Anion Binding and Sensing With Self-Assembled Metallo-Supramolecular Assemblies. Anions are of particular significance in several areas relating to the day-to-day lives of Australians; for example as contaminants in waterways and nuclear waste streams, as indicators of chemical weapons, and as antagonists in biological systems. The proposed research programme will investigate a relatively unexplored approach to binding and sensing anions. This will further research in the area of supramolecular ....Anion Binding and Sensing With Self-Assembled Metallo-Supramolecular Assemblies. Anions are of particular significance in several areas relating to the day-to-day lives of Australians; for example as contaminants in waterways and nuclear waste streams, as indicators of chemical weapons, and as antagonists in biological systems. The proposed research programme will investigate a relatively unexplored approach to binding and sensing anions. This will further research in the area of supramolecular chemistry, providing additional research expertise in this rapidly progressing area of the chemical sciences. In terms of Breakthrough science the targeted assemblies will shed further light on self-assembly processes involving ligands with different domains, placing Australian research at the forefront of such investigations.Read moreRead less
Internally decorated discrete Metallo-supramolecular Assemblies and infinite Metal-Organic Frameworks as molecular containers. In the macroscopic world, containers are used to hold, provide physical protection, or create a modified environment for their contents. This project will result in the synthesis of novel molecular container materials that provide decorated internal surfaces capable of selectively binding chemical species. In addition to the breakthrough scientific benefits of establish ....Internally decorated discrete Metallo-supramolecular Assemblies and infinite Metal-Organic Frameworks as molecular containers. In the macroscopic world, containers are used to hold, provide physical protection, or create a modified environment for their contents. This project will result in the synthesis of novel molecular container materials that provide decorated internal surfaces capable of selectively binding chemical species. In addition to the breakthrough scientific benefits of establishing the fundamentals of these systems, the binding of chemicals, which are environmental contaminants, will provide the grounding for applications that will contribute to the national priority of 'Frontier technologies'. Furthermore, this research will lead to the training of the next generation of Australian scientists by quality international researchers.Read moreRead less
Linkage Infrastructure, Equipment And Facilities - Grant ID: LE0346515
Funder
Australian Research Council
Funding Amount
$507,000.00
Summary
Fluorescence Detector for the Australian National Beamline Facility. X-ray absorption spectroscopy (XAS) is an extremely important synchrotron radiation tool for determining the local structure around an X-ray absorbing atom. This has many applications in the study of materials, minerals, metal complexes, and metalloproteins and can often be used to obtain information that is not available by other techniques, because structural information can be obtained in the solid or solution state and in ....Fluorescence Detector for the Australian National Beamline Facility. X-ray absorption spectroscopy (XAS) is an extremely important synchrotron radiation tool for determining the local structure around an X-ray absorbing atom. This has many applications in the study of materials, minerals, metal complexes, and metalloproteins and can often be used to obtain information that is not available by other techniques, because structural information can be obtained in the solid or solution state and in mixtures. The current proposal is aimed at introducing new technology into the Australian National Beamline Facility that will greatly improve the quality and quantity of experiments that can be performed and extend studies into dilute solutions and protein samples.Read moreRead less
Linkage Infrastructure, Equipment And Facilities - Grant ID: LE0238533
Funder
Australian Research Council
Funding Amount
$480,000.00
Summary
In Situ Spectroscopy of Particle and Material Interfaces. We seek to establish a world-class research facility for the in situ study of particle and material interfaces. The two techniques that will form the backbone of the facility are Raman scattering and surface second harmonic generation (SHG). The proposed in situ spectroscopy facility will be multi-disciplinary, contributing to research in chemistry, chemical engineering, geology, forensic science, and biotechnology. The establishment o ....In Situ Spectroscopy of Particle and Material Interfaces. We seek to establish a world-class research facility for the in situ study of particle and material interfaces. The two techniques that will form the backbone of the facility are Raman scattering and surface second harmonic generation (SHG). The proposed in situ spectroscopy facility will be multi-disciplinary, contributing to research in chemistry, chemical engineering, geology, forensic science, and biotechnology. The establishment of the facility will enhance research in the areas of minerals processing, mineralogy, water treatment, and drug delivery.Read moreRead less
Linkage Infrastructure, Equipment And Facilities - Grant ID: LE0989068
Funder
Australian Research Council
Funding Amount
$637,120.00
Summary
Equipment for Metastable Induced Electron Spectroscopy: surface analysis with excellent surface sensitivity. One of the major research strengths of Australia is surface science as it is important for both fundamental and industry related research. In many cases it is crucial to investigate the outermost layer of a material or mineral. Metastable Induced Electron Spectroscopy is an ideal technique as it is sensitive exclusively to the outermost layer of a broad range of samples. The information g ....Equipment for Metastable Induced Electron Spectroscopy: surface analysis with excellent surface sensitivity. One of the major research strengths of Australia is surface science as it is important for both fundamental and industry related research. In many cases it is crucial to investigate the outermost layer of a material or mineral. Metastable Induced Electron Spectroscopy is an ideal technique as it is sensitive exclusively to the outermost layer of a broad range of samples. The information gained is not accessible by any other method. The proposed equipment will be the first of this type in Australia and will complement existing surface science facilities. The project will enhance Australia's position in surface science internationally and a large number of projects will benefit from access to the equipment.Read moreRead less
