Solar-driven massive hydrogen production from biomass and biomass/coal mixtures by supercritical water gasification. Cheap and massive hydrogen production from renewable resources is one of the key challenges to achieve a hydrogen economy that promises to ultimately solve critical problems, such as energy depletion and climate change. This project exactly falls into this research and development priority and will benefit Australian economy and environment.
Nano- and micro-scale engineering of MoS2-based catalyst for conversion of syngas to ethanol. Domestic production of ethanol to provide a 10% blend in petrol (E10) can be achieved from waste methane gas that Australia currently vents or flares to atmosphere. This project aims to develop a conversion process for making ethanol from syngas (the product of coal or methane gasification). Small scale, modularised plants would make ethanol locally to the methane emission source. The benefits of local ....Nano- and micro-scale engineering of MoS2-based catalyst for conversion of syngas to ethanol. Domestic production of ethanol to provide a 10% blend in petrol (E10) can be achieved from waste methane gas that Australia currently vents or flares to atmosphere. This project aims to develop a conversion process for making ethanol from syngas (the product of coal or methane gasification). Small scale, modularised plants would make ethanol locally to the methane emission source. The benefits of local E10 production would be a reduction in the oil trade deficit of $1 billion per year, $500 million per year in lower carbon imposts to industry and government, 25 million tonnes per year of reduced CO2e release to atmosphere and significantly improved urban air through reduced emissions from car transport, with attendant human health benefits.Read moreRead less
Hydrogen Production by Non-thermal Plasma Assisted Catalytic Pyrolysis of Natural Gas. This project aims to develop a cost effective technology for hydrogen production using catalytic pyrolysis of natural gas assisted by non-thermal plasma. The mechanism and kinetics of catalytic hydrocarbon decomposition on carbons produced in situ will be systematically studied. Based on the fundamental understanding of carbon nanostructures and their catalytic activities and stabilities, the non-thermal plasm ....Hydrogen Production by Non-thermal Plasma Assisted Catalytic Pyrolysis of Natural Gas. This project aims to develop a cost effective technology for hydrogen production using catalytic pyrolysis of natural gas assisted by non-thermal plasma. The mechanism and kinetics of catalytic hydrocarbon decomposition on carbons produced in situ will be systematically studied. Based on the fundamental understanding of carbon nanostructures and their catalytic activities and stabilities, the non-thermal plasma and the catalytic reactions will be optimized to achieve high conversion and catalytic stability. The project will lead to a new process combining effective carbon catalyst and low temperature plasma to produce pure hydrogen with high energy efficiency and no CO2 emissions.Read moreRead less
Multicomponent gas counter-diffusion in coal. Coalbed methane resources in Australia surpass $20billion at present gas prices. Using CO2 as an enhancement fluid, recovery of methane can potentially be improved by 50% adding a further $10b value, simultaneously permanently and safely sequestering the CO2, with possible carbon credits of up to $15b. The nature of the simultaneous exchange of CO2, methane and other gases within the coal dictates many of the engineering requirements for optimal exp ....Multicomponent gas counter-diffusion in coal. Coalbed methane resources in Australia surpass $20billion at present gas prices. Using CO2 as an enhancement fluid, recovery of methane can potentially be improved by 50% adding a further $10b value, simultaneously permanently and safely sequestering the CO2, with possible carbon credits of up to $15b. The nature of the simultaneous exchange of CO2, methane and other gases within the coal dictates many of the engineering requirements for optimal exploitation. It underlies the development of coal gas reservoir simulators, which currently do not incorporate this critical feature. This project is directed at understanding that counterflow and exchange.Read moreRead less
Development of Superflux Carbon Nanotube Membranes for Gas Separation. The project seeks to develop gas separation membranes displaying superfluxes - throughputs 10 to 100 times higher than current systems, with lower operating costs. There is compelling evidence that very high flow rates are achievable and they have been shown for single gas transport. Theory predicts that highly selective separations are possible, but this has not yet been experimentally shown - a key outcome from this proje ....Development of Superflux Carbon Nanotube Membranes for Gas Separation. The project seeks to develop gas separation membranes displaying superfluxes - throughputs 10 to 100 times higher than current systems, with lower operating costs. There is compelling evidence that very high flow rates are achievable and they have been shown for single gas transport. Theory predicts that highly selective separations are possible, but this has not yet been experimentally shown - a key outcome from this project. The applications are widespread and include separation of carbon dioxide from power station flue gas for sequestration, purification of natural gas and provision of pure component gases such as oxygen and nitrogen amongst others.Read moreRead less
Membrane distillation development for concentrated solar thermal systems. Membrane distillation development for concentrated solar thermal systems. This project aims to develop a new membrane distillation module that works with a high efficiency solar thermal tower system. Fresh water and energy are inextricably linked and form the basis for all human activity. Remote locations in Australia and the Middle East and North Africa are blessed with abundant solar resources and increasing levels of de ....Membrane distillation development for concentrated solar thermal systems. Membrane distillation development for concentrated solar thermal systems. This project aims to develop a new membrane distillation module that works with a high efficiency solar thermal tower system. Fresh water and energy are inextricably linked and form the basis for all human activity. Remote locations in Australia and the Middle East and North Africa are blessed with abundant solar resources and increasing levels of development, but burdened by access to reliable water treatment and electricity generation facilities. This project will use recently developed materials and design tools to overcome technical challenges that limited membrane distillation technology. This is expected to open up an innovative method for co-production of water and electricity which can handle transient solar and water quality inputs.Read moreRead less
Controllable Synthesis of Defects in Catalysts for Electrocatalysis . This project aims to address the most critical issue of electrocatalysis: identification of active sites for carbon-based metal free catalysts (CMFCs). Through the development of new methodologies, this proposal will, for the first time, controllably synthesise the vacancy defects that are the major active sites for CMFCs. The expected outcomes from this project include in-depth understanding of the fundamentals of electrocata ....Controllable Synthesis of Defects in Catalysts for Electrocatalysis . This project aims to address the most critical issue of electrocatalysis: identification of active sites for carbon-based metal free catalysts (CMFCs). Through the development of new methodologies, this proposal will, for the first time, controllably synthesise the vacancy defects that are the major active sites for CMFCs. The expected outcomes from this project include in-depth understanding of the fundamentals of electrocatalysis: the reactivity of active sites and the catalytic performance with the number of active sites; which will not only significantly advance knowledge but also achieve breakthrough technologies that greatly benefit to the society and economy both for Australia and worldwide.Read moreRead less
Methane Coupling Using Mixed Conducting Catalytic Ceramic Hollow Fibre Membrane Reactor. The Gas product industry is one of the most important economic sectors in Australia, employing 10000 people with market value of $ 100 billion per year from power generation and LNG export. However, there are increasing concerns over issues of the green house gases emission and petroleum dwindling. This project addresses the technology needs in converting natural gas to more useful chemicals via a more effic ....Methane Coupling Using Mixed Conducting Catalytic Ceramic Hollow Fibre Membrane Reactor. The Gas product industry is one of the most important economic sectors in Australia, employing 10000 people with market value of $ 100 billion per year from power generation and LNG export. However, there are increasing concerns over issues of the green house gases emission and petroleum dwindling. This project addresses the technology needs in converting natural gas to more useful chemicals via a more efficient and cleaner means of methane utilization. The project target is to make the natural gas resources in Australia to delivery high value products with considerable economic benefits and increased employment opportunities. Read moreRead less
Perovskite Asymmetric Hollow Fibres for Oxygen Separation in Clean Coal Energy Delivery. The coal industry is one of the most important economic sectors in Australia, employing 30000 people, whilst black coal is Australia's largest export worth around $24.5 billion. Energy security of supply is critical to Australia's social stability and economic growth, though Australia's reliance on coal for energy delivery is under strong scrutiny due to carbon mitigation. This project addresses the technolo ....Perovskite Asymmetric Hollow Fibres for Oxygen Separation in Clean Coal Energy Delivery. The coal industry is one of the most important economic sectors in Australia, employing 30000 people, whilst black coal is Australia's largest export worth around $24.5 billion. Energy security of supply is critical to Australia's social stability and economic growth, though Australia's reliance on coal for energy delivery is under strong scrutiny due to carbon mitigation. This project addresses the technology needs in tonnage oxygen separation towards a more efficient and cleaner means of generating energy. The project's benefits target at providing Australian consumers with affordable electricity in a decarbonised economy, enabling clean coal energy delivery to underpin the international competitiveness of the entire Australian economy.Read moreRead less
Discovery Early Career Researcher Award - Grant ID: DE150100820
Funder
Australian Research Council
Funding Amount
$390,000.00
Summary
Nanowire photoelectrodes for carbon dioxide conversion. Returning carbon dioxide (CO2) to a useful state is a significant and challenging problem which requires appropriate devices and energy input. By utilising sunlight as a promising and green energy input, the conversion of CO2 into liquid fuel would positively impact the global carbon balance. This project aims to prepare abundant, non-toxic and sufficiently active photoelectrodes with one dimensional nanostructure, then develop appropriate ....Nanowire photoelectrodes for carbon dioxide conversion. Returning carbon dioxide (CO2) to a useful state is a significant and challenging problem which requires appropriate devices and energy input. By utilising sunlight as a promising and green energy input, the conversion of CO2 into liquid fuel would positively impact the global carbon balance. This project aims to prepare abundant, non-toxic and sufficiently active photoelectrodes with one dimensional nanostructure, then develop appropriate and robust photoelectrochemical devices to convert CO2 into liquid fuels. This project aims to help reduce the atmospheric CO2 concentrations and explore a new energy source.Read moreRead less