Putting metal organic frameworks to work at interfaces. This project aims to develop new strategies to better synthesize ultrathin Metal-organic framework (MOF) membranes by nanostructured and chemically functionalized substrates. MOF materials have enormous potential due to the extraordinary structural and chemical diversity of these crystalline microporous materials and their potential applications in gas storage, separation, catalysis and sensing. However, a major challenge is fabricating thi ....Putting metal organic frameworks to work at interfaces. This project aims to develop new strategies to better synthesize ultrathin Metal-organic framework (MOF) membranes by nanostructured and chemically functionalized substrates. MOF materials have enormous potential due to the extraordinary structural and chemical diversity of these crystalline microporous materials and their potential applications in gas storage, separation, catalysis and sensing. However, a major challenge is fabricating thin robust MOF films or patterns on porous, flexible, and nonporous substrates, quickly and easily in order to construct useful devices. The project will grow ultrathin layers of molecular sieving and electroactive MOFs to produce technology platforms for large scale device manufacturing.Read moreRead less
Unlocking the catalytic activity of metal oxides through hybrid catalysis. This project aims to understand the interaction of light responsive nano-metals and metal oxide supports in photo-thermal catalysis, and channel light and heat to efficiently drive catalytic reactions. From this understanding, it will develop principles to activate the active site of metal oxides and control catalytic activity with high selectivity and stability. It will use this knowledge to selectively oxidate methane a ....Unlocking the catalytic activity of metal oxides through hybrid catalysis. This project aims to understand the interaction of light responsive nano-metals and metal oxide supports in photo-thermal catalysis, and channel light and heat to efficiently drive catalytic reactions. From this understanding, it will develop principles to activate the active site of metal oxides and control catalytic activity with high selectivity and stability. It will use this knowledge to selectively oxidate methane and oxidative coupling of methane reactions. The expected outcome is an inexpensive green catalysis method for chemical manufacture. This should lower the amount of waste, decrease energy consumption and improve human health, finite global resources and quality of life.Read moreRead less