Linkage Infrastructure, Equipment And Facilities - Grant ID: LE160100033
Funder
Australian Research Council
Funding Amount
$500,000.00
Summary
Equipment for Advanced Surface Analysis. Equipment for advanced surface analysis:
This project aims to establish equipment for advanced surface analysis to provide Australian researchers with cutting-edge capabilities in surface science. Vital chemical and physical reactions often occur at surfaces. Understanding these reactions requires analysis of the composition and electronic structure of the surface and near-surface regions. Neutral impact collision ion scattering spectroscopy and inverse ....Equipment for Advanced Surface Analysis. Equipment for advanced surface analysis:
This project aims to establish equipment for advanced surface analysis to provide Australian researchers with cutting-edge capabilities in surface science. Vital chemical and physical reactions often occur at surfaces. Understanding these reactions requires analysis of the composition and electronic structure of the surface and near-surface regions. Neutral impact collision ion scattering spectroscopy and inverse photoemission spectroscopy measure concentration depth profiles and electronic structure. The depth resolution of the profiles is in the order of the distance between two neighbouring atoms in a solid or liquid and is the best currently achievable. The equipment providing these capabilities is expected to support research with applications in photovoltaics, catalysis, colloid surfaces and interfaces, coatings and nanocomposites.Read moreRead less
Designed to last: novel gradient coatings for extreme environments. Hard coatings are frequently applied to equipment operating in harsh environments. Often such coatings are highly brittle and so fragile under stress, especially at high temperatures or in corrosive environments. Premature failure can affect safety and lead to negative economic and environmental consequences. The objective of this project is to combine bioinspired microstructural design with an emerging alloying concept to produ ....Designed to last: novel gradient coatings for extreme environments. Hard coatings are frequently applied to equipment operating in harsh environments. Often such coatings are highly brittle and so fragile under stress, especially at high temperatures or in corrosive environments. Premature failure can affect safety and lead to negative economic and environmental consequences. The objective of this project is to combine bioinspired microstructural design with an emerging alloying concept to produce a breakthrough in the development of engineering coatings; for example, overcoming the long standing trade-off between hardness and toughness. Such an innovative coating is expected to be highly durable in extreme conditions, and in so doing will help transform manufacturing, mining and desalination industries.Read moreRead less
Design of Tough, Durable and Corrosion-resistant Coatings. Coatings are frequently applied to components operating in harsh environments to enhance durability. Often such coatings exhibit low toughness and poor corrosion resistance that leads to premature failure. The aim of this project is to design, characterise and test innovative coatings that exhibit unique architectures based on natural materials such as teeth and nacre. It is envisaged that these coatings will be hard, tough and durable i ....Design of Tough, Durable and Corrosion-resistant Coatings. Coatings are frequently applied to components operating in harsh environments to enhance durability. Often such coatings exhibit low toughness and poor corrosion resistance that leads to premature failure. The aim of this project is to design, characterise and test innovative coatings that exhibit unique architectures based on natural materials such as teeth and nacre. It is envisaged that these coatings will be hard, tough and durable in hostile, corrosive environments, and will thus, transform industries such as manufacturing, mining and offshore oil exploration as well as enhance the lifetime of prosthetic devices.Read moreRead less
Linkage Infrastructure, Equipment And Facilities - Grant ID: LE0346733
Funder
Australian Research Council
Funding Amount
$399,466.00
Summary
Ultra-Sensitive CCD Diffractometer with High Intensity X-ray Photon Generator. X-ray photon diffraction from single crystals provides the most accurate, precise and detailed three dimensional chemical structure information. It is however often difficult to obtain crystals of complex chemical assemblies, such as those used in nanotechnology and photon technology, suitable for diffraction analysis using equipment currently available at Australian chemical crystal structure facilities. The collab ....Ultra-Sensitive CCD Diffractometer with High Intensity X-ray Photon Generator. X-ray photon diffraction from single crystals provides the most accurate, precise and detailed three dimensional chemical structure information. It is however often difficult to obtain crystals of complex chemical assemblies, such as those used in nanotechnology and photon technology, suitable for diffraction analysis using equipment currently available at Australian chemical crystal structure facilities. The collaborating institutions seek to overcome this problem by purchasing a high sensitivity CCD area detector coupled to an intense laboratory source of X-ray photons. The installation of the equipment would be the first of its kind at an Australian facility and only the fourth worldwide.Read moreRead less