Structure-Property Relationships of Polymers with Controlled Architecture. Mechanical properties of a polymer (e.g., how elastic it is and how it dissipates energy when compressed) govern how well it performs as an adhesive, or its behaviour when melted and shaped into a consumer item. This project aims to relate molecular architecture to mechanical properties, using new techniques which permit the creation of polymers wherein each architectural characteristic is separately controlled. This has ....Structure-Property Relationships of Polymers with Controlled Architecture. Mechanical properties of a polymer (e.g., how elastic it is and how it dissipates energy when compressed) govern how well it performs as an adhesive, or its behaviour when melted and shaped into a consumer item. This project aims to relate molecular architecture to mechanical properties, using new techniques which permit the creation of polymers wherein each architectural characteristic is separately controlled. This has the potential to develop fundamental understanding for structure-property relations for the type of branched polymers that are in common use in industry and for which adequate models do not currently exist.Read moreRead less
An Integrated Framework for Optimisation and Control of Key Product Properties in Emulsion Polymerisation. Emulsion polymerization is of major industrial importance. In addition to process efficiency, the use of water as the reactor medium provides environmental benefits. This proposal is aimed at building an integrated framework to analyse, model, control and optimise emulsion polymerisation systems in order to understand, design and operate such complex systems to obtain desired polymer produc ....An Integrated Framework for Optimisation and Control of Key Product Properties in Emulsion Polymerisation. Emulsion polymerization is of major industrial importance. In addition to process efficiency, the use of water as the reactor medium provides environmental benefits. This proposal is aimed at building an integrated framework to analyse, model, control and optimise emulsion polymerisation systems in order to understand, design and operate such complex systems to obtain desired polymer product characteristics. Complex kinetic, transport and evolution equations will be analysed and solved for predicting and controlling key product properties. This project will provide not only a significant advance in fundamental knowledge of polymerisation systems but will also enable production of cost-effective ?designer polymers? for a wide-range of applications.Read moreRead less
Nanostructured materials by controlled photopolymerization. Photo-polymerization is an important and flexible means of converting a crosslinkable monomer into a solid and has application ranging from lens production to photo-lithography. This project aims at developing the technology of producing multi-phase structures of controllable morphology by selective and independent dual photo-polymerization of blends of crosslinkable monomers at controlled rates. These morphologies may have applicatio ....Nanostructured materials by controlled photopolymerization. Photo-polymerization is an important and flexible means of converting a crosslinkable monomer into a solid and has application ranging from lens production to photo-lithography. This project aims at developing the technology of producing multi-phase structures of controllable morphology by selective and independent dual photo-polymerization of blends of crosslinkable monomers at controlled rates. These morphologies may have applications in toughening polymers with minimum loss in strength and optical transparency, abrasion resistant coatings, tissue engineering (where the phases have differing biodegradability), in microfluidics, and microelectro-mechanical systems (where sub-micron channels/domains are required) or in membrane separation.Read moreRead less
Novel network polymers with photoinduced plasticity. The production of crosslinked polymers (thermosets and rubbers) is a multi-billion dollar industry and these polymers are irreplaceable in their use in numerous applications in the household goods, medical, electronics, automotive and construction industries. However, they shrink during solidification causing internal stresses which weaken them and they can not be reshaped, repaired or recycled. This study will develop a novel range of cros ....Novel network polymers with photoinduced plasticity. The production of crosslinked polymers (thermosets and rubbers) is a multi-billion dollar industry and these polymers are irreplaceable in their use in numerous applications in the household goods, medical, electronics, automotive and construction industries. However, they shrink during solidification causing internal stresses which weaken them and they can not be reshaped, repaired or recycled. This study will develop a novel range of crosslinkable polymers which can change shape on irradiation by light (or by heating) for use in applications ranging from repairable composites, stress-free lens, non-shrinking dental filling materials and light-sensitive actuators which will have significant benefit to industry.Read moreRead less
High efficiency photoinitiators for novel photopolymerization processes. The radiation curing industry is worth several billion dollars world-wide with an Australian market of ca. $100 million and an even greater market in the Asian region. One of the main factors controlling the expansion of this industry is the development of new photoinitiator systems with improved performance. This project aims to combine the skills of three leading scientists in the photocuring field to develop more efficie ....High efficiency photoinitiators for novel photopolymerization processes. The radiation curing industry is worth several billion dollars world-wide with an Australian market of ca. $100 million and an even greater market in the Asian region. One of the main factors controlling the expansion of this industry is the development of new photoinitiator systems with improved performance. This project aims to combine the skills of three leading scientists in the photocuring field to develop more efficient, environmentally-friendly systems by controlling the initiation and polymerization mechanisms in (meth)acrylate, cyclic ether, cyanate and vinyl ethers. This should benefit local manufacturers exporting into the printing, adhesive, dental, lithography, composite industries and to the photopolymer industry generally.Read moreRead less