and statistical physics of networks, leading to design and characterization of robust self-assembled materials and complex systems.Read moreRead less
Computational approaches to selection and design of ionic materials. Advanced batteries, fuel cells and solar cell technologies are beginning to use ionic liquids/plastic crystals as electrolytes due to their superb stability and valuable properties. As a broad class these ionic materials have only been known for the last 10 years or so and there is much to learn about their structure and properties. The project will develop and advance quantum chemical techniques for selection and design of ion ....Computational approaches to selection and design of ionic materials. Advanced batteries, fuel cells and solar cell technologies are beginning to use ionic liquids/plastic crystals as electrolytes due to their superb stability and valuable properties. As a broad class these ionic materials have only been known for the last 10 years or so and there is much to learn about their structure and properties. The project will develop and advance quantum chemical techniques for selection and design of ionic materials with the goal of developing electrolytes for a range of applications from advanced metal batteries, solar cells to fuel cells. These applications will have impact on energy efficiency and energy conservation by enabling CO2 replacing technologies. Read moreRead less
Fully ab initio, large-scale calculations of thermodynamic and transport properties of ionic materials. Advanced batteries, fuel cells, and photonic device technologies are beginning to use ionic materials as electrolytes due to their superb stability and technologically valuable properties. As a broad class these materials have only been known for just over a decade and there is still more unknown than known about their structure and properties. The project will develop new advanced computation ....Fully ab initio, large-scale calculations of thermodynamic and transport properties of ionic materials. Advanced batteries, fuel cells, and photonic device technologies are beginning to use ionic materials as electrolytes due to their superb stability and technologically valuable properties. As a broad class these materials have only been known for just over a decade and there is still more unknown than known about their structure and properties. The project will develop new advanced computational methods as a basis for understanding their properties and thereby allowing us to design-in desired features. Ultimately these advances will have support the development of energy efficient CO2 replacement technologies.Read moreRead less
Electronic coupling and nanoscale engineering of two-dimensional nanojunctions. This project aims to improve the design of photovoltaic, energy storage, and nanocatalytic devices by using quantum-size tuning, orientation control, strain engineering, and surface modification to manipulate the electronic coupling and charge transfer of two-dimensional nanojunctions. The limitations of and potential environmental damage from fossil-fuel-based energy resources have increased interest in renewable en ....Electronic coupling and nanoscale engineering of two-dimensional nanojunctions. This project aims to improve the design of photovoltaic, energy storage, and nanocatalytic devices by using quantum-size tuning, orientation control, strain engineering, and surface modification to manipulate the electronic coupling and charge transfer of two-dimensional nanojunctions. The limitations of and potential environmental damage from fossil-fuel-based energy resources have increased interest in renewable energy research. The expected outcomes are electron-scale understanding of the tuneable functionalisation of two-dimensional nanojunctions and the design of low-cost and high-efficiency renewable energy devices.Read moreRead less
Tailoring geopolymer concretes for sustainable development. This project will benefit Australia by enhancing the wider uptake of environmentally friendly geopolymer concretes. These materials are now commercially available in Australia, and provide the opportunity to obtain value from multiple millions of tonnes of industrial wastes (coal fly ash and metallurgical slags). An Australian company, Zeobond, is currently the world's leading commercial producer of geopolymers, and is collaborating in ....Tailoring geopolymer concretes for sustainable development. This project will benefit Australia by enhancing the wider uptake of environmentally friendly geopolymer concretes. These materials are now commercially available in Australia, and provide the opportunity to obtain value from multiple millions of tonnes of industrial wastes (coal fly ash and metallurgical slags). An Australian company, Zeobond, is currently the world's leading commercial producer of geopolymers, and is collaborating in this project to develop a scientific understanding of how best to formulate durable geopolymer concretes. Geopolymer concrete will provide the opportunity to reduce Australia's CO2 emissions by over a million tonnes per year when implemented on a commercial scale.Read moreRead less
Engineered control of polarisation rotation in ferroelectric bilayers. This project aims to develop interface engineered nanoscale ferroelectric thin films with functional properties suitable for integration. Bulk ferroelectrics form the core of traditional stand-alone electromechanical devices such as sensors, actuators and ultrasonic devices. Future applications need to be integrated into thin film form on semiconductor wafers, but the attachment to the wafer induces a mechanical constraint, w ....Engineered control of polarisation rotation in ferroelectric bilayers. This project aims to develop interface engineered nanoscale ferroelectric thin films with functional properties suitable for integration. Bulk ferroelectrics form the core of traditional stand-alone electromechanical devices such as sensors, actuators and ultrasonic devices. Future applications need to be integrated into thin film form on semiconductor wafers, but the attachment to the wafer induces a mechanical constraint, which dramatically suppresses the electromechanical response. This project aims to solve this problem by "polarisation rotation", achieved by layered stacking of thin film ferroelectrics. Engineered control of ferroelectric polarization rotation could be the pathway to modern electromechanical devices.Read moreRead less
Design and exploration of novel p-block materials for visible light photocatalysis. This project aims to design and explore novel visible light p-block photocatalysts through in depth surface studies of materials at an atomic level. A new strategy of band structure engineering and in-situ investigation of atomic-level photocatalytic dynamics will be the key elements in this research which is expected to yield several novel visible light photocatalysts. The outcome of the project will be the unde ....Design and exploration of novel p-block materials for visible light photocatalysis. This project aims to design and explore novel visible light p-block photocatalysts through in depth surface studies of materials at an atomic level. A new strategy of band structure engineering and in-situ investigation of atomic-level photocatalytic dynamics will be the key elements in this research which is expected to yield several novel visible light photocatalysts. The outcome of the project will be the understanding of processes and mechanisms underlying the photocatalysis and building the foundation of usable, stable, and durable visible-light photocatalytic applications.Read moreRead less
Reducing gas and ash corrosion in advanced power generation. Advanced power generation using new coal combustion technologies increases energy efficiency and makes carbon dioxide capture possible, but increases the corrosion problems. This project aims to determine the corrosion behaviour of chromia-scale forming iron- and nickel-base alloys in the presence of deposits (coal ashes and salts) under carbon dioxide rich gas atmospheres. The increased understanding of alloy behaviour in hot corrosiv ....Reducing gas and ash corrosion in advanced power generation. Advanced power generation using new coal combustion technologies increases energy efficiency and makes carbon dioxide capture possible, but increases the corrosion problems. This project aims to determine the corrosion behaviour of chromia-scale forming iron- and nickel-base alloys in the presence of deposits (coal ashes and salts) under carbon dioxide rich gas atmospheres. The increased understanding of alloy behaviour in hot corrosive ashes and gases, will permit more effective materials design and selection leading to more efficient and economic technologies for reliable and low cost carbon capture in energy production, waste-energy conversion and related industries.Read moreRead less
Two-dimensional plasmonic heterogeneous nanostructures for photocatalysis. This project aims to design and explore two-dimensional heterogeneous photocatalysts that can convert solar energy into usable chemical energy. This project will investigate the correlation between surface plasmonic resonance and photocatalytic activities on the atomic level. Heterogeneous engineering and in-situ investigation of atomic-level photocatalytic dynamics is expected to yield several new full-solar-spectrum pho ....Two-dimensional plasmonic heterogeneous nanostructures for photocatalysis. This project aims to design and explore two-dimensional heterogeneous photocatalysts that can convert solar energy into usable chemical energy. This project will investigate the correlation between surface plasmonic resonance and photocatalytic activities on the atomic level. Heterogeneous engineering and in-situ investigation of atomic-level photocatalytic dynamics is expected to yield several new full-solar-spectrum photocatalysts. The project is expected to contribute to the understanding of the processes and mechanisms underlying photocatalysis, and lead to useable, stable and durable photocatalytics. The outcomes will enable efficient, cost-effective and reliable production of clean energy in a low-emission way.Read moreRead